najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/22208054201564479488najo-1028Research ArticleСтатьиEvolution of size and composition of a multicomponent gas bubble in liquid solutionEvolution of size and composition of a multicomponent gas bubble in liquid solutionKuchmaA. E.KuchmaA. E.

Department of Statistical Physics, Faculty of Physics

Ulyanovskaya 1, Petrodvoretz, St. Petersburg, 198504

Department of Statistical Physics, Faculty of Physics

Ulyanovskaya 1, Petrodvoretz, St. Petersburg, 198504

ShchekinA. K.ShchekinA. K.

Department of Statistical Physics, Faculty of Physics

Ulyanovskaya 1, Petrodvoretz, St. Petersburg, 198504

Department of Statistical Physics, Faculty of Physics

Ulyanovskaya 1, Petrodvoretz, St. Petersburg, 198504

akshch@list.ruSt. Petersburg State UniversityRussian Federation20151608202564479488Copyright © Kuchma A.E., Shchekin A.K., 20252025Kuchma A.E., Shchekin A.K.Kuchma A.E., Shchekin A.K.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/1028

The equations describing the transient and steady stages of size and composition evolution for a gas bubble which grows or shrinks due to the diffusion of several gases dissolved in liquid solution have been derived. The diffusion fluxes for gases in the liquid mixture caused by the bubble growth or dissolution were assumed to be quasi-stationary and the mixture of the gases in the bubble was treated as ideal. The analytical solutions for the obtained evolution equations have been found for bubbles of any size with an arbitrary number of components in the case of equal products of diffusivities and solubilities of dissolved gases in the liquid solution, and for sufficiently large binary bubbles for which capillary effects can be neglected.

The equations describing the transient and steady stages of size and composition evolution for a gas bubble which grows or shrinks due to the diffusion of several gases dissolved in liquid solution have been derived. The diffusion fluxes for gases in the liquid mixture caused by the bubble growth or dissolution were assumed to be quasistationary and the mixture of the gases in the bubble was treated as ideal. The analytical solutions for the obtained evolution equations have been found for bubbles of any size with an arbitrary number of components in the case of equal products of diffusivities and solubilities of dissolved gases in the liquid solution, and for sufficiently large binary bubbles for which capillary effects can be neglected.

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The authors declare that there are no conflicts of interest present.