najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2024-15-5-710-715najo-168Research ArticleCHEMISTRY AND MATERIAL SCIENCEХИМИЯ И МАТЕРИАЛОВЕДЕНИЕSynthesis of CdSTe nanoparticles by laser ablationСинтез наночастиц CdSTe методом лазерной абляцииДжафаровМ. А.JafarovMaarif A.

Маариф Джафаров, заведующей кафедры «Химическая физика наноматериалов», проф. кафедры «Физика полупроводников» физического факультета

AZ1148 Баку

Maarif A. Jafarov

AZ1148 Baku

maarif.jafarov@mail.ruhttps://orcid.org/0000-0002-8826-4419СалмановВ. М.SalmanovVagif M.

Вагиф Салманов, заведующей кафедры «Физика полупроводников» физического факультета

AZ1148 Баку

Vagif M. Salmanov

AZ1148 Baku

vagif_salmanov@yahoo.comhttps://orcid.org/0000-0003-3672-8899MaмeдовР. М.MamedovRovshan М.

Ровшан Мамедов, доц. кафедры «Физика полупроводников» физического факультета

AZ1148 Баку

Rovshan M. Mamedov

AZ1148 Baku

poluprovod@rambler.ruНасировЭ. Ф.NasirovElshan F.

Эльшан  Насиров, Старший научный сотрудник лаборатории «Физика полупроводников» Института «Физических проблем»

AZ1148 Баку

Elshan F. Nasirov

AZ1148 Baku

el.nasir@mail.ruМамедоваТ. А.MammadovaTurana A.

Турана Мамедова, аспирант кафедры «Физика полупроводников» физического факультета

AZ1148 Баку

Turana A. Mammadova

AZ1148 Baku

turka.memmedova@gmail.comБакинский государственный университетBaku State University202403062025155710715Copyright © Jafarov M.A., Salmanov V.M., Mamedov R.М., Nasirov E.F., Mammadova T.A., 20252025Джафаров М.А., Салманов В.М., Maмeдов Р.М., Насиров Э.Ф., Мамедова Т.А.Jafarov M.A., Salmanov V.M., Mamedov R.М., Nasirov E.F., Mammadova T.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/168

Synthesis of CdSTe nanoparticles using CdCl2, Na2S2O3 and TeO2 solutions under the action of laser radiation was experimentally studied. The radiation source was a pulsed Nd:YAG laser with built-in generators of the 2nd and 3rd harmonics, designed to generate radiation with a wavelength of 1064, 532, and 335 nm. The laser pulse duration was 10 ns with an energy of 135 mJ per pulse. In a colloidal solution, the formation of nanoparticles with a diameter of 10 to 50 nm was observed. X-ray diffraction analysis established that the crystal structure of the nanoparticles is the same as that of the bulk material (hexagonal). It is shown that the photoluminescence emission of the obtained nanoparticles has a green color (∼560 nm) and is associated with the radiative recombination of free excitons.

Экспериментально исследован синтез наночастиц CdSTe с использованием растворов CdCl2, Na2S2O3 и TeO2 под действием лазерного излучения. Источником излучения служил импульсный Nd:YAG-лазер со встроенными генераторами 2-й и 3-й гармоник, рассчитанный на генерацию излучения с длиной волны 1064, 532 и 335 нм. Длительность лазерного импульса составляла 10 нс при энергии в импульсе 135 мДж. В коллоидном растворе наблюдалось образование наночастиц диаметром от 10 до 50 нм. Рентгеноструктурным анализом установлено, что кристаллическая структура наночастиц такая же, как и у объемного материала (гексагональная). Показано, что фотолюминесцентное излучение полученных наночастиц имеет зеленый цвет (~560 нм) и связано с излучательной рекомбинацией свободных экситонов. 

наночастицы CdSTeлазерная абляцияфотолюминесценцияCdSTe nanoparticleslaser ablationphotoluminescenceReferencesSemaltianos N.G., Logothetidis S., Perrie W., Romani S., Potter R.J., Sharp M., Dearden G. and Watkins K.G. CdSTe nanoparticles synthesized by laser ablation. Applied physics letters, 2009, 95, P. 033301–033306.Semaltianos N.G., Logothetidis S., Perrie W., Romani S., Potter R.J., Sharp M., Dearden G. and Watkins K.G. CdSTe nanoparticles synthesized by laser ablation. Applied physics letters, 2009, 95, P. 033301–033306.afarov M.A., Nasirov E.F., Jahangirova S.A., Jafarli R. NanoZnS thin films for solar cell. Nanosystems: physics, chemistry, mathematics, 2015, 6(5), P. 644–649.afarov M.A., Nasirov E.F., Jahangirova S.A., Jafarli R. NanoZnS thin films for solar cell. Nanosystems: physics, chemistry, mathematics, 2015, 6(5), P. 644–649.Jafarov M.A., Nasirov E.F., Mammadov R., Jafarli R. Fabrication and characterization ZnCdS nanowire. Nanosystems: physics, chemistry, mathematics, 2014, 5(6), P. 796–802.Jafarov M.A., Nasirov E.F., Mammadov R., Jafarli R. Fabrication and characterization ZnCdS nanowire. Nanosystems: physics, chemistry, mathematics, 2014, 5(6), P. 796–802.Bulqakov A.V. Yevtushenko A.B., Shukhov Yu.Q., Ozerov I., Marin V. Quantum electronics, 2010, 40(11), 1021–1033.Bulqakov A.V. Yevtushenko A.B., Shukhov Yu.Q., Ozerov I., Marin V. Quantum electronics, 2010, 40(11), 1021–1033.Jafarov M.A., Nasirov E.F. Nanoscale Structures based on the Zn1−xCdxS. Nanosystems: physics, chemistry, mathematics, 2013, 4(5), P. 680– 689.Jafarov M.A., Nasirov E.F. Nanoscale Structures based on the Zn1−xCdxS. Nanosystems: physics, chemistry, mathematics, 2013, 4(5), P. 680– 689.Morales-Acevado A. Thin film CdS/CdSTe solar cells: research perspectives. Solar Energy, 2006, 80, 675 p.Morales-Acevado A. Thin film CdS/CdSTe solar cells: research perspectives. Solar Energy, 2006, 80, 675 p.Zweibel K. Engineering. The impact of tellurium supply on cadmium telluride photovoltaics. Science, 2010, 328, 699 p.Zweibel K. Engineering. The impact of tellurium supply on cadmium telluride photovoltaics. Science, 2010, 328, 699 p.Johnsto R.L. Atomic and Molecular Clusters. London: CRC Press, 2002, 256 p.Johnsto R.L. Atomic and Molecular Clusters. London: CRC Press, 2002, 256 p.Smirnov B.M. Generation of cluster beams. Advances in the physical sciences, 2003, 173, P. 609.Smirnov B.M. Generation of cluster beams. Advances in the physical sciences, 2003, 173, P. 609.Makarov Q.N. Extremal processes in clusters in collision with a solid surface. Advances in the physical sciences, 2006, 176, P. 121.Makarov Q.N. Extremal processes in clusters in collision with a solid surface. Advances in the physical sciences, 2006, 176, P. 121.Peng Z.A. and Peng X. Formation of High-Quality CdSTe, CdSe, and CdS Nanocrystals Using CdO as Precursor. J. Am. Chem. Soc., 2001, 123, P. 183.Peng Z.A. and Peng X. Formation of High-Quality CdSTe, CdSe, and CdS Nanocrystals Using CdO as Precursor. J. Am. Chem. Soc., 2001, 123, P. 183.Marc-Oliver Piepenbrock M., Tom Stirner, Mary O’Neill and Stephen M. Kelly. Growth dynamics of CdSTe nanoparticles in liquid and crystalline phases. J. Am. Chem. Soc., 2007, 129, 24, P. 7674.Marc-Oliver Piepenbrock M., Tom Stirner, Mary O’Neill and Stephen M. Kelly. Growth dynamics of CdSTe nanoparticles in liquid and crystalline phases. J. Am. Chem. Soc., 2007, 129, 24, P. 7674.Martin Sharp. CdSTe nanoparticles synthesized by laser ablation. Applied Physics Letters, 2009, 95, P. 033302.Martin Sharp. CdSTe nanoparticles synthesized by laser ablation. Applied Physics Letters, 2009, 95, P. 033302.Albert A.R., John A.Y. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2006, 279, 1-3 P. 121.Albert A.R., John A.Y. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2006, 279, 1-3 P. 121.Patrone L., Nelson D., Safarov V.I., Sentis M., Marine W.J. Photoluminescence of silicon nanoclusters with reduced size dispersion produced by laser ablation. Appl. Phys., 2000, 87, P. 3829.Patrone L., Nelson D., Safarov V.I., Sentis M., Marine W.J. Photoluminescence of silicon nanoclusters with reduced size dispersion produced by laser ablation. Appl. Phys., 2000, 87, P. 3829.Seto T., Orii T., Hirasawa M., Aya N. Fabrication of silicon nanostructured films by deposition of size-selected nanoparticles generated by pulsed laser ablation. Thin Solid Films, 2003, 437, P. 230.Seto T., Orii T., Hirasawa M., Aya N. Fabrication of silicon nanostructured films by deposition of size-selected nanoparticles generated by pulsed laser ablation. Thin Solid Films, 2003, 437, P. 230.Lukyanchuk B., Marine W. On the delay time in photoluminescence of Si-nanoclusters, produced by laser ablation. Appl. Surf. Sci., 2000, 314, P. 154.Lukyanchuk B., Marine W. On the delay time in photoluminescence of Si-nanoclusters, produced by laser ablation. Appl. Surf. Sci., 2000, 314, P. 154.Anisimov S.I., Lukyanchuk B.S. Selected problems of the theory of laser ablation. Advances in the physical sciences, 2002, 172, P. 301.Anisimov S.I., Lukyanchuk B.S. Selected problems of the theory of laser ablation. Advances in the physical sciences, 2002, 172, P. 301.Bulgakov A.V., Ozerov I., Marine W. Silicon clusters produced by femtosecond laser ablation: non-thermal emission and gas-phase condensation. Appl. Phys. A, 2004, 79, P. 1591.Bulgakov A.V., Ozerov I., Marine W. Silicon clusters produced by femtosecond laser ablation: non-thermal emission and gas-phase condensation. Appl. Phys. A, 2004, 79, P. 1591.Xu S., Ziegler J., Nann T.J. Rapid synthesis of highly luminescent InP and InP/ZnS nanocrystals. Mater. Chem., 2008, 18, P. 2653.Xu S., Ziegler J., Nann T.J. Rapid synthesis of highly luminescent InP and InP/ZnS nanocrystals. Mater. Chem., 2008, 18, P. 2653.Ozerov I., Nelson D., Bulgakov A.V., Marine W., Sentis M. Synthesis and laser processing of ZnO nanocrystalline thin films. Appl. Surf. Sci., 2003, 349, P. 212.Ozerov I., Nelson D., Bulgakov A.V., Marine W., Sentis M. Synthesis and laser processing of ZnO nanocrystalline thin films. Appl. Surf. Sci., 2003, 349, P. 212.Neretina S., Mascher P., Hughes R.A., Braidy N., Gong W.H., Britten J.F., Preston J.S., Sochinskii N.V., Dippo P. Evolution of wurtzite CdSTe through the formation of cluster assembled films. Appl. Phys. Lett., 2006, 89, P. 133101.Neretina S., Mascher P., Hughes R.A., Braidy N., Gong W.H., Britten J.F., Preston J.S., Sochinskii N.V., Dippo P. Evolution of wurtzite CdSTe through the formation of cluster assembled films. Appl. Phys. Lett., 2006, 89, P. 133101.JCPDS, International Centre for Diffraction Data, USA, Card Number 15-0770.JCPDS, International Centre for Diffraction Data, USA, Card Number 15-0770.Samuel S. Nanolasers: lasing from nanoscale quantum wires. Int. J. of Nanotechnology, 2004, 1, P. 42–85.Samuel S. Nanolasers: lasing from nanoscale quantum wires. Int. J. of Nanotechnology, 2004, 1, P. 42–85.

The authors declare that there are no conflicts of interest present.