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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">najo-1044</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMISTRY AND MATERIAL SCIENCE</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЯ И МАТЕРИАЛОВЕДЕНИЕ</subject></subj-group></article-categories><title-group><article-title>Volume properties of water solution and refraction at 25 oC water-soluble tris-malonate of light fullerene- C60[=C(COOH)2]3</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Semenov</surname><given-names>K. N.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Charykov</surname><given-names>N. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Kritchenkov</surname><given-names>A. S.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Cherepkova</surname><given-names>I. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Manyakina</surname><given-names>O. S.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Tyurin</surname><given-names>D. P.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Shestopalova</surname><given-names>A. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Keskinov</surname><given-names>V. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><email xlink:type="simple">keskinov@mail.ru</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Ivanova</surname><given-names>K. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Ivanova</surname><given-names>N. M.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Letenko</surname><given-names>D. G.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Nikitin</surname><given-names>V. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-5"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Fokina</surname><given-names>E. L.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Rakhimova</surname><given-names>O. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>Saint-Petersburg</p></bio><xref ref-type="aff" rid="aff-6"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>St. Petersburg State University</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-2"><institution>St. Petersburg State University; St. Petersburg State Technological Institute (Technical University)</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-3"><institution>St. Petersburg State Technological Institute (Technical University)</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-4"><institution>St. Petersburg State University Architecture Academy</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-5"><institution>St. Petersburg State Technical University</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-6"><institution>St. Petersburg State Electro-Technical University (LETI)</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2014</year></pub-date><pub-date pub-type="epub"><day>15</day><month>08</month><year>2025</year></pub-date><volume>5</volume><issue>3</issue><fpage>427</fpage><lpage>434</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Semenov K.N., Charykov N.A., Kritchenkov A.S., Cherepkova I.A., Manyakina O.S., Tyurin D.P., Shestopalova A.A., Keskinov V.A., Ivanova K.V., Ivanova N.M., Letenko D.G., Nikitin V.A., Fokina E.L., Rakhimova O.V., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Semenov K.N., Charykov N.A., Kritchenkov A.S., Cherepkova I.A., Manyakina O.S., Tyurin D.P., Shestopalova A.A., Keskinov V.A., Ivanova K.V., Ivanova N.M., Letenko D.G., Nikitin V.A., Fokina E.L., Rakhimova O.V.</copyright-holder><copyright-holder xml:lang="en">Semenov K.N., Charykov N.A., Kritchenkov A.S., Cherepkova I.A., Manyakina O.S., Tyurin D.P., Shestopalova A.A., Keskinov V.A., Ivanova K.V., Ivanova N.M., Letenko D.G., Nikitin V.A., Fokina E.L., Rakhimova O.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/1044">https://nanojournal.ifmo.ru/jour/article/view/1044</self-uri><abstract><p>The volume Properties of water soluble tris-malonate of light fullerene — C60[=C(COOH)2]3 were investigated with the help of quartz pycnometers at 25 ◦C, including the concentration dependence of density, average molar volume of the solutions and partial molar volumes of C60[=C(COOH)2]3 and H2O. Concentration dependence of the refraction index in water solutions of C60[=C(COOH)2]3 was also determined with the help of refractometer, specific and molar refraction of the components were calculated with the help of the rules of the additive refraction of solution components.</p></abstract><kwd-group xml:lang="en"><kwd>tris-malonate of light fullerene</kwd><kwd>volume properties</kwd><kwd>refraction</kwd></kwd-group><funding-group><funding-statement xml:lang="en">Research was performed with using the equipment of the Resource Center ‘GeoModel’ of Saint-Petersburg State University. This work has been accomplished as the part of the Ministry of Education and Science of the placecountry-regionRussian Federation research assignment ‘Realization of scientific research (fundamental studies, applied research and advanced developments)’. Project code: 2548.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">K.N.Semenov, N.A.Charykov, A.S.Kritchenkov, et al. Synthesis and identification water-soluble tris-malonate of light fullerene – C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics, 5 (2), P. 315–319 (2014).</mixed-citation><mixed-citation xml:lang="en">K.N.Semenov, N.A.Charykov, A.S.Kritchenkov, et al. Synthesis and identification water-soluble tris-malonate of light fullerene – C60[=C(COOH)2]3. Nanosystems: Physics, Chemistry, Mathematics, 5 (2), P. 315–319 (2014).</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">I.Lamparth, A.Hirsch. Water-soluble malonic acid derivatives of C60 with a defined three-dimensional structure. J. Chem. Soc Chem. 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