<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">najo-1318</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PAPERS, PRESENTED AT MAM-12</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>PAPERS, PRESENTED AT MAM-12</subject></subj-group></article-categories><title-group><article-title>Electrofabrication of nanostructured multilayer coatings for better corrosion protection</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Vaishaka</surname><given-names>R. R.</given-names></name></name-alternatives><bio xml:lang="en"><p>Electrochemistry Research Laboratory, Department of Chemistry</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Hegde</surname><given-names>A. C.</given-names></name></name-alternatives><bio xml:lang="en"><p>Electrochemistry Research Laboratory, Department of Chemistry</p></bio><email xlink:type="simple">hegdeac@rediffmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>National Institute of Technology Karnataka, Surathkal&#13;
Srinivasnagar</institution><country>India</country></aff><pub-date pub-type="collection"><year>2013</year></pub-date><pub-date pub-type="epub"><day>21</day><month>08</month><year>2025</year></pub-date><volume>4</volume><issue>3</issue><fpage>409</fpage><lpage>416</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Vaishaka R.R., Hegde A.C., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Vaishaka R.R., Hegde A.C.</copyright-holder><copyright-holder xml:lang="en">Vaishaka R.R., Hegde A.C.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/1318">https://nanojournal.ifmo.ru/jour/article/view/1318</self-uri><abstract><p>In an effort to improve the corrosion resistance of monolayer Zn-Ni alloy coatings, nanostructure multilayer coating (NMC) has been developed using a pulsed current. Successive layers of alloys with alternately changing compositions were deposited on mild steel (MS) by making the cathode current cycle between two values during deposition. Multilayer coatings with different configurations in terms of composition and number of layers were developed and their corrosion behaviors were studied by electrochemical methods. The effect of cyclic cathode current densities (CCCD’s), and the number of layers have been studied, and coating configurations have been optimized for highest corrosion resistances. Multilayer coatings and their degradation during corrosion were confirmed by Scanning Electron Microscopy (SEM) analysis. The improved corrosion resistance of NMC in relation to monolayer alloy coatings, deposited from same bath has been analyzed and results were discussed in terms of increased number of interfaces due to layering.</p></abstract><kwd-group xml:lang="en"><kwd>Zn-Ni alloy</kwd><kwd>Multilayer alloy</kwd><kwd>Corrosion study</kwd><kwd>SEM and XRD</kwd></kwd-group><funding-group><funding-statement xml:lang="en">Mr. Vaishaka R. Rao acknowledges National Institute of Technology Karnataka (NITK), Surathkal for supporting this research in the form of Institute Fellowship.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">J.Fei, G.D.Wilcox. Electrodeposition of zinc-nickel compositionally modulated multilayer coatings and their corrosion behaviours. Surf. Coat. Technol, 200, P. 3533–3539 (2006).</mixed-citation><mixed-citation xml:lang="en">J.Fei, G.D.Wilcox. Electrodeposition of zinc-nickel compositionally modulated multilayer coatings and their corrosion behaviours. Surf. Coat. Technol, 200, P. 3533–3539 (2006).</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">A.Maciej, G.Nawrat, W.Simka, J.Piotrowski. Formation of compositionally modulated Zn-Ni alloy coatings on steel. Mater. Chem. Phys, 132, P. 1095–1102 (2012).</mixed-citation><mixed-citation xml:lang="en">A.Maciej, G.Nawrat, W.Simka, J.Piotrowski. Formation of compositionally modulated Zn-Ni alloy coatings on steel. Mater. Chem. Phys, 132, P. 1095–1102 (2012).</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">M.R.Kalantary, G.D.Wilcox, D.R.Gabe. The production of compositionally modulated alloys by simulated high speed Electrodeposition from a single bath solution. Electrochim. Acta, 40, P. 1609–1616 (1995).</mixed-citation><mixed-citation xml:lang="en">M.R.Kalantary, G.D.Wilcox, D.R.Gabe. The production of compositionally modulated alloys by simulated high speed Electrodeposition from a single bath solution. Electrochim. Acta, 40, P. 1609–1616 (1995).</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">W.Blum. The structure and properties of alternately deposited metals. Trans Am Electrochem Soc, 40, P. 307– 320 (1921).</mixed-citation><mixed-citation xml:lang="en">W.Blum. The structure and properties of alternately deposited metals. Trans Am Electrochem Soc, 40, P. 307– 320 (1921).</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">A.Brenner. Electrodeposition of Alloy. Academic Press, New York (1963).</mixed-citation><mixed-citation xml:lang="en">A.Brenner. Electrodeposition of Alloy. Academic Press, New York (1963).</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">M.Rahsepar, M.E.Bahrololoom. Corrosion study of Ni/Zn compositionally modulated multilayer coatings using electrochemical impedance spectroscopy. Corros. Sci, 51, P. 2537–2543 (2009).</mixed-citation><mixed-citation xml:lang="en">M.Rahsepar, M.E.Bahrololoom. Corrosion study of Ni/Zn compositionally modulated multilayer coatings using electrochemical impedance spectroscopy. Corros. Sci, 51, P. 2537–2543 (2009).</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">F.Jing-yin, L.Guo-zheng, X.Wen-li, W.Wei-kang. Compositionally Modulated Multilayer Coatings. J. Iron. Steel Res. Int, 13 (4), P. 61–67 (2006).</mixed-citation><mixed-citation xml:lang="en">F.Jing-yin, L.Guo-zheng, X.Wen-li, W.Wei-kang. Compositionally Modulated Multilayer Coatings. J. Iron. Steel Res. Int, 13 (4), P. 61–67 (2006).</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">I.Kirilova, I.Ivanov. Corrosion behaviour of Zn-Co compositionally modulated multilayers electrodeposited from single and dual baths. J. Appl. Electrochem, 29, P. 1133–1137 (1999).</mixed-citation><mixed-citation xml:lang="en">I.Kirilova, I.Ivanov. Corrosion behaviour of Zn-Co compositionally modulated multilayers electrodeposited from single and dual baths. J. Appl. Electrochem, 29, P. 1133–1137 (1999).</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">I.Kirilova, I.Ivanov, St.Rashkov. Anodic behaviour of composition modulated Zn-Co multilayers electrode- posited from single and dual baths. J. Appl. Electrochem, 28, P. 1359–1363 (1998).</mixed-citation><mixed-citation xml:lang="en">I.Kirilova, I.Ivanov, St.Rashkov. Anodic behaviour of composition modulated Zn-Co multilayers electrode- posited from single and dual baths. J. Appl. Electrochem, 28, P. 1359–1363 (1998).</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">D.Tench, J.White. Tensile Properties of Nanostructured Ni-Cu Multilayered Materials Prepared by Electrode- position. J. Electrochem. Soc, 138, P. 3757–3758 (1991).</mixed-citation><mixed-citation xml:lang="en">D.Tench, J.White. Tensile Properties of Nanostructured Ni-Cu Multilayered Materials Prepared by Electrode- position. J. Electrochem. Soc, 138, P. 3757–3758 (1991).</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">V.Thangaraj, K.Ravishankar, A.C.Hegde. Surface modification by compositionally modulated multilayered Zn-Fe alloy coatings. Chin. J. Chem, 26, P. 1–10 (2008).</mixed-citation><mixed-citation xml:lang="en">V.Thangaraj, K.Ravishankar, A.C.Hegde. Surface modification by compositionally modulated multilayered Zn-Fe alloy coatings. Chin. J. Chem, 26, P. 1–10 (2008).</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">V.Thangaraj, N.Eliaz, A.C.Hegde. Corrosion behavior of composition modulated multilayer Zn-Co electrode- posits produced using a single-bath technique. J. Appl. Electrochem, 39, P. 339–345 (2009).</mixed-citation><mixed-citation xml:lang="en">V.Thangaraj, N.Eliaz, A.C.Hegde. Corrosion behavior of composition modulated multilayer Zn-Co electrode- posits produced using a single-bath technique. J. Appl. Electrochem, 39, P. 339–345 (2009).</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">S.Yogesha, A.C.Hegde. Optimization of deposition conditions for development of high corrosion resistant Zn-Fe multilayer coatings. J. Mater. Process. Technol, 211, P. 1409–1415 (2011).</mixed-citation><mixed-citation xml:lang="en">S.Yogesha, A.C.Hegde. Optimization of deposition conditions for development of high corrosion resistant Zn-Fe multilayer coatings. J. Mater. Process. Technol, 211, P. 1409–1415 (2011).</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">P.Ganesan, S.P.Kumaraguru, B.N.Popov. Development of compositionally modulated multilayer Zn-Ni de- posits as replacement for cadmium. Surf. Coat. Technol, 201, P. 7896–7904 (2007).</mixed-citation><mixed-citation xml:lang="en">P.Ganesan, S.P.Kumaraguru, B.N.Popov. Development of compositionally modulated multilayer Zn-Ni de- posits as replacement for cadmium. Surf. Coat. Technol, 201, P. 7896–7904 (2007).</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">C.Bories, J.P.Bonino, A.Rousset. Structure and thermal stability of zinc-nickel electrodeposits. J. Appl. Elec- trochem, 29, P. 1045–1051 (1999).</mixed-citation><mixed-citation xml:lang="en">C.Bories, J.P.Bonino, A.Rousset. Structure and thermal stability of zinc-nickel electrodeposits. J. Appl. Elec- trochem, 29, P. 1045–1051 (1999).</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
