najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2023-14-2-202-207najo-132Research ArticlePHYSICSФИЗИКАInvestigation of stability of composite Nafion/nanocarbon materialИсследование стабильности композита Nafion/наноуглеродный материалhttps://orcid.org/0000-0003-4519-0111ГлебоваН. В.GlebovaN. V.

Nadezhda V. Glebova

26 Politechnicheskaya str., St. Petersburg, 194021

glebova@mail.ioffe.ruhttps://orcid.org/0000-0002-2746-6762МазурА. С.MazurA. S.

Anton S. Mazur

7-9 Universitetskaya emb., St. Petersburg, 199034

a.mazur@spbu.ruhttps://orcid.org/0000-0001-6709-5559КрасноваА. О.KrasnovaA. O.

Anna O. Krasnova

26 Politechnicheskaya str., St. Petersburg, 194021

krasnova@mail.ioffe.ruhttps://orcid.org/0000-0002-6707-6216ПлешаковИ. В.PleshakovI. V.

Ivan V. Pleshakov

26 Politechnicheskaya str., St. Petersburg, 194021

inanple@yandex.ruhttps://orcid.org/0000-0002-9895-6822НечитайловА. А.NechitailovA. A.

Andrey A. Nechitailov

26 Politechnicheskaya str., St. Petersburg, 194021

aan.shuv@mail.ioffe.ruIoffe InstituteRussian FederationSt. Petersburg State UniversityRussian Federation202303062025142202207Copyright © Glebova N.V., Mazur A.S., Krasnova A.O., Pleshakov I.V., Nechitailov A.A., 20252025Глебова Н.В., Мазур А.С., Краснова А.О., Плешаков И.В., Нечитайлов А.А.Glebova N.V., Mazur A.S., Krasnova A.O., Pleshakov I.V., Nechitailov A.A.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/132

The article presents the results of a study of inorganic-polymer nanocomposites Nafion/thermally expanded graphite and Nafion/carbon black by nuclear magnetic resonance and thermogravimetry. The struc ture of carbon materials was characterized by electron microscopy and adsorption structural analysis by low temperature nitrogen adsorption. The presence of the interaction of Nafion polymer and carbon material at the interface between the components leading to thermal stabilization of the composites is shown, and the differences between thermally expanded graphite and carbon black due to their morphology during interaction with Nafion are discussed.

В статье представлены результаты исследования неоргано-полимерных нанокомпозитов Nafion/терморасширенный графит и Nafion/углеродная сажа методами ядерного магнитного резонанса и термогравиметрии. Структура углеродных материалов охарактеризована с помощью электронной микроскопии и адсорбционного структурного анализа методом низкотемпературной адсорбции азота. Показано наличие взаимодействия полимера Nafion и углеродного материала на границе контакта компонентов, приводящего к термостабилизации композитов, обсуждаются различия между терморасширенным графитом и сажей, обусловленные их морфологией при взаимодействии с Nafion.

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The authors declare that there are no conflicts of interest present.