najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2025-16-6-872-886najo-1626Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХThe relationship between the impregnation solution composition and the active component distribution NiMo/ZSM-23 catalysts for the plant lipids hydroprocessingВзаимосвязь между составом пропиточного раствора и распределением активных компонентов катализаторов NiMo/ZSM-23 для гидрообработки растительных липидовhttps://orcid.org/0000-0003-3558-4918КовалевскаяК. С.KovalevskayaK. S.

Ksenia S. Kovalevskaya

Akademika Lavrentieva av. 5, 630090, Novosibirsk

shinkevich@catalysis.ruhttps://orcid.org/0000-0001-8124-352XКукушкинР. Г.KukushkinR. G.

Roman G. Kukushkin

Akademika Lavrentieva av. 5, 630090, Novosibirsk

roman@catalysis.ruЗаикинаО. О.ZaikinaO. O.

Olesya O. Zaikina

Akademika Lavrentieva av. 5, 630090, Novosibirsk

omironenko@catalysis.ruhttps://orcid.org/0000-0001-5944-2629БулавченкоО. А.BulavchenkoO. A.

Olga A. Bulavchenko

Akademika Lavrentieva av. 5, 630090, Novosibirsk

isizy@catalysis.ruhttps://orcid.org/0000-0001-5015-3521ЯковлевВ. А.YakovlevV. A.

Vadim A. Yakovlev

Akademika Lavrentieva av. 5, 630090, Novosibirsk

yakovlev@catalysis.ruBoreskov Institute of Catalysis SB RASRussian Federation202506012026166872886Copyright © Kovalevskaya K.S., Kukushkin R.G., Zaikina O.O., Bulavchenko O.A., Yakovlev V.A., 20262026Ковалевская К.С., Кукушкин Р.Г., Заикина О.О., Булавченко О.А., Яковлев В.А.Kovalevskaya K.S., Kukushkin R.G., Zaikina O.O., Bulavchenko O.A., Yakovlev V.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/1626

The nature of the interaction between metals and a catalyst support is a crucial factor in determining the dispersed state of active component phases. In this study, a series of Ni-Mo/ZSM-23 catalysts for the hydroprocessing of plant lipids was prepared by incipient wetness impregnation. The catalysts were prepared by a different sequence of metal deposition and using various complexing agents. The catalysts were investigated by a few physico-chemical methods (TPR, UV-Vis spectroscopy, XRD, TPD-NH3, Raman spectroscopy, HRTEM). It was found that the charge of the ZSM-23 zeolite surface (positive/negative) and the type of metal ions in the impregnation solution affect the formation of phases on the support surface. The use of ammonia impregnating solutions leads to the formation of phases NiO, α-NiMoO4 and β-NiMoO4. In the case of using aqueous and citrate impregnating solutions, only the formation of NiO and β-NiMoO4 phases is observed.

Характер взаимодействия между металлами и носителем катализатора является решающим фактором, определяющим дисперсное состояние фаз активных компонентов. В этом исследовании была получена серия катализаторов NiMo/ZSM-23 путем пропитки по влагоёмкости для гидрообработки растительных липидов. Катализаторы были получены с использованием различной последовательности нанесения металлов и с использованием различных комплексообразователей. Катализаторы были исследованы несколькими физико-химическими методами (ТПВ, УФ-Вид спектроскопия, РФА, TПД-NH3, Рамановская спектроскопия, ПЭМ ВР). Было обнаружено, что заряд поверхности цеолита ZSM-23 (положительный/отрицательный) и тип ионов металлов в растворе для пропитки влияют на образование фаз на поверхности носителя. Использование аммиачных пропитывающих растворов приводит к образованию фаз NiO, α-NiMoO4 и β-NiMoO4.В случае использования водных и цитратных пропитывающих растворов наблюдается только образование фаз NiO и β-NiMoO4.

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The authors declare that there are no conflicts of interest present.