najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2023-14-2-254-263najo-151Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХStructural and magnetic study of Tb3+ doped zinc ferrite by sol-gel auto-combustion techniqueСтруктурные и магнитные исследования допированного Tb3+ феррита цинка, полученного методом автовзгорания геляhttps://orcid.org/0000-0002-9393-5619ДжамдадеШ. Г.JamdadeSh. G.

Shrinivas G. Jamdade – Department of Physics

Pune

hvjamdade@yahoo.comhttps://orcid.org/0000-0002-2108-7067ТамбадеП. С.TambadeP. S.

Popat S. Tambade – Department of Physics, Prof. Ramkrishna More Arts

Akurdi, Pune

pstam3@rediffmail.comhttps://orcid.org/0000-0003-2357-9791РатодС. М.RathodS. M.

Sopan M. Rathod – Department of Physics

Pune

smragc@rediffmail.comNowrosjee Wadia CollegeIndiaCommerce and Science CollegeIndiaAbasaheb Garware CollegeIndia202303062025142254263Copyright © Jamdade S.G., Tambade P.S., Rathod S.M., 20252025Джамдаде Ш.Г., Тамбаде П.С., Ратод С.М.Jamdade S.G., Tambade P.S., Rathod S.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/151

In this study, the influence of Tb3+ substitution in zinc ferrite is reported. ZnTbxFe(2-x)O4 (x = 0, 0025, 005, 0075, 01, 0125, and 015) were prepared using sol-gel auto-combustion technique. All the samples were sintered at 400 C for 4 hours. The structure has been studied using XRD, FTIR, UV-visible, and VSM. X-ray diffraction evaluation demonstrates formation of spinel ferrite with nano size distribution. Vibrating sample magnetometer was used to study the magnetic properties of the samples. It was found that as terbium content increases, the coercive field decreases while the saturation magnetization increases. The Tb3+ doped nano crystalline zinc ferrites show ferrimagnetic behavior. FTIR analysis show the presence of two expected bands attributed to tetrahedral and octahedral metal oxygen vibrations at 320 and 450 cm -1.

Статья посвящена исследованию влиянии введения Tb3+ на свойства феррита цинка. ZnTbxFe(2-x)O4 (x = 0, 0,025, 0,05, 0,075, 0,1, 0,125 и 0,15) получали методом автосжигания геля. Все полученные образцы подвергались термообработке при температуре 400°С в течение 4 часов. Структура и свойства были изучены с помощью методов рентгеновской дифракции, ИК- и УФ-спектроскопии и вибрационной магнитометрии. Методом рентгеновской дифракции показано образование нанокристаллов феррита цинка со структурой шпинели. Для исследования магнитных свойств образцов использовался вибрационный магнитометр. Установлено, что с увеличением содержания Tb3+ в системе приводит к уменьшению коэрцитивной силы и увеличению намагниченности насыщения. Нанокристаллический феррит цинка, легированный Tb3+, демонстрирует ферримагнитные свойства. Анализ методом ИК-спектроскопии показывает наличие двух полос, относящихся к колебаниям связи металла-кислород в тетраэдрическом и октаэдрическом окружении - при 320 см-1 и 450 см-1.

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The authors declare that there are no conflicts of interest present.