najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМОnajo-1381Research ArticlePAPERS, PRESENTED AT MAM-12PAPERS, PRESENTED AT MAM-12Miscibility studies of PVC/PMMA blends in Tetrahydrofuran by viscosity, density, refractive index and ultrasonic velocity methodSahGautam Kumar

University Department of Chemistry (Physical Chemistry section)

Darbhanga

gautamdar@gmail.comGuptaAshok Kumar

University Department of Chemistry (Physical Chemistry section)

Darbhanga

ashokkumargupta80@gmail.comLalit Narayan Mithila UniversityIndia20132208202542288293Copyright © Sah G.K., Gupta A.K., 20252025Sah G.K., Gupta A.K.Sah G.K., Gupta A.K.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/1381

The density and Coefficient of Viscosity for Polyvinyl chloride/poly(methyl methacrylate)(PVC/PMMA)blends in tetrahydrofuran at 303.15 K and 313.15 K were measured. These measured parameters were then used to estimate few other related physical quantities like Huggin’s constants and the interaction parameters μ and α proposed by Chee and Sun et al. to identify the molecular interaction arising in the mentioned polymer blend solutions. The peculiar deviation confirms the structural changes in the solution of blends.

viscositypolymer blendspoly(methyl methacrylate)poly (vinyl chloride)molecular interac tionReferencesStephen A.M., Kumar T.P., Renganathan N.G., Pitchumani S., Thirunakaran R., Muniyandi N. Ionic conductivity and FT-IR studies on plasticized PVC/PMMA blend polymer electrolytes. J.Power Sources, 89(1), P. 80-87 (2000).Stephen A.M., Kumar T.P., Renganathan N.G., Pitchumani S., Thirunakaran R., Muniyandi N. Ionic conductivity and FT-IR studies on plasticized PVC/PMMA blend polymer electrolytes. J.Power Sources, 89(1), P. 80-87 (2000).Subban R.H.Y., Arof A.K. Plasticizer interactions with polymer and salt in PVC–LiCF3SO3–DMF electrolytes. Eur. Polym. J., 40(8), P. 1841–1847 (2004).Subban R.H.Y., Arof A.K. Plasticizer interactions with polymer and salt in PVC–LiCF3SO3–DMF electrolytes. Eur. Polym. J., 40(8), P. 1841–1847 (2004).Sun Z., Wang W., Feng Z. Criterion of polymer-polymer miscibility determined by viscometry. Eur. Polym. J., 28(10), P. 1259–1261 (1992). Tang M., Liau W.R. Solvent effect on the miscibility of poly(4 hydroxystyrene)–poly(ethylene oxide) blends. Eur. Polym. J., 36(12), P. 2597–2603 (2000).Sun Z., Wang W., Feng Z. Criterion of polymer-polymer miscibility determined by viscometry. Eur. Polym. J., 28(10), P. 1259–1261 (1992). Tang M., Liau W.R. Solvent effect on the miscibility of poly(4 hydroxystyrene)–poly(ethylene oxide) blends. Eur. Polym. J., 36(12), P. 2597–2603 (2000).Chee, Sun et al., Sun Z., Wang W., Feng Z. Criterion of polymer-polymer miscibility determined by viscometry. Eur. Polym. J., 28(10), P. 1259–1261 (1992).Chee, Sun et al., Sun Z., Wang W., Feng Z. Criterion of polymer-polymer miscibility determined by viscometry. Eur. Polym. J., 28(10), P. 1259–1261 (1992).Wu W., Luo X., Ma D. Miscibility of the segmented polyurethane blends with chlorinated poly(vinyl chloride). Eur. Polym. J., 35(6), P. 985–990 (1999).Wu W., Luo X., Ma D. Miscibility of the segmented polyurethane blends with chlorinated poly(vinyl chloride). Eur. Polym. J., 35(6), P. 985–990 (1999).Zhao Y., Prud’homme R.E. A nonradiative energy transfer fluorescence spectroscopy study of poly (vinylchloride)/poly (methyl methacrylate) blends. Polym Bull, 26(1), P. 101 (1991).Zhao Y., Prud’homme R.E. A nonradiative energy transfer fluorescence spectroscopy study of poly (vinylchloride)/poly (methyl methacrylate) blends. Polym Bull, 26(1), P. 101 (1991).Honeycutt J.D. A Theoretical study of tacticity effects on poly(vinylchloride) poly(methyl methacrylate) miscibility. Macromolecules, 27(19), P. 5377–5381 (1994).Honeycutt J.D. A Theoretical study of tacticity effects on poly(vinylchloride) poly(methyl methacrylate) miscibility. Macromolecules, 27(19), P. 5377–5381 (1994).Karlou K., Schneider H.A. DSC and PVT study of PVC/PMMA blends. J. Therm. Anal. Calorim., 59(1–2), P. 59 (2000).Karlou K., Schneider H.A. DSC and PVT study of PVC/PMMA blends. J. Therm. Anal. Calorim., 59(1–2), P. 59 (2000).Oh B., Kim Y.R. (1999). Evaluation and characteristics of a blend polymer for a solid polymer elec trolyte. Solid state Ionics, 124(1-2). P. 83–89.Oh B., Kim Y.R. (1999). Evaluation and characteristics of a blend polymer for a solid polymer elec trolyte. Solid state Ionics, 124(1-2). P. 83–89.Ohno N., Kumanotani J. Synthesis and Physical Properties of Blends of Donor Polymers from 2-(p Dimethylaminobenzyl)-1,3- propanediol and Acceptor Polymers from 2-(3,5-Dinitrobenzyl)-1,3- propane diol: A New Phase Composed of Donor and AcceptorPolymers. Polym J., 11(12), P. 947–954 (1979).Ohno N., Kumanotani J. Synthesis and Physical Properties of Blends of Donor Polymers from 2-(p Dimethylaminobenzyl)-1,3- propanediol and Acceptor Polymers from 2-(3,5-Dinitrobenzyl)-1,3- propane diol: A New Phase Composed of Donor and AcceptorPolymers. Polym J., 11(12), P. 947–954 (1979).Singh R.P., Paladhi R. Miscibility and interaction studies on some aqueous polymer blend solutions by ultrasonic and rheological techniques. J. Appl. Polym. Sci., 51(9), P. 1559–1565 (1994).Singh R.P., Paladhi R. Miscibility and interaction studies on some aqueous polymer blend solutions by ultrasonic and rheological techniques. J. Appl. Polym. Sci., 51(9), P. 1559–1565 (1994).Paul D.R., Newman S. Polymer blends, vol. 1. Academic Press, New York (1978).Paul D.R., Newman S. Polymer blends, vol. 1. Academic Press, New York (1978).Pingping Z., Haiyang Y., Yiming Z. Viscosity behavior of incompatible poly(vinyl chloride) (PVC)/polystyrene (PS) blends in various solvents. Eur Polym J, 35(5), P. 915–921 (1999).Pingping Z., Haiyang Y., Yiming Z. Viscosity behavior of incompatible poly(vinyl chloride) (PVC)/polystyrene (PS) blends in various solvents. Eur Polym J, 35(5), P. 915–921 (1999).

The authors declare that there are no conflicts of interest present.