najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2024-15-6-755-767najo-158Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХThe role of non-autonomous phases in the formation and transformation of solid-phase oxide systemsРоль неавтономных фаз в формировании и трансформации твёрдофазных оксидных системhttps://orcid.org/0000-0002-6132-4178АльмяшеваО. В.AlmjashevaO. V.

Oksana V. Almjasheva

199034, St. Petersburg

almjasheva@mail.ruBranch of Petersburg Nuclear Physics Institute named by B.P. Konstantinov of National Research Centre “Kurchatov Institute” – Institute of Silicate ChemistryRussian Federation202405062025156755767Copyright © Almjasheva O.V., 20252025Альмяшева О.В.Almjasheva O.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/158

It is shown that the nature of processes in oxide solid-phase systems, primarily in nanosized ones, is determined by the behavior of the substance in a non-autonomous state. The composition of non-autonomous phases, the temperature of transition of non-autonomous phases to a liquid-like state, the equilibrium (locally equilibrium) and metastable thickness of non-autonomous phases, and the viscosity of the liquid-like non-autonomous phase are considered as the main parameters of non-autonomous phases.

Показано, что характер процессов в оксидных твёрдофазных системах, прежде всего в наноразмерных, определяется поведением вещества в неавтономном состоянии. В качестве основных параметров неавтономных фаз, рассмотрены состав неавтономных фаз, температура перехода неавтономных фаз в жидко-подобное состояние, равновесная (локально-равновесная) и метастабильная толщина неавтономных фаз, вязкость жидко-подобной неавтономной фазы.

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The authors declare that there are no conflicts of interest present.