najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2018-9-1-125-128najo-1417Research ArticleСтатьиFacile synthesis of 2D carbon structures as a filler for polymer compositesVoznyakovskiiA. P.

St. Petersburg

NeverovskayaA. Yu.

St. Petersburg

OtvalkoJa. A.

St. Petersburg

GorelovaE. V.

St. Petersburg

ZabelinaA. N.

St. Petersburg

S. V. Lebedev Research Institute of Synthetic RubberRussian Federation20182408202591125–128Copyright © Voznyakovskii A.P., Neverovskaya A.Y., Otvalko J.A., Gorelova E.V., Zabelina A.N., 20252025Voznyakovskii A.P., Neverovskaya A.Y., Otvalko J.A., Gorelova E.V., Zabelina A.N.Voznyakovskii A.P., Neverovskaya A.Y., Otvalko J.A., Gorelova E.V., Zabelina A.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/1417

The method of self-propagating high-temperature synthesis has been employed to prepare 2D graphene structures (SHS-graphSHS procedure for carbonizing cyclic organic structures is a simple accessible method for making 2D graphene structures in practically needed amounts. The material obtained is designated as SHS-graphene. The study on starch carbonization product by combined complementary methods has shown the structure of SHS-graphene particles is similar to 2–3-layered graphene particles. The addition of graphene to NBR matrix results in the significant (to twice) enhancement of strength and thermal characteristics of composition material obtained, as compared to unfilled rubber.ene). A set of complementary methods (scanning electron microscopy, Raman microscopy, X-ray diffraction analysis) evidenced 2–3-layer graphene structure of the substance obtained. SHS-graphene has been utilized to modify NBR and thereby markedly strengthen the polymer matrix.

graphenenitrile-butadiene rubberself-propagating high-temperature synthesisReferencesStarch in food: structure, function and applications, ed. by Ann-Charlotte Eliasson. CRC Press, Cambridge: Woodhead Pub., 2004, 605 p.Starch in food: structure, function and applications, ed. by Ann-Charlotte Eliasson. CRC Press, Cambridge: Woodhead Pub., 2004, 605 p.Jin Dingfeng, Yang Xiao, Zhang Ming, Hong Bo, Jin Hongxiao, Peng Xiaoling, Li Jing, Ge Hongliang, Wang Xinqing, Wang Zhengbao, Lou Hui. A novel high surface area spherical carbon from cassava starch. Mater. Lett., 2015, 139, P. 262–264.Jin Dingfeng, Yang Xiao, Zhang Ming, Hong Bo, Jin Hongxiao, Peng Xiaoling, Li Jing, Ge Hongliang, Wang Xinqing, Wang Zhengbao, Lou Hui. A novel high surface area spherical carbon from cassava starch. Mater. Lett., 2015, 139, P. 262–264.Sytschev A.E., Merzhanov A.G. Self-propagating high-temperature synthesis of nanomaterials. Rus. Chem. Rev., 2004, 73, P. 147–159.Sytschev A.E., Merzhanov A.G. Self-propagating high-temperature synthesis of nanomaterials. Rus. Chem. Rev., 2004, 73, P. 147–159.Shuck C.E., Manukyan K.V., Rouvimov S., Rogachev A.S., Mukasyan A.S. Solid-flame: Experimental validation. Combust. Flame, 2016, 163, P. 487–493.Shuck C.E., Manukyan K.V., Rouvimov S., Rogachev A.S., Mukasyan A.S. Solid-flame: Experimental validation. Combust. Flame, 2016, 163, P. 487–493.Merzhanov A.G. History and Recent Developments in SHS. Ceramics International, 1995, 21, P. 371–379.Merzhanov A.G. History and Recent Developments in SHS. Ceramics International, 1995, 21, P. 371–379.Stankovich S., Dikin D.A., Piner R.D., Kohlhaas K.A., Kleinhammes A., Jia Y., Ruoff R.S. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon, 2007, 45(7), P. 1558–1565.Stankovich S., Dikin D.A., Piner R.D., Kohlhaas K.A., Kleinhammes A., Jia Y., Ruoff R.S. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon, 2007, 45(7), P. 1558–1565.Ferrari A.C., Basko D.M. Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat. Nanotechnol., 2013, 8(4), P. 235–246.Ferrari A.C., Basko D.M. Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat. Nanotechnol., 2013, 8(4), P. 235–246.Kim H., Abdala A.A., Macosko C.W. Graphene/Polymer Nanocomposites. Macromolecules, 2010, 43(16), P. 6515–6530.Kim H., Abdala A.A., Macosko C.W. Graphene/Polymer Nanocomposites. Macromolecules, 2010, 43(16), P. 6515–6530.

The authors declare that there are no conflicts of interest present.