najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2024-15-3-388-397najo-109Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХCopper-modified g-C3N4/TiO2 nanostructured photocatalysts for H2 evolution from glucose aqueous solutionМодифицированные медью наноструктурированные фотокатализаторы g-C3N4/TiO2 для получения водорода из водных растворов глюкозыhttps://orcid.org/0009-0000-9399-0231ХаринаС. Н.KharinaS. N.

София Н. Харина

630090; просп. Академика Лаврентьева, 5; Новосибирск

Sofiya N. Kharina

630090; Lavrentieva Ave, 5; Novosibirsk

skharina@catalysis.ruhttps://orcid.org/0000-0002-4150-7049КуренковаА. Ю.KurenkovaA. Yu.

Анна Ю. Куренкова

630090; просп. Академика Лаврентьева, 5; Новосибирск

Anna Yu. Kurenkova

630090; Lavrentieva Ave, 5; Novosibirsk

kurenkova@catalysis.ruhttps://orcid.org/0000-0001-9610-9921СараевА. А.SaraevA. A.

Андрей А. Сараев

630090; просп. Академика Лаврентьева, 5; Новосибирск

Andrey A. Saraev

630090; Lavrentieva Ave, 5; Novosibirsk

asaraev@catalysis.ruhttps://orcid.org/0000-0002-3230-3335ГерасимовЕ. Ю.GerasimovE. Yu.

Евгений Ю. Герасимов

630090; просп. Академика Лаврентьева, 5; Новосибирск

Evgeny Yu. Gerasimov

630090; Lavrentieva Ave, 5; Novosibirsk

gerasimov@catalysis.ruhttps://orcid.org/0000-0001-8944-7666КозловаЕ. А.KozlovaE. A.

Екатерина А. Козлова

630090; просп. Академика Лаврентьева, 5; Новосибирск

Ekaterina A. Kozlova

630090; Lavrentieva Ave, 5; Novosibirsk

kozlova@catalysis.ruИнститут катализа им. Г.К. Борескова СО РАНBoreskov Institute of Catalysis SB RAS202401062025153388397Copyright © Kharina S.N., Kurenkova A.Y., Saraev A.A., Gerasimov E.Y., Kozlova E.A., 20252025Харина С.Н., Куренкова А.Ю., Сараев А.А., Герасимов Е.Ю., Козлова Е.А.Kharina S.N., Kurenkova A.Y., Saraev A.A., Gerasimov E.Y., Kozlova E.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/109

   Two strategies for synthesis of copper-modified composite photocatalysts based on graphitic carbon nitride and titanium dioxide for hydrogen evolution reaction are presented. The first one is based on the mechanical dispersion of separately prepared g-C3N4 and commercial TiO2 (Evonik P25), modified with copper. Another approach is co-calcination of melamine and commercial TiO2 with subsequent modification by copper. The samples were characterized using X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (UV-vis DRS), X-ray photoelectron spectroscopy (XPS), and high-resolution transmission electron microscopy (HRTEM). The synthesized photocatalysts were tested in hydrogen evolution from glucose aqueous solution under visible light irradiation (440 nm). The largest photocatalytic activities met 235 and 259 µmol·g−1·h−1, corresponding to the first and the second photocatalyst series, respectively. The most active photocatalyst from the first series 1 wt. % g-C3N4/1 wt. % CuOn/TiO2 maintained its hydrogen production rate during a 6-hour cyclic stability test.

   В данной работе представлены две методики синтеза композитных фотокатализаторов на основе графитоподобного нитрида углерода и диоксида титана, модифицированных медью, для получения водорода. Первый метод основывается на механическом смешении предварительно синтезированного g-C3N4 и TiO2 (Evonik P25), модифицированного медью. Другой подход заключается в совместном прокаливании меламина и TiO2 с последующим нанесением частиц меди. Образцы охарактеризованы с помощью рентгенофазового анализа (РФА), спектроскопии диффузного отражения в УФ и видимой областях (СДО), рентгеновской фотоэлектронной спектроскопии (РФЭС) и просвечивающей электронной микроскопии высокого разрешения (ПЭМ ВР). Полученные фотокатализаторы протестированы в реакции выделения водорода из водных растворов глюкозы под действием видимого света (440 нм). Самые высокие значения фотокаталитической активности равны 235 и 259 мкмоль·г-1·ч-1 для фотокатализаторов из первой и второй серии, соответственно. Наиболее активный фотокатализатор из первой серии сохраняет начальную скорость выделения водорода в течение 6 часов циклических испытаний.

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The authors declare that there are no conflicts of interest present.