<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2016-7-4-599-603</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-1244</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>Dielectric studies of nanocrystalline calcium tungstate</article-title><trans-title-group xml:lang="ru"><trans-title>Dielectric studies of nanocrystalline calcium tungstate</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Aloysius</surname><given-names>N.</given-names></name><name name-style="western" xml:lang="en"><surname>Aloysius</surname><given-names>N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Physics</p><p>Thodupuzha-685 585, Kerala</p></bio><bio xml:lang="en"><p>Department of Physics</p><p>Thodupuzha-685 585, Kerala</p></bio><email xlink:type="simple">nanoncm@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Rintu</surname><given-names>M. S.</given-names></name><name name-style="western" xml:lang="en"><surname>Rintu</surname><given-names>M. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Physics</p><p>Ernakulam-682 011, Kerala</p></bio><bio xml:lang="en"><p>Department of Physics</p><p>Ernakulam-682 011, Kerala</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Muhammed</surname><given-names>E. M.</given-names></name><name name-style="western" xml:lang="en"><surname>Muhammed</surname><given-names>E. M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Physics</p><p>Ernakulam-682 011, Kerala</p></bio><bio xml:lang="en"><p>Department of Physics</p><p>Ernakulam-682 011, Kerala</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Varghese</surname><given-names>T.</given-names></name><name name-style="western" xml:lang="en"><surname>Varghese</surname><given-names>T.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Physics, Newman College;   Nanoscience Research Centre (NSRC), Department of Physics, Nirmala College</p><p>Thodupuzha-685 585, Kerala;Muvattupuzha – 686 661, Kerala</p></bio><bio xml:lang="en"><p>Department of Physics, Newman College;   Nanoscience Research Centre (NSRC), Department of Physics, Nirmala College</p><p>Thodupuzha-685 585, Kerala; Muvattupuzha – 686 661, Kerala</p></bio><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Newman College</institution></aff><aff xml:lang="en"><institution>Newman College</institution></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Maharajas College</institution></aff><aff xml:lang="en"><institution>Maharajas College</institution></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Newman College; &#13;
Nirmala College</institution></aff><aff xml:lang="en"><institution>Newman College; &#13;
Nirmala College</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2016</year></pub-date><pub-date pub-type="epub"><day>22</day><month>08</month><year>2025</year></pub-date><volume>7</volume><issue>4</issue><fpage>599</fpage><lpage>603</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Aloysius N., Rintu M.S., Muhammed E.M., Varghese T., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Aloysius N., Rintu M.S., Muhammed E.M., Varghese T.</copyright-holder><copyright-holder xml:lang="en">Aloysius N., Rintu M.S., Muhammed E.M., Varghese T.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/1244">https://nanojournal.ifmo.ru/jour/article/view/1244</self-uri><abstract><p>Nanocrystalline samples of CaWO4 were prepared at room temperature by simple chemical precipitation. The samples were characterized by X-ray diffraction and scanning electron microscopy. Energy dispersive X-ray analysis confirmed the elements present in the sample. The frequency and temperature dependence of the dielectric constant and ac electrical conductivity of the nanomaterial were investigated. Very low dielectric loss in nanocrystalline CaWO4 powder was observed at high frequencies. The values of ac electrical conductivity calculated from the permittivity studies were found to increase as frequency increased, conforming to small polaron hopping.</p></abstract><trans-abstract xml:lang="ru"><p>Nanocrystalline samples of CaWO4 were prepared at room temperature by simple chemical precipitation. The samples were characterized by X-ray diffraction and scanning electron microscopy. Energy dispersive X-ray analysis confirmed the elements present in the sample. The frequency and temperature dependence of the dielectric constant and ac electrical conductivity of the nanomaterial were investigated. Very low dielectric loss in nanocrystalline CaWO4 powder was observed at high frequencies. The values of ac electrical conductivity calculated from the permittivity studies were found to increase as frequency increased, conforming to small polaron hopping.</p></trans-abstract><kwd-group xml:lang="en"><kwd>chemical precipitation</kwd><kwd>dielectric constant</kwd><kwd>ac electrical conductivity</kwd><kwd>polaron hopping</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The authors are indebted to NSRC, Nirmala College, Muvattupuzha and Newman College, Thodupuzha for the support to undertake this study. The financial support from the University Grants Commission, New Delhi, India (FIP/12th Plan/KLMG020 TF03) is greatly acknowledged.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Kobayashi M., Ishii M., Usuki Y., Yahagi H. Scintillation characteristics of PbWO4 single crystals at room temperature. Nuclear Instru- ments and Methods in Physics Research A, 1993, 333 (2-3), P. 429–433.</mixed-citation><mixed-citation xml:lang="en">Kobayashi M., Ishii M., Usuki Y., Yahagi H. Scintillation characteristics of PbWO4 single crystals at room temperature. Nuclear Instru- ments and Methods in Physics Research A, 1993, 333 (2-3), P. 429–433.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Katelnikovas A., Grigorjeva L., et al. Sol-Gel Preparation of Nanocrystalline CaWO4 . Lithuanian J. of Physics, 2007, 47 (1), P. 63–68.</mixed-citation><mixed-citation xml:lang="en">Katelnikovas A., Grigorjeva L., et al. Sol-Gel Preparation of Nanocrystalline CaWO4 . Lithuanian J. of Physics, 2007, 47 (1), P. 63–68.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Phuruangrat A., Thongtem T., Thongtem S. Synthesis, characterization and photoluminescence of nanocrystalline calcium tungstate. J. Exp. Nanosci., 2009, 5, P. 263–267.</mixed-citation><mixed-citation xml:lang="en">Phuruangrat A., Thongtem T., Thongtem S. Synthesis, characterization and photoluminescence of nanocrystalline calcium tungstate. J. Exp. Nanosci., 2009, 5, P. 263–267.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Lou Z., Cocivera M. Cathodoluminescence of CaWO4 and SrWO4 thin films prepared by spray pyrolysis. Mater. Res. Bull., 2002, 37, P. 1573–1582.</mixed-citation><mixed-citation xml:lang="en">Lou Z., Cocivera M. Cathodoluminescence of CaWO4 and SrWO4 thin films prepared by spray pyrolysis. Mater. Res. Bull., 2002, 37, P. 1573–1582.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Nagirnyi V., Feldbach E., et al. Excitonic and recombination processes in CaWO4 and CdWO4 scintillators under synchrotron irradiation. Radiat. Meas., 1998, 29, P. 247–250.</mixed-citation><mixed-citation xml:lang="en">Nagirnyi V., Feldbach E., et al. Excitonic and recombination processes in CaWO4 and CdWO4 scintillators under synchrotron irradiation. Radiat. Meas., 1998, 29, P. 247–250.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Oishi S., Hirao M. Growth of CaWO4 whiskers from KCl flux. J.Mater.Sci., Lett., 1989, 8 (12), P. 1397–1398.</mixed-citation><mixed-citation xml:lang="en">Oishi S., Hirao M. Growth of CaWO4 whiskers from KCl flux. J.Mater.Sci., Lett., 1989, 8 (12), P. 1397–1398.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Liping L., Yiguo S., Guangshe L. Size-induced symmetric enhancement and its relevance to scheelite CaWO4 nanocrystals. J. Appl. Phys. Lett., 2007, 90, P. 054105–054107.</mixed-citation><mixed-citation xml:lang="en">Liping L., Yiguo S., Guangshe L. Size-induced symmetric enhancement and its relevance to scheelite CaWO4 nanocrystals. J. Appl. Phys. Lett., 2007, 90, P. 054105–054107.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Mogilevsky P., Parthasarathy T.A., Petry M.D. Anisotropy in room temperature microhardness and fracture of CaWO4 scheelite. Acta Materialia, 2004, 52, P. 5529–5537.</mixed-citation><mixed-citation xml:lang="en">Mogilevsky P., Parthasarathy T.A., Petry M.D. Anisotropy in room temperature microhardness and fracture of CaWO4 scheelite. Acta Materialia, 2004, 52, P. 5529–5537.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Vidya S., Sam Solomon., Thomas J.K. Synthesis of Nanocrystalline CaWO4 as Low-Temperature Co-Fired Ceramic Material: Processing, Structural and Physical Properties. Journal of Electronic Materials, 2012, 42, P. 129–137.</mixed-citation><mixed-citation xml:lang="en">Vidya S., Sam Solomon., Thomas J.K. Synthesis of Nanocrystalline CaWO4 as Low-Temperature Co-Fired Ceramic Material: Processing, Structural and Physical Properties. Journal of Electronic Materials, 2012, 42, P. 129–137.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Pullar R.C., Farrah S., Alford N.M. MgWO4, ZnWO4, NiWO4 and CoWO4 microwave dielectric ceramics. Journal of the European Ceramic Society, 2007, 27, P. 1059–1063.</mixed-citation><mixed-citation xml:lang="en">Pullar R.C., Farrah S., Alford N.M. MgWO4, ZnWO4, NiWO4 and CoWO4 microwave dielectric ceramics. Journal of the European Ceramic Society, 2007, 27, P. 1059–1063.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Sreedevi A., Priyanka K.P., et al. Nanophase α-Silver Tungstate for Potential Applications in Light Emitting Diodes and Gate Dielectrics. Advanced Science, Engineering and Medicine, 2015, 7, P. 498–505.</mixed-citation><mixed-citation xml:lang="en">Sreedevi A., Priyanka K.P., et al. Nanophase α-Silver Tungstate for Potential Applications in Light Emitting Diodes and Gate Dielectrics. Advanced Science, Engineering and Medicine, 2015, 7, P. 498–505.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Bao-Chun Guo, Peng Liu, et al. Effect of Preparation Methods on Microstructures and Microwave Dielectric Properties of CdWO4 ceramics. Integrated Ferroelectrics, 2015, 167, P. 107–114.</mixed-citation><mixed-citation xml:lang="en">Bao-Chun Guo, Peng Liu, et al. Effect of Preparation Methods on Microstructures and Microwave Dielectric Properties of CdWO4 ceramics. Integrated Ferroelectrics, 2015, 167, P. 107–114.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Chi Kao K. Dielectric phenomena in Solids. Elsevier, New York, 2004.</mixed-citation><mixed-citation xml:lang="en">Chi Kao K. Dielectric phenomena in Solids. Elsevier, New York, 2004.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Kar T., Choudhary R.N., Sharma S., Singh K.S. Structural and electrical properties of Ba2Na3RNb10O30 Ceramics. Indian J. Phys. A, 1999, 73 (4), P. 453-459.</mixed-citation><mixed-citation xml:lang="en">Kar T., Choudhary R.N., Sharma S., Singh K.S. Structural and electrical properties of Ba2Na3RNb10O30 Ceramics. Indian J. Phys. A, 1999, 73 (4), P. 453-459.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Ravinder D., Vijayakumar K. Dielectric behaviour of erbium substituted Mn–Zn ferrites. Bull. Mater. Sci., 2001, 24 (5), P. 505–509.</mixed-citation><mixed-citation xml:lang="en">Ravinder D., Vijayakumar K. Dielectric behaviour of erbium substituted Mn–Zn ferrites. Bull. Mater. Sci., 2001, 24 (5), P. 505–509.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Potty S.N., Khader M.A. Dielectric Properties of nanophase Ag2HgI4 and Ag2HgI4–Al2O3 nanocomposites. Bull. Mater. Sci., 2000, 23 (5), P. 361–367.</mixed-citation><mixed-citation xml:lang="en">Potty S.N., Khader M.A. Dielectric Properties of nanophase Ag2HgI4 and Ag2HgI4–Al2O3 nanocomposites. Bull. Mater. Sci., 2000, 23 (5), P. 361–367.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Murthy V., Sobhanadri J. Dielectric properties of some nickel-zinc ferrites at radio frequency. Phys Status Solidi (a), 1976, 36 (2), K133–K135.</mixed-citation><mixed-citation xml:lang="en">Murthy V., Sobhanadri J. Dielectric properties of some nickel-zinc ferrites at radio frequency. Phys Status Solidi (a), 1976, 36 (2), K133–K135.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Priyanka K.P., Sunny J., et al. Dielectric properties and a. c. conductivity of nanocrystalline titania. J. Basic Appl. Phys., 2013, 2, P. 105–108.</mixed-citation><mixed-citation xml:lang="en">Priyanka K.P., Sunny J., et al. Dielectric properties and a. c. conductivity of nanocrystalline titania. J. Basic Appl. Phys.,  2013, 2, P. 105–108.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Elliot S.R. Temperature dependence of a.c. conductivity of chalcogenide glasses. Phil. Mag. Part B, 1978, 37 (5), P. 553.</mixed-citation><mixed-citation xml:lang="en">Elliot S.R. Temperature dependence of a.c. conductivity of chalcogenide glasses. Phil. Mag. Part B, 1978, 37 (5), P. 553.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
