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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2025-16-6-887-896</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-1627</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMISTRY AND MATERIALS SCIENCE</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЯ И НАУКА О МАТЕРИАЛАХ</subject></subj-group></article-categories><title-group><article-title>MXene based electrocatalysts for efficient water splitting</article-title><trans-title-group xml:lang="ru"><trans-title>Электрокатализаторы на основе MXene для эффективного расщепления воды</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0004-2222-2461</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Маманазиров</surname><given-names>Д.</given-names></name><name name-style="western" xml:lang="en"><surname>Mamanazirov</surname><given-names>J.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Джавлонбек Маманазиров</p></bio><bio xml:lang="en"><p>Javlonbek Mamanazirov</p><p>Chingiz Aytmatov 2B St., Tashkent, 100084; Bodomzor Yuli 2B St., Tashkent, 100084</p></bio><email xlink:type="simple">j.mamanazirov@imssolar.uz</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-9694-4430</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Маматкулов</surname><given-names>Ш.</given-names></name><name name-style="western" xml:lang="en"><surname>Mamatkulov</surname><given-names>Sh.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Шавкат Маматкулов</p></bio><bio xml:lang="en"><p>Shavkat Mamatkulov</p><p>Chingiz Aytmatov 2B St., Tashkent, 100084; Mirzo Ulug’bek district, Qori Niyaziy street 39, Tashkent, 100000</p></bio><email xlink:type="simple">mi-shavkat@yandex.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Джумаева</surname><given-names>М.</given-names></name><name name-style="western" xml:lang="en"><surname>Jumayeva</surname><given-names>M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Махфуза Джумаева</p></bio><bio xml:lang="en"><p>Maxfuza Jumayeva</p><p>Chingiz Aytmatov 2B St., Tashkent, 100084</p></bio><email xlink:type="simple">m.jumayeva1988@gmail.com</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-1805-9089</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Бутанов</surname><given-names>Х.</given-names></name><name name-style="western" xml:lang="en"><surname>Butanov</surname><given-names>Kh.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Хакимжан Бутанов</p></bio><bio xml:lang="en"><p>Khakimjan Butanov</p><p>Chingiz Aytmatov 2B St., Tashkent, 100084</p></bio><email xlink:type="simple">kh.butanov@gmail.com</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-7673-7274</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Хэ</surname><given-names>В.</given-names></name><name name-style="western" xml:lang="en"><surname>He</surname><given-names>Wen</given-names></name></name-alternatives><bio xml:lang="ru"><p>Вэнь Хэ</p></bio><bio xml:lang="en"><p>Wen He</p><p>Hefei, 230601</p></bio><email xlink:type="simple">hewen@ahu.edu.cn</email><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-2486-6357</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Лоу</surname><given-names>Ц.</given-names></name><name name-style="western" xml:lang="en"><surname>Low</surname><given-names>Jingxiang</given-names></name></name-alternatives><bio xml:lang="ru"><p>Цзинсян Лоу</p></bio><bio xml:lang="en"><p>Jingxiang Low</p><p>Tianjin, 300387, P.R.</p></bio><email xlink:type="simple">jxlow@ustc.edu.cn</email><xref ref-type="aff" rid="aff-5"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-7494-3445</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Парпиев</surname><given-names>О.</given-names></name><name name-style="western" xml:lang="en"><surname>Parpiev</surname><given-names>Odilhuja</given-names></name></name-alternatives><bio xml:lang="ru"><p>Одилхуджа Парпиев</p></bio><bio xml:lang="en"><p>Odilhuja Parpiev</p><p>Chingiz Aytmatov 2B St., Tashkent, 100084</p></bio><email xlink:type="simple">o.parpiev@imssolar.uz</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-9186-9080</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Рузимурадов</surname><given-names>О.</given-names></name><name name-style="western" xml:lang="en"><surname>Ruzimuradov</surname><given-names>Olim</given-names></name></name-alternatives><bio xml:lang="ru"><p>Олим Рузимурадов</p></bio><bio xml:lang="en"><p>Olim Ruzimuradov</p><p>Tashkent, 100095</p></bio><email xlink:type="simple">o.ruzimuradov@new.polito.uz</email><xref ref-type="aff" rid="aff-6"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="en">Institute of Materials Science, Uzbekistan Academy of Sciences; National Research Institute of Renewable Energy Sources, Ministry of Energy<country>Uzbekistan</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="en">Institute of Materials Science, Uzbekistan Academy of Sciences; &#13;
Institute of Fundamental and Applied Research under TIIAME National Research University<country>Uzbekistan</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="en">Institute of Materials Science, Uzbekistan Academy of Sciences<country>Uzbekistan</country></aff></aff-alternatives><aff-alternatives id="aff-4"><aff xml:lang="en">School of Materials Science and Engineering, Anhui University<country>China</country></aff></aff-alternatives><aff-alternatives id="aff-5"><aff xml:lang="en">School of Physical Science and Technology, Tiangong University<country>China</country></aff></aff-alternatives><aff-alternatives id="aff-6"><aff xml:lang="en">Turin Polytechnic University in Tashkent<country>Uzbekistan</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>06</day><month>01</month><year>2026</year></pub-date><volume>16</volume><issue>6</issue><fpage>887</fpage><lpage>896</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Mamanazirov J., Mamatkulov S., Jumayeva M., Butanov K., He W., Low J., Parpiev O., Ruzimuradov O., 2026</copyright-statement><copyright-year>2026</copyright-year><copyright-holder xml:lang="ru">Маманазиров Д., Маматкулов Ш., Джумаева М., Бутанов Х., Хэ В., Лоу Ц., Парпиев О., Рузимурадов О.</copyright-holder><copyright-holder xml:lang="en">Mamanazirov J., Mamatkulov S., Jumayeva M., Butanov K., He W., Low J., Parpiev O., Ruzimuradov O.</copyright-holder><license license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/1627">https://nanojournal.ifmo.ru/jour/article/view/1627</self-uri><abstract><p>In this study, we modified Ni based electrodes with MXene and MXene-based composite catalysts for water splitting. The MXene based catalyst exhibited excellent electrochemical surface area (ECSA) of 1840 cm2 , highlighting its abundant active sites. To further enhance catalytic activity, MXene was modified with graphene oxide (GO) and carbon black (CB), which significantly reduced the overpotential from 300 mV to 196 mV at 10 mA cm−2 and improved the reaction kinetics, as evidenced by a low Tafel slope of 96.35 mV dec−1 . Moreover, the MXene–GO–CB composite demonstrated outstanding long-term durability, maintaining stable operation for 50 h at 100 mA cm−2 with only a 34 mV increase in overpotential at 10 mA cm−2 . These results confirm that the synergistic combination of MXene with GO and CB yields a highly active and durable electrocatalyst, offering strong potential for practical water electrolysis applications.</p></abstract><trans-abstract xml:lang="ru"><p>В этом исследовании мы модифицировали электроды на основе Ni с помощью MXene и композитных катализаторов на основе MXene для расщепления воды. Катализатор на основе MXene продемонстрировал превосходную электрохимическую площадь поверхности (ECSA) 1840 см², что подчеркивает его обилие активных центров. Для дальнейшего повышения каталитической активности MXene был модифицирован оксидом графена (GO) и сажей (CB), что значительно снизило перенапряжение с 300 мВ до 196 мВ при 10 мА см⁻² и улучшило кинетику реакции, о чем свидетельствует низкий наклон Тафеля 96,35 мВ dec⁻¹. Более того, композит MXene–GO–CB продемонстрировал выдающуюся долговременную долговечность, сохраняя стабильную работу в течение 50 ч при 100 мА см⁻² с увеличением перенапряжения всего на 34 мВ при 10 мА см⁻². Эти результаты подтверждают, что синергетическое сочетание MXene с GO и CB дает высокоактивный и долговечный электрокатализатор, обладающий большим потенциалом для практического применения в электролизе воды.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>композиты на основе MXene</kwd><kwd>HER</kwd><kwd>OER</kwd><kwd>электрокатализаторы</kwd></kwd-group><kwd-group xml:lang="en"><kwd>MXene based composites</kwd><kwd>HER</kwd><kwd>OER</kwd><kwd>electrocatalysts</kwd></kwd-group><funding-group xml:lang="en"><funding-statement>The authors gratefully acknowledge the support of the Agency of Innovative Development under the Ministry of Higher Education, Science and Innovation of the Republic of Uzbekistan within the framework of research project No. ALM-20230502808. 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