najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2016-7-4-624-628najo-1268Research ArticleСтатьиStudy of Faraday effect on Co1-xZnxFe2O4 nanoferrofluidsStudy of Faraday effect on Co1-xZnxFe2O4 nanoferrofluidsKarthickRKarthickR.

Department of Physics

Dindigul–624622

Department of Physics

Dindigul–624622

karthickr4584@gmail.comRamachandranK.RamachandranK.

School of Physics

Madurai–625021

School of Physics

Madurai–625021

thirumalchandran@gmail.comSrinivasanR.SrinivasanR

Department of Physic

Madurai–625009

Department of Physic

Madurai–625009

rsrini2067@yahoo.co.inPSNA College of Engineering and TechnologyИндияPSNA College of Engineering and TechnologyIndiaMadurai Kamaraj UniversityИндияMadurai Kamaraj UniversityIndiaThiagarajar CollegeИндияThiagarajar CollegeIndia20162208202574624628Copyright © Karthick R., Ramachandran K., Srinivasan r., 20252025Karthick R., Ramachandran K., Srinivasan R.Karthick R., Ramachandran K., Srinivasan r.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/1268

Zinc doped cobalt ferriteCo1−xZnxFe2O4 nanoparticles (x = 0.1,  0.5, 0.9) were synthesized by chemical co-precipitation method. The crystallite size, which was calculated from the full width half maximum (FWHM) value of the strongest peak (311) plane using Scherer approximation, was found to decrease with higher zinc content. The surface morphology of the powder samples was obtained using transmission electron microscopy (TEM). Magnetic properties, such as Saturation magnetization (Ms), Remanent Magnetization (Mr ) and Coercivity of the powder samples, were measured using Vibrating Sample Magnetometer (VSM) at room temperature and were found to decrease with increased zinc content.  Aqueous ferrofluids prepared from the powder samples were subjected to magnetic field to measure their Faraday rotation. Faraday rotation of the ferrofluids was found to increase with applied magnetic field and decrease with increasing zinc composition.

Zinc doped cobalt ferriteCo1−xZnxFe2O4 nanoparticles (x = 0.1,  0.5, 0.9) were synthesized by chemical co-precipitation method. The crystallite size, which was calculated from the full width half maximum (FWHM) value of the strongest peak (311) plane using Scherer approximation, was found to decrease with higher zinc content. The surface morphology of the powder samples was obtained using transmission electron microscopy (TEM). Magnetic properties, such as Saturation magnetization (Ms), Remanent Magnetization (Mr ) and Coercivity of the powder samples, were measured using Vibrating Sample Magnetometer (VSM) at room temperature and were found to decrease with increased zinc content.  Aqueous ferrofluids prepared from the powder samples were subjected to magnetic field to measure their Faraday rotation. Faraday rotation of the ferrofluids was found to increase with applied magnetic field and decrease with increasing zinc composition.

nanoferrofluidvibrating sample magnetometerfaraday rotationnanoferrofluidvibrating sample magnetometerfaraday rotationReferencesIbrahim Sharifi, Shokrollai H., Amiri S. Ferrite based magnetic nanofluids used in hyperthermia applications. Journal of Magnetism and Magnetic Materials, 2012, 324(6), P. 903–915.Ibrahim Sharifi, Shokrollai H., Amiri S. Ferrite based magnetic nanofluids used in hyperthermia applications. Journal of Magnetism and Magnetic Materials, 2012, 324(6), P. 903–915.Masajada J., Bacia M., Drobczyn´ski S. Cluster formation in ferrofluids induced by holographic optical tweezers. Optics Letters, 2013, 38(19), P. 3910–3913.Masajada J., Bacia M., Drobczyn´ski S. Cluster formation in ferrofluids induced by holographic optical tweezers. Optics Letters, 2013, 38(19), P. 3910–3913.Bhatt H., Patel R. Optical transport in bidispersed magnetic colloids with varying refractive index. Journal of nanofluids, 2013, 2(3), P. 188–193.Bhatt H., Patel R. Optical transport in bidispersed magnetic colloids with varying refractive index. Journal of nanofluids, 2013, 2(3), P. 188–193.Mahendran V., Philip J. Nanofluid based optical sensor for rapid visual inspection of defects in ferromagnetic materials. Applied Physics Letters, 2012, 100(7), P. 073104.Mahendran V., Philip J. Nanofluid based optical sensor for rapid visual inspection of defects in ferromagnetic materials. Applied Physics Letters, 2012, 100(7), P. 073104.Fan C.Z., Wang G., Huang J.P. Magnetocontrollable photonic crystals based on colloidal ferrofluids. Journal of Applied Physics, 2008, 103(9), P. 094107.Fan C.Z., Wang G., Huang J.P. Magnetocontrollable photonic crystals based on colloidal ferrofluids. Journal of Applied Physics, 2008, 103(9), P. 094107.Duncan P.D., Camp P.J. Aggregation kinetics and the nature of phase separation in two-dimensional dipolar fluids. Physical Review Letters, 2006, 97(10), P. 107202.Duncan P.D., Camp P.J. Aggregation kinetics and the nature of phase separation in two-dimensional dipolar fluids. Physical Review Letters, 2006, 97(10), P. 107202.Ukai T., Maekawa T. Patterns formed by paramagnetic particles in a horizontal layer of a magnetorheological fluid subjected to a dc magnetic field. Physical Review E, 2004, 69(3), P. 032501.Ukai T., Maekawa T. Patterns formed by paramagnetic particles in a horizontal layer of a magnetorheological fluid subjected to a dc magnetic field. Physical Review E, 2004, 69(3), P. 032501.Regmi R., Black C., Sudakar C., Keyes P.H., Naik R., Lawes G., Vaishnava P., Rablau C., Kahn D., Lavoie M., Garg V.K., Oliveira A.C. Effects of fatty acid surfactants on the magnetic and magnetohydrodynamic properties of ferrofluids. Journal of Applied Physics, 2009, 106(11), P. 113902.Regmi R., Black C., Sudakar C., Keyes P.H., Naik R., Lawes G., Vaishnava P., Rablau C., Kahn D., Lavoie M., Garg V.K., Oliveira A.C. Effects of fatty acid surfactants on the magnetic and magnetohydrodynamic properties of ferrofluids. Journal of Applied Physics, 2009, 106(11), P. 113902.Brojabasi S., Muthukumaran T., Laskar J.M., John Philip. The effect of suspended Fe3O4 nanoparticle size on magneto-optical properties of ferrofluids. Optics Communications, 2015, 336, P. 278–285.Brojabasi S., Muthukumaran T., Laskar J.M., John Philip. The effect of suspended Fe3O4 nanoparticle size on magneto-optical properties of ferrofluids. Optics Communications, 2015, 336, P. 278–285.Amighian J., Karimzadeh E., Mozaffri M. The effect on Mn2+ substitution on magnetic properties of MnxFe3−xO4 nanoparticles prepared by coprecipitation method. Journal of Magnetism and Magnetic Materials, 2013, 332, P. 157–162.Amighian J., Karimzadeh E., Mozaffri M. The effect on Mn2+ substitution on magnetic properties of MnxFe3−xO4 nanoparticles prepared by coprecipitation method. Journal of Magnetism and Magnetic Materials, 2013, 332, P. 157–162.Yin H., Too H.P., Chow G.M. The effects of particle size and Surface coating on the cytotoxicity of nickel ferrite. Biomaterials, 2005, 26(29), P. 5818–5826.Yin H., Too H.P., Chow G.M. The effects of particle size and Surface coating on the cytotoxicity of nickel ferrite. Biomaterials, 2005, 26(29), P. 5818–5826.VijayaBhasker Reddy P., Ramesh B., GopalReddy Ch. Electrical conductivity and dielectric properties of zinc substituted lithium ferrites prepared by sol-gel method. Physica B, 2010, 405(7), P. 1852–1856.VijayaBhasker Reddy P., Ramesh B., GopalReddy Ch. Electrical conductivity and dielectric properties of zinc substituted lithium ferrites prepared by sol-gel method. Physica B, 2010, 405(7), P. 1852–1856.Woo K., Lee H.J., Ahn J.P., Park Y.S. Sol-gel mediated synthesis of Fe2O3 naorods. Advanced Materials, 2003, 15(20), P. 1761–1764.Woo K., Lee H.J., Ahn J.P., Park Y.S. Sol-gel mediated synthesis of Fe2O3 naorods. Advanced Materials, 2003, 15(20), P. 1761–1764.Bragg W.H. The Structure of magnetite and the Spinels. Nature, 1915, 95(2386), P. 561.Bragg W.H. The Structure of magnetite and the Spinels. Nature, 1915, 95(2386), P. 561.BehshidBehdafar, Ahmad Kermanpur, HojjatSadeghi-Aliabadi, Maria del Puerto Morales, MortezaMozaffari. Synthesis of aqueous fer- rofluids of ZnxFe3−xO4 nanoparticles by citric acid assisted hydrothermal-reduction route for magnetic hyperthermia applications. Journal of Magnetism and Magnetic Materials, 2012, 324(14), P. 2211–2217.BehshidBehdafar, Ahmad Kermanpur, HojjatSadeghi-Aliabadi, Maria del Puerto Morales, MortezaMozaffari. Synthesis of aqueous fer- rofluids of ZnxFe3−xO4 nanoparticles by citric acid assisted hydrothermal-reduction route for magnetic hyperthermia applications. Journal of Magnetism and Magnetic Materials, 2012, 324(14), P. 2211–2217.VeenaGopalan E., Al-Omari I.A., Malini K.A., Joy P.A., Sakthi Kumar D., Yasuhiko Yoshida, Anantharaman M.R. Impact of zinc substitution on the structural and magnetic properties of chemically derived nanosized manganese zinc mixed ferrites. Journal of Magnetism and Magnetic Materials, 2009, 321(8), P. 1092–1099.VeenaGopalan E., Al-Omari I.A., Malini K.A., Joy P.A., Sakthi Kumar D., Yasuhiko Yoshida, Anantharaman M.R. Impact of zinc substitution on the structural and magnetic properties of chemically derived nanosized manganese zinc mixed ferrites. Journal of Magnetism and Magnetic Materials, 2009, 321(8), P. 1092–1099.Yu¨ksel Ko¨seogˇlu. Structural, magnetic, electrical and dielectric properties of MnxNi1−xFe2O4 spinel nanoferrites prepared by PEG assisted hydrothermal method. Ceramics International, 2013, 39(4), P. 4221–4230.Yu¨ksel Ko¨seogˇlu. Structural, magnetic, electrical and dielectric properties of MnxNi1−xFe2O4 spinel nanoferrites prepared by PEG assisted hydrothermal method. Ceramics International, 2013, 39(4), P. 4221–4230.Lo´pez J., Gonza´lez-Bahamo´n L.F., Prado J., Caicedo J.C., Zambrano G., Go´mez M.E., Esteve J., Prieto P. Study of magnetic and structural properties of ferrofluids based on cobalt-zinc ferrite nanoparticles. Journal of Magnetism and Magnetic Materials, 2012, 324(4), P. 394–402.Lo´pez J., Gonza´lez-Bahamo´n L.F., Prado J., Caicedo J.C., Zambrano G., Go´mez M.E., Esteve J., Prieto P. Study of magnetic and structural properties of ferrofluids based on cobalt-zinc ferrite nanoparticles. Journal of Magnetism and Magnetic Materials, 2012, 324(4), P. 394–402.Vaidyanathan G., Sendhilnathan S., Arulmurugan R. Structural and magnetic properties of Co1−xZnxFe2O4 nanoparticles by co- precipitation method. Journal of Magnetism and Magnetic Materials, 2007, 313(2), P. 293–299.Vaidyanathan G., Sendhilnathan S., Arulmurugan R. Structural and magnetic properties of Co1−xZnxFe2O4 nanoparticles by co- precipitation method. Journal of Magnetism and Magnetic Materials, 2007, 313(2), P. 293–299.Yeongll Kim, Don Kim, Choong Sub Lee. Synthesis and characterization of CoFe2O4 magnetic nanoparticles prepared by temperature- controlled coprecipitation method. Physica B: Condensed Matter, 2003, 337(1-4), P. 42–51.Yeongll Kim, Don Kim, Choong Sub Lee. Synthesis and characterization of CoFe2O4 magnetic nanoparticles prepared by temperature- controlled coprecipitation method. Physica B: Condensed Matter, 2003, 337(1-4), P. 42–51.Mathew D.S., Juang R.S. An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions. Chemical Engineering Journal, 2007, 129(1-3), P. 51–65.Mathew D.S., Juang R.S. An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions. Chemical Engineering Journal, 2007, 129(1-3), P. 51–65.Prashant K. Jain, Yanhong Xiao. Ronald Walsworth and Adam E. Cohen. Surface Plasmon resonance enhanced magneto-optics (SuPREMO): Faraday rotation enhancement in gold coated iron oxide nanocrystals. Nano Letters, 2009, 9(4), P. 1644–1650.Prashant K. Jain, Yanhong Xiao. Ronald Walsworth and Adam E. Cohen. Surface Plasmon resonance enhanced magneto-optics (SuPREMO): Faraday rotation enhancement in gold coated iron oxide nanocrystals. Nano Letters, 2009, 9(4), P. 1644–1650.Choi K.H. Magnetic behavior of Fe3O4 nanostructure fabricated by template method. Journal of Magnetism and Magnetic Materials, 2007, 310(2), P. e861–e863.Choi K.H. Magnetic behavior of Fe3O4 nanostructure fabricated by template method. Journal of Magnetism and Magnetic Materials, 2007, 310(2), P. e861–e863.

The authors declare that there are no conflicts of interest present.