<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">najo-1101</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PHYSICS</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ФИЗИКА</subject></subj-group></article-categories><title-group><article-title>Dependence of quantum yield of up-conversion luminescence on the composition of fluorite-type solid solution NaY1-x-yYbxEryF4</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Yasyrkina</surname><given-names>D. S.</given-names></name></name-alternatives><bio xml:lang="en"><p>38 Vavilov Street, Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Kuznetsov</surname><given-names>S. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>38 Vavilov Street, Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Ryabova</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>38 Vavilov Street, Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Pominova</surname><given-names>D. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>38 Vavilov Street, Moscow, 119991,</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Voronov</surname><given-names>V. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>38 Vavilov Street, Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Ermakov</surname><given-names>R. P.</given-names></name></name-alternatives><bio xml:lang="en"><p>38 Vavilov Street, Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Fedorov</surname><given-names>P. P.</given-names></name></name-alternatives><bio xml:lang="en"><p>38 Vavilov Street, Moscow, 119991</p></bio><email xlink:type="simple">ppfedorov@yandex.ru</email><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>A. M. Prokhorov General Physics Institute, Russian Academy of Sciences,</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-2"><institution>A. M. Prokhorov General Physics Institute, Russian Academy of Sciences</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2013</year></pub-date><pub-date pub-type="epub"><day>17</day><month>08</month><year>2025</year></pub-date><volume>4</volume><issue>5</issue><fpage>648</fpage><lpage>656</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Yasyrkina D.S., Kuznetsov S.V., Ryabova A.V., Pominova D.V., Voronov V.V., Ermakov R.P., Fedorov P.P., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Yasyrkina D.S., Kuznetsov S.V., Ryabova A.V., Pominova D.V., Voronov V.V., Ermakov R.P., Fedorov P.P.</copyright-holder><copyright-holder xml:lang="en">Yasyrkina D.S., Kuznetsov S.V., Ryabova A.V., Pominova D.V., Voronov V.V., Ermakov R.P., Fedorov P.P.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/1101">https://nanojournal.ifmo.ru/jour/article/view/1101</self-uri><abstract><p>A study of the properties of polycrystalline uorite-type NaY1􀀀x􀀀yYbxEryF4 solid solutions demonstrated that NaY0:87Yb0:10Er0:03F4 and NaY0:885Yb0:1Er0:015F4 samples produced up-conversion luminescence with 3.35% and 3.62% quantum yields, which were higher than quantum yields of the other NaY1-x-yyYbxEryF4 samples. NaY1-x-yYbxEryF4 specimens were prepared by co-precipitation from aqueous solutions by drop- wise addition of rare earth nitrate solutions to aqueous sodium uoride.</p></abstract><kwd-group xml:lang="en"><kwd>uorides</kwd><kwd>nanopowders</kwd><kwd>sodium</kwd><kwd>yttrium</kwd><kwd>up-conversion luminescence</kwd><kwd>quantum yield</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">P.P. Fedorov, A.A. Luginina, S.V. Kuznetsov, and V.V. Osiko. Nano uorides. J. Fluorine Chem., 132, P. 1012{1039 (2011).</mixed-citation><mixed-citation xml:lang="en">P.P. Fedorov, A.A. Luginina, S.V. Kuznetsov, and V.V. Osiko. Nano uorides. J. Fluorine Chem., 132, P. 1012{1039 (2011).</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">P. Zhang, W. Steelant, M. Kumar, M. Scholeld. Versatile photosensitizers for photodynamic therapy at infrared excitation. J. Am. Chem. Soc., 129, P. 4526{45257 (2007).</mixed-citation><mixed-citation xml:lang="en">P. Zhang, W. Steelant, M. Kumar, M. Scholeld. Versatile photosensitizers for photodynamic therapy at infrared excitation. J. Am. Chem. Soc., 129, P. 4526{45257 (2007).</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">D.K. Chatterjee, L. Sh. Fong, and Y. Zhang. Nanoparticle photodynamic therapy PDT. Advanced Drug Delivery Reviews., 60, P. 1627{1637 (2008).</mixed-citation><mixed-citation xml:lang="en">D.K. Chatterjee, L. Sh. Fong, and Y. Zhang. Nanoparticle photodynamic therapy PDT. Advanced Drug Delivery Reviews., 60, P. 1627{1637 (2008).</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">M. Haase and H. Schafer. Upconverting Nanoparticles. Angew. Chem. Int. Ed., 50, P. 5808-5829 (2011).</mixed-citation><mixed-citation xml:lang="en">M. Haase and H. Schafer. Upconverting Nanoparticles. Angew. Chem. Int. Ed., 50, P. 5808-5829 (2011).</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">F. Auzel. Upconversion and anti-stokes processes with f and d ions in solids. Chem Rev., 104, P. 139{173 (2004).</mixed-citation><mixed-citation xml:lang="en">F. Auzel. Upconversion and anti-stokes processes with f and d ions in solids. Chem Rev., 104, P. 139{173 (2004).</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">V.V. Ovsyankin, P.P. Feolov. Mechanism of summation of electronic excitations in activated crystals. JETP Lett., 3, P. 322{323 (1966).</mixed-citation><mixed-citation xml:lang="en">V.V. Ovsyankin, P.P. Feolov. Mechanism of summation of electronic excitations in activated crystals. JETP Lett., 3, P. 322{323 (1966).</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">P.P. Fedorov. Systems of alkali and rare-earth metal uorides. Russian J. Inorg. Chem., 44, P. 1703{1727 (1999).</mixed-citation><mixed-citation xml:lang="en">P.P. Fedorov. Systems of alkali and rare-earth metal uorides. Russian J. Inorg. Chem., 44, P. 1703{1727 (1999).</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">P.P. Fedorov, B.P. Sobolev, S.F. Belov. Fusibility diagram of the system NaF-YF3, and the cross-section Na0:4Y0:6F2:2-YOF. Inorg. Mater., 15(5), P. 640{643 (1979).</mixed-citation><mixed-citation xml:lang="en">P.P. Fedorov, B.P. Sobolev, S.F. Belov. Fusibility diagram of the system NaF-YF3, and the cross-section Na0:4Y0:6F2:2-YOF. Inorg. Mater., 15(5), P. 640{643 (1979).</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">S.V. Kuznetsov, A.V. Ryabova, D.S. Los`, P.P. Fedorov, V.V. Voronov, R.P. Ermakov, V.B. Loshchenov, V.V. Volkov, A.E. Baranchikov, V.V. Osiko. Synthesis and luminescent characteristics of submicron powders on the basis of sodium and yttrium uorides doped with rare earth elements. Nanotechnologies in Russia, 7, P. 615{628 (2012).</mixed-citation><mixed-citation xml:lang="en">S.V. Kuznetsov, A.V. Ryabova, D.S. Los`, P.P. Fedorov, V.V. Voronov, R.P. Ermakov, V.B. Loshchenov, V.V. Volkov, A.E. Baranchikov, V.V. Osiko. Synthesis and luminescent characteristics of submicron powders on the basis of sodium and yttrium uorides doped with rare earth elements. Nanotechnologies in Russia, 7, P. 615{628 (2012).</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">A.V. Ryabova, D.V. Pominova, V.A. Krut'ko, M.G. Komova, V.B. Loschenov. Spectroscopic research of upconversion nanomaterials based on complex oxide compounds doped with rare-earth ion pairs: benet for cancer diagnostics by upconversion uorescence and radio sensitive methods. Photon Lasers Med (2013). DOI 10.1515/plm-2013-0013.</mixed-citation><mixed-citation xml:lang="en">A.V. Ryabova, D.V. Pominova, V.A. Krut'ko, M.G. Komova, V.B. Loschenov. Spectroscopic research of upconversion nanomaterials based on complex oxide compounds doped with rare-earth ion pairs: benet for cancer diagnostics by upconversion uorescence and radio sensitive methods. Photon Lasers Med (2013). DOI 10.1515/plm-2013-0013.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">P.P. Fedorov, S.V. Kuznetsov, V.V. Voronov, I.V. Yarotskaya, V.V. Arbenina. Soft chemical synthesis of NaYF4 nanopowders. Russian J. Inorg. Chem., 53, P. 1681{1685 (2008).</mixed-citation><mixed-citation xml:lang="en">P.P. Fedorov, S.V. Kuznetsov, V.V. Voronov, I.V. Yarotskaya, V.V. Arbenina. Soft chemical synthesis of NaYF4 nanopowders. Russian J. Inorg. Chem., 53, P. 1681{1685 (2008).</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">D.S. Yasyrkina, S.V. Kuznetsov, P.P. Fedorov, V.V. Voronov, R.P. Ermakov, A.V. Ryabova, et al. Eect of the pH on the formation of NaYF4:Yb:Er nanopowders by co-crystallization in presence of polyethyleneimine. J. Fluorine Chem., accepted for publication.</mixed-citation><mixed-citation xml:lang="en">D.S. Yasyrkina, S.V. Kuznetsov, P.P. Fedorov, V.V. Voronov, R.P. Ermakov, A.V. Ryabova, et al. Eect of the pH on the formation of NaYF4:Yb:Er nanopowders by co-crystallization in presence of polyethyleneimine. J. Fluorine Chem., accepted for publication.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">P.P. Fedorov, V.B. Alexandrov, O.S. Bondareva, I.I. Buchinskaya, M.D. Val'covskii, and B.P. Sobolev. Concentration dependences of the unit-cell parameters of nonstoichiometric uorite-type phases Na0;5􀀀xR0;5+xF2+2x (R = Rare-earth elements). Crystallography Reports., 46, P. 239{245 (2001).</mixed-citation><mixed-citation xml:lang="en">P.P. Fedorov, V.B. Alexandrov, O.S. Bondareva, I.I. Buchinskaya, M.D. Val'covskii, and B.P. Sobolev. Concentration dependences of the unit-cell parameters of nonstoichiometric uorite-type phases Na0;5􀀀xR0;5+xF2+2x (R = Rare-earth elements). Crystallography Reports., 46, P. 239{245 (2001).</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">M. Pollnau, D. R. Gamelin, S. R. Luthi, H. U. Gudel, M. P. Hehlen. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems. Phys. Rev. B, 61, P. 3337{3346 (2000).</mixed-citation><mixed-citation xml:lang="en">M. Pollnau, D. R. Gamelin, S. R. Luthi, H. U. Gudel, M. P. Hehlen. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems. Phys. Rev. B, 61, P. 3337{3346 (2000).</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">D.O. Faulkner, S. Petrov, D.D. Perovic, N.P. Kherani, G.A. Ozin. Absolute quantum yields in NaYF4:Er,Yb upconverters { synthesis temperature and power dependence. J. Mater. Chem., 22, P. 24330{24334 (2012).</mixed-citation><mixed-citation xml:lang="en">D.O. Faulkner, S. Petrov, D.D. Perovic, N.P. Kherani, G.A. Ozin. Absolute quantum yields in NaYF4:Er,Yb upconverters { synthesis temperature and power dependence. J. Mater. Chem., 22, P. 24330{24334 (2012).</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">J-Ch. Boyer and Fr. van Veggel. Absolute quantum yield measurements of colloidal NaYF4: Er3+,Yb3+ upconverting nanoparticles. Nanoscale, 2, P. 1417{1419 (2010).</mixed-citation><mixed-citation xml:lang="en">J-Ch. Boyer and Fr. van Veggel. Absolute quantum yield measurements of colloidal NaYF4: Er3+,Yb3+ upconverting nanoparticles. Nanoscale, 2, P. 1417{1419 (2010).</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
