najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2026-17-1-97-106najo-1693Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХSelf-propagating high-temperature synthesis of Zr-based ceramics from Zr–B4C composite powderCамораспространяющийся высокотемпературный синтез керамик на основе циркония из композиционного порошка Zr-B4Chttps://orcid.org/0009-0006-1953-2359ДраникМ. С.DranikM. S.

Maria S.Dranik

Leninskii prosp., 31.4, Moscow, 119071

m.dranik@yandex.ruhttps://orcid.org/0009-0002-3000-8778ЯгудинЛ. Д.YagudinL. D.

Leonid D.Yagudin

Leninskii prosp.,31.4,Moscow,119071

yagudinld@icloud.comhttps://orcid.org/0000-0001-8085-7116МалкинА. И.MalkinA. I.

Alexander I. Malkin

Leninskii prosp., 31.4, Moscow, 119071

mlkn@list.ruhttps://orcid.org/0000-0003-1574-7951ЧижевскаяС. В.ChizhevskayaS. V.

Svetlana V. Chizhevskaya

Miusskayasq., 9,Moscow, 125047

chizhrctu@rambler.ruhttps://orcid.org/0000-0001-7938-0082ЖуковА. В.ZhukovA. V.

Alexander V. Zhukov

Miusskaya sq., 9, Moscow, 125047

lexzhukov@yandex.ruhttps://orcid.org/0000-0002-2892-6054НикифороваГ. Е.NikiforovaG. E.

Galina E. Nikiforova

Leninskii prosp., 31, Moscow, 119991

gen@igic.ras.ruFrumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of SciencesRussian FederationMendeleev University of Chemical TechnologyRussian FederationKurnakov Institute of General and Inorganic Chemistry of the Russian Academy of SciencesRussian Federation20260403202617197106Copyright © Dranik M.S., Yagudin L.D., Malkin A.I., Chizhevskaya S.V., Zhukov A.V., Nikiforova G.E., 20262026Драник М.С., Ягудин Л.Д., Малкин А.И., Чижевская С.В., Жуков А.В., Никифорова Г.Е.Dranik M.S., Yagudin L.D., Malkin A.I., Chizhevskaya S.V., Zhukov A.V., Nikiforova G.E.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/1693

The ZrB2–ZrC ceramic powders were prepared by self-propagating high-temperature synthesis (SHS) using Zr–B4C composite powders as a precursor. Composite powders were obtained by ball milling in hexane (3÷12 min). The structure, morphology, phase and fractional composition were investigated for both composite powders and SHS products. It was found that B4C grains are intensively embedded in Zr, and their distribution in composite particles becomes uniform by 9 min of ball milling. The possible route of the SHS reaction is proposed.

В работе получены керамические порошки ZrB2-ZrC методом самораспространяющегося высокотемпературного синтеза (СВС) из композиционных порошков-прекурсоров Zr-B4C. Композиционные порошки были получены путем механообработки смеси порошков Zr и B4C в планетарной шаровой мельнице в течение 3-12 минут среде гексана. Изучена структура, морфология, фазовый и фракционный состав композиционных порошков-прекурсоров и керамических порошков, полученных методом СВС. Показано, что в процессе механообработки частицы B4C интенсивно внедряются в Zr, достигая равномерного распределения спустя 9 минут обработки. Сделано предположение о возможном механизме СВС.

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The authors declare that there are no conflicts of interest present.