najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2024-15-6-855-866najo-184Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХDevelopment of spectral methods for the analysis of nanocized ferrogarnets of the Y3−xCexFe5−yGayO12 compositionРазработка спектральных методов анализа наноразмерных феррогранатов состава Y3−xCexFe5−yGayO12https://orcid.org/0000-0003-1269-6570КоротковаН. А.KorotkovaN. A.

Короткова Наталья Александровна

Natalia A. Korotkova

Leninskii prosp., 31, Moscow, 119991

natalya.korotkova.95@mail.ruhttps://orcid.org/0000-0002-2242-8572АрхипенкоА. А.ArkhipenkoA. A.

Архипенко Александра Александровна

Alexandra A. Arkhipenko

Leninskii prosp., 31, Moscow, 119991

alexandra622@mail.ruhttps://orcid.org/0000-0003-2707-7975СмирноваМ. Н.SmirnovaM. N.

Смирнова Мария Николаевна

Maria N. Smirnova

Leninskii prosp., 31, Moscow, 119991

smirnovamn@igic.ras.ruhttps://orcid.org/0000-0002-0076-9990БарановскаяВ. Б.BaranovskayaV. B.

Барановская Василиса Борисовна

Vasilisa B. Baranovskaya

Leninskii prosp., 31, Moscow, 119991

baranovskaya@list.ruhttps://orcid.org/0000-0003-4553-1019ДоронинаМ. Н.DoroninaM. S.

Доронина Марина Николаевна

Marina S. Doronina

Leninskii prosp., 31, Moscow, 119991

ms.semenova@gmail.comhttps://orcid.org/0000-0002-2075-1755КецкоВ. А.KetskoV. A.

Кецко Валерий Александрович 

Valerii A. Ketsko

Leninskii prosp., 31, Moscow, 119991

ketsko@igic.ras.ruhttps://orcid.org/0009-0000-2872-2150МарьинаГ. Е.MarinaG. E.

Марьина Галина Евгеньевна 

Galina E. Marina

Leninskii prosp., 31, Moscow, 119991

gelim@mail.ruKurnakov Institute of General and Inorganic Chemistry of the Russian Academy of SciencesRussian Federation202405062025156855866Copyright © Korotkova N.A., Arkhipenko A.A., Smirnova M.N., Baranovskaya V.B., Doronina M.S., Ketsko V.A., Marina G.E., 20252025Короткова Н.А., Архипенко А.А., Смирнова М.Н., Барановская В.Б., Доронина М.Н., Кецко В.А., Марьина Г.Е.Korotkova N.A., Arkhipenko A.A., Smirnova M.N., Baranovskaya V.B., Doronina M.S., Ketsko V.A., Marina G.E.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/184

The study and development of yttrium-iron garnets are in demand and promising when creating materials for integrated optics and magnetic microelectronics. The authors synthesized nanosized cerium-substituted yttrium-iron-gallium garnet of the composition Y3−xCexFe5−yGayO12 (where x = 0.4 – 0.5, and y = 2.4 – 2.6), which is characterized by improved magnetic and optical properties. However, the efficiency of applying this material directly depends on the chemical purity of the source materials, as well as the elemental composition of the intermediate and final products. In this regard, the development of multi-element, selective and accurate methods of analysis is an urgent task. As a result of the studies, methods for spectral analysis of cerium-substituted yttrium-iron-gallium garnet were developed. The conditions for determining target analytes (Mg, Al, Si, Ca, Sc, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Se, Y, Cd, Sn, Te, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Pb) in the materials in question were studied and established using X-ray fluorescence spectrometry (XRF), arc atomic emission spectrometry (AAES) and inductively coupled plasma mass spectrometry (ICP-MS). Approaches to reducing and eliminating the main spectral and non-spectral interferences in the methods studied were proposed. A comprehensive complementary approach to the analytical control of garnets of the Y3−xCexFe5−yGayO12 composition was developed, which ensures high accuracy and relia- bility of the results, and allows one to expand the nomenclature of target analytes and the boundaries of the determined contents.

Исследование и разработка феррогранатов иттрия востребованы и перспективны при создании материалов для интегральной оптики и магнитной микроэлектроники. Авторами работы синтезирован нанокристаллический церий-замещенный иттрий-железо-галлиевый гранат состава Y3-хCeхFe5-yGayO12 (где х = 0.4 – 0.5, а у = 2.4 – 2.6), который отличается улучшенными магнитными и оптическими свойствами. Однако эффективность применения данного материала напрямую зависит от химической чистоты исходных веществ, а также элементного состава промежуточных и конечных продуктов. В связи с этим разработка многоэлементных, селективных и точных методов анализа является актуальной задачей. В результате проведенных исследований разработаны методики спектрального анализа церий-замещенного иттрий-железо-галлиевого граната. Изучены и установлены условия определения целевых аналитов (Mg, Al, Si, Ca, Sc, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Se, Y, Cd, Sn, Te, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Pb) в исследуемых материалах методами ренгенофлуоресцентной спектрометрии (РФА), дуговой атомно-эмиссионной спектрометрии (ДАЭС) и масс-спектрометрии с индуктивно связанной плазмой (МС-ИСП). Предложены подходы к уменьшению и устранению основных спектральных и неспектральных помех в исследуемых методах. Разработан комплексный взаимодополняющий подход к аналитическому контролю гранатов состава Y3-хCeхFe5-yGayO12, что обеспечивает высокую точность и достоверность результатов, позволяет расширить номенклатуру целевых аналитов и границы определяемых содержаний.

Феррогранат иттриярентгенофлуоресцентная спектрометриядуговая атомно-эмиссионная спектрометриямасс-спектрометрия с индуктивно связанной плазмойанализyttrium-iron-gallium garnetX-ray fluorescence spectrometryarc atomic emission spectrometryinductively coupled plasma mass spectrometryanalysisThis research was performed using the equipment of the JRC PMR IGIC RAS and JRC of GIREDMET. This work was supported by the Ministry of Science and Higher Education of the Russian Federation as part of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.ReferencesDehghani D.O., Shokrollahi H., Yang H. The enhancement of the Ce-solubility limit and saturation magnetization in the Ce0.25BixPryY2.75−x−yFe5O12 garnet synthesized by the conventional ceramic method. Ceramics International, 2020, 46(3), P. 2709–2723.Dehghani D.O., Shokrollahi H., Yang H. The enhancement of the Ce-solubility limit and saturation magnetization in the Ce0.25BixPryY2.75−x−yFe5O12 garnet synthesized by the conventional ceramic method. Ceramics International, 2020, 46(3), P. 2709–2723.Shen T., Dai H., Song M., Liu H., Wei X. Structure and Magnetic Properties of Ce-Substituted Yttrium Iron Garnet Prepared by Conventional Sintering Techniques. Journal of Superconductivity and Novel Magnetism, 2017, 30, P. 937–941.Shen T., Dai H., Song M., Liu H., Wei X. Structure and Magnetic Properties of Ce-Substituted Yttrium Iron Garnet Prepared by Conventional Sintering Techniques. Journal of Superconductivity and Novel Magnetism, 2017, 30, P. 937–941.Jung H.K., Kim C.H., Hong A.-R., Lee S.H., Kim T.C., Jang H.S., Kim D.H. Luminescent and magnetic properties of cerium-doped yttrium aluminum garnet and yttrium iron garnet composites. Ceramics International 2019, 45, P. 9846–9851.Jung H.K., Kim C.H., Hong A.-R., Lee S.H., Kim T.C., Jang H.S., Kim D.H. Luminescent and magnetic properties of cerium-doped yttrium aluminum garnet and yttrium iron garnet composites. Ceramics International 2019, 45, P. 9846–9851.Hapishah A.N., Hamidon M.N., Syazwan M.M., Shafiee F.N. Effect of grain size on microstructural and magnetic properties of holmium substituted yttrium iron garnets (Y1.5Ho1.5Fe5O12), Results in Physics, 2019, 14, P. 102391.Hapishah A.N., Hamidon M.N., Syazwan M.M., Shafiee F.N. Effect of grain size on microstructural and magnetic properties of holmium substituted yttrium iron garnets (Y1.5Ho1.5Fe5O12), Results in Physics, 2019, 14, P. 102391.Gota T., Onbasli M.C., Kim D.H., Singh V., Inoue M., Kimerling L.C., Ross C.A. A nonreciprocal racetrack resonator based on vacuum-annealed magnetooptical cerium-substituted yttrium iron garnet. Optics Express, 2014, 22, P. 19047–19054.Gota T., Onbasli M.C., Kim D.H., Singh V., Inoue M., Kimerling L.C., Ross C.A. A nonreciprocal racetrack resonator based on vacuum-annealed magnetooptical cerium-substituted yttrium iron garnet. Optics Express, 2014, 22, P. 19047–19054.Randoshkin V.V., Chervonenkis A.Ya. Applied magneto-optics, Moscow, Energoatomizdat, 1990, 320 p.Randoshkin V.V., Chervonenkis A.Ya. Applied magneto-optics, Moscow, Energoatomizdat, 1990, 320 p.Smirnova M.N., Glazkova I.S., Nikiforova G.E., Kop’eva M.A., Eliseev A.A., Gorbachev E.A., Ketsko V.A. Synthesis of Ce:YIG nanopowder by gel combustion. Nanosystems: Physics, Chemistry, Mathematics, 2021, 12(2), P. 210–217.Smirnova M.N., Glazkova I.S., Nikiforova G.E., Kop’eva M.A., Eliseev A.A., Gorbachev E.A., Ketsko V.A. Synthesis of Ce:YIG nanopowder by gel combustion. Nanosystems: Physics, Chemistry, Mathematics, 2021, 12(2), P. 210–217.Sharm V., Kuanr B.K. Magnetic and crystallographic properties of rare-earth substituted yttrium-iron garnet. Journal of Alloys and Compounds, 2018, 748, P. 591–600.Sharm V., Kuanr B.K. Magnetic and crystallographic properties of rare-earth substituted yttrium-iron garnet. Journal of Alloys and Compounds, 2018, 748, P. 591–600.Bokshyts Y.V., Kichanov S.E., Shevchenko G.P., Tratsiak E.V., Parshikova E.A., Kozlenko D.P. Structure and luminescence properties of (Y1−xLax)3(La1−yGay)O12:Ce+3. Inorganic Materials, 2019, 55(8), P. 820–826.Bokshyts Y.V., Kichanov S.E., Shevchenko G.P., Tratsiak E.V., Parshikova E.A., Kozlenko D.P. Structure and luminescence properties of (Y1−xLax)3(La1−yGay)O12:Ce+3. Inorganic Materials, 2019, 55(8), P. 820–826.Smirnova M.N., Nikiforova G.E., Goeva L.V. One-stage synthesis of (Y0,5Bi0,5)3(Fe0,5Ga0,5)5O12 garnet using the organometallic gel autocombustion approach. Ceramics international, 2018, 45(4), P. 4509–4513.Smirnova M.N., Nikiforova G.E., Goeva L.V. One-stage synthesis of (Y0,5Bi0,5)3(Fe0,5Ga0,5)5O12 garnet using the organometallic gel autocombustion approach. Ceramics international, 2018, 45(4), P. 4509–4513.Smirnova M.N., Nipan G.D., Nikiforova G.E. (Y1−xBix)3(Fe1−yGay)5O12 Solid Solution Region in the Ieneke Diagram, Inorganic materials, 2018, 54(7), P. 683–688.Smirnova M.N., Nipan G.D., Nikiforova G.E. (Y1−xBix)3(Fe1−yGay)5O12 Solid Solution Region in the Ieneke Diagram, Inorganic materials, 2018, 54(7), P. 683–688.Shen T., Dai H., Song M. Structure and Magnetic Properties of Ce-Substituted Yttrium Iron Garnet Prepared by Conventional Sintering Techniques. Journal of Superconductivity and Novel Magnetism, 2017, 30, P. 937–941.Shen T., Dai H., Song M. Structure and Magnetic Properties of Ce-Substituted Yttrium Iron Garnet Prepared by Conventional Sintering Techniques. Journal of Superconductivity and Novel Magnetism, 2017, 30, P. 937–941.Lisnevskaya I.V., Bobrova I.A., Lupeiko T.G. Y3Fe5O12/Na,Bi,Sr-doped PZT particulate magnetoelectric composites. Journal of Magnetism and Magnetic Materials, 2016, 397, P. 86–95.Lisnevskaya I.V., Bobrova I.A., Lupeiko T.G. Y3Fe5O12/Na,Bi,Sr-doped PZT particulate magnetoelectric composites. Journal of Magnetism and Magnetic Materials, 2016, 397, P. 86–95.Huang M., Zhang S. Growth and characterization of cerium-substituted yttrium iron garnet single crystals for magneto-optical applications Applied Physics A, 2002, 74, P. 177–180.Huang M., Zhang S. Growth and characterization of cerium-substituted yttrium iron garnet single crystals for magneto-optical applications Applied Physics A, 2002, 74, P. 177–180.Teterina Yu.A., Smirnova M.N., Maslakov K.I., Teterin A.Yu., Kop’eva M.A., Nikiforova G.E., Ketsko V.A. Ionic and Phase Compositions of Y2.5Ce0.5Fe2.5Ga2.5O12. Ferrogarnet Powder Produced by Gel Combustion. Doklady Physical Chemistry, 2022, 5032, P. 45–49.Teterina Yu.A., Smirnova M.N., Maslakov K.I., Teterin A.Yu., Kop’eva M.A., Nikiforova G.E., Ketsko V.A. Ionic and Phase Compositions of Y2.5Ce0.5Fe2.5Ga2.5O12. Ferrogarnet Powder Produced by Gel Combustion. Doklady Physical Chemistry, 2022, 5032, P. 45–49.Yushchuk S.I., Yuryev S.O., Moklyak V.V. Monocrystalline ferrogarnet films with low magnetizations and small magnetic losses. Materials Today: Proceedings, 2022, 62, P. 5771–5774.Yushchuk S.I., Yuryev S.O., Moklyak V.V. Monocrystalline ferrogarnet films with low magnetizations and small magnetic losses. Materials Today: Proceedings, 2022, 62, P. 5771–5774.Khivintsev Y.V., Sakharov V.K., Kozhevnikov A.V., Dudko G.M., Filimonov Y.A., Khitun A. Spin waves in YIG based magnonic networks: Design and technological aspects. Journal of Magnetism and Magnetic Materials, 2022, 545, P. 168754.Khivintsev Y.V., Sakharov V.K., Kozhevnikov A.V., Dudko G.M., Filimonov Y.A., Khitun A. Spin waves in YIG based magnonic networks: Design and technological aspects. Journal of Magnetism and Magnetic Materials, 2022, 545, P. 168754.Jin L., Jia K., He Y., Wang G., Zhong Z., Zhang H. Pulsed laser deposition grown yttrium-iron-garnet thin films: Effect of composition and iron ion valences on microstructure and magnetic properties. Applied Surface Science, 2019, 483, P. 947–952.Jin L., Jia K., He Y., Wang G., Zhong Z., Zhang H. Pulsed laser deposition grown yttrium-iron-garnet thin films: Effect of composition and iron ion valences on microstructure and magnetic properties. Applied Surface Science, 2019, 483, P. 947–952.Rao Y., Zhang D., Zhang H., Jin L., Yang Q., Zhong Z., Li M., Hong C., Ma B.O. Thickness dependence of magnetic properties in submicron yttrium iron garnet films. Journal Physics D: Applied Physics, 2018, 51(43), P. 435001.Rao Y., Zhang D., Zhang H., Jin L., Yang Q., Zhong Z., Li M., Hong C., Ma B.O. Thickness dependence of magnetic properties in submicron yttrium iron garnet films. Journal Physics D: Applied Physics, 2018, 51(43), P. 435001.Arkhipenko A.A., Koshel E.S., Baranovskaya V.B. Analysis of cerium oxide by arc atomic emission spectrometry. Zavodskaya laboratoriya. Diagnostika materialov, 2021, 87(11), P. 19–25.Arkhipenko A.A., Koshel E.S., Baranovskaya V.B. Analysis of cerium oxide by arc atomic emission spectrometry. Zavodskaya laboratoriya. Diagnostika materialov, 2021, 87(11), P. 19–25.Koshel E.S., Arkhipenko A.A., Baranovskaya V.B.. Lutetium oxide analysis by direct arc atomic emission spectrometry. Analytics and control, 2021, 25(2), P. 70–83.Koshel E.S., Arkhipenko A.A., Baranovskaya V.B.. Lutetium oxide analysis by direct arc atomic emission spectrometry. Analytics and control, 2021, 25(2), P. 70–83.Vasilyeva I.E. Shabanova E.V. Stages of arc atomic emission spectrometry development as applied to the solid geological samples’ analysis. Analytics and Control, 2021, 25(4), P. 280–295.Vasilyeva I.E. Shabanova E.V. Stages of arc atomic emission spectrometry development as applied to the solid geological samples’ analysis. Analytics and Control, 2021, 25(4), P. 280–295.Schramm R. Use of X-ray Fluorescence Analysis for the Determination of Rare Earth Elements. Physical Sciences Reviews, 2016, 1(1), P. 20160061.Schramm R. Use of X-ray Fluorescence Analysis for the Determination of Rare Earth Elements. Physical Sciences Reviews, 2016, 1(1), P. 20160061.Sitko R., Zawisza B., Czaja M. Fundamental parameters method for determination of rare earth elements in apatites by wavelength-dispersive X-ray fluorescence spectrometry. Journal of Analytical Atomic Spectrometry, 2005, 20, P. 741–745.Sitko R., Zawisza B., Czaja M. Fundamental parameters method for determination of rare earth elements in apatites by wavelength-dispersive X-ray fluorescence spectrometry. Journal of Analytical Atomic Spectrometry, 2005, 20, P. 741–745.Bondarenko A.V., Belonovsky A.V., Katsman Ya.M. Application of the method of fundamental parameters in X-ray fluorescence analysis of pulp products of ore enrichment. Mining Industry, 2021, 5-2, P. 84–88Bondarenko A.V., Belonovsky A.V., Katsman Ya.M. Application of the method of fundamental parameters in X-ray fluorescence analysis of pulp products of ore enrichment. Mining Industry, 2021, 5-2, P. 84–88Beckhoff B., Kanngießer B., Langhoff N., Wedell R., Wolff H. Handbook of Practical X-ray Fluorescence Analysis; Part 5 Quantitative Analysis, Berlin/Heidelberg, Springer, 2006, 863 p.Beckhoff B., Kanngießer B., Langhoff N., Wedell R., Wolff H. Handbook of Practical X-ray Fluorescence Analysis; Part 5 Quantitative Analysis, Berlin/Heidelberg, Springer, 2006, 863 p.Karandashev V.K., Orlova T.V., Zybinsky A.M., Kordyukov S.V., Simakov V.A., Kolotov V.P. Analysis of niobium-rare-earth ores by inductively coupled plasma mass spectrometry. Journal of Analytical Chemistry, 2018, 7, P. 364–373.Karandashev V.K., Orlova T.V., Zybinsky A.M., Kordyukov S.V., Simakov V.A., Kolotov V.P. Analysis of niobium-rare-earth ores by inductively coupled plasma mass spectrometry. Journal of Analytical Chemistry, 2018, 7, P. 364–373.Salem D.B., Barrat J.A. Determination of rare earth elements in gadolinium-based contrast agents by ICP-MS. Talanta, 2021, 221, P. 121589.Salem D.B., Barrat J.A. Determination of rare earth elements in gadolinium-based contrast agents by ICP-MS. Talanta, 2021, 221, P. 121589.Korotkova N.A., Baranovskaya V.B., Petrova K.V. Microwave Digestion and ICP-MS Determination of Major and Trace Elements in Waste Sm-Co Magnets. Metals, 2022, 12(8), P. 1308.Korotkova N.A., Baranovskaya V.B., Petrova K.V. Microwave Digestion and ICP-MS Determination of Major and Trace Elements in Waste Sm-Co Magnets. Metals, 2022, 12(8), P. 1308.eiga M., Mattiazzi P., S. de Gois J., Nascimentod P.C., Borgese D.L.G., Bohrer D. Presence of other rare earth metals in gadolinium-based contrast agents. Talanta, 2020, 216, P. 120940.eiga M., Mattiazzi P., S. de Gois J., Nascimentod P.C., Borgese D.L.G., Bohrer D. Presence of other rare earth metals in gadolinium-based contrast agents. Talanta, 2020, 216, P. 120940.Tanner S.D., Baranov V.I., Bandura D.R. Reaction cells and collision cells for ICP-MS: a tutorial review. Spectrochimica Acta Part B, 2002, 57, P. 1361–1452.Tanner S.D., Baranov V.I., Bandura D.R. Reaction cells and collision cells for ICP-MS: a tutorial review. Spectrochimica Acta Part B, 2002, 57, P. 1361–1452.Balaram V. Strategies to overcome interferences in elemental and isotopic geochemical analysis by quadrupole inductively coupled plasma mass spectrometry: A critical evaluation of the recent developments. Rapid Commun Mass Spectrom, 2021, 35, P. e9065.Balaram V. Strategies to overcome interferences in elemental and isotopic geochemical analysis by quadrupole inductively coupled plasma mass spectrometry: A critical evaluation of the recent developments. Rapid Commun Mass Spectrom, 2021, 35, P. e9065.Agatemor C., Beauchemin D. Matrix effects in inductively coupled plasma mass spectrometry: A review. Analytica Chimica Acta, 2011, 706(1), P. 66–83.Agatemor C., Beauchemin D. Matrix effects in inductively coupled plasma mass spectrometry: A review. Analytica Chimica Acta, 2011, 706(1), P. 66–83.Makonnen Y., Beauchemin D. Investigation of a measure of robustness in inductively coupled plasma mass spectrometry. Spectrochimica Acta Part B, 2015, 103–104, P. 57–62.Makonnen Y., Beauchemin D. Investigation of a measure of robustness in inductively coupled plasma mass spectrometry. Spectrochimica Acta Part B, 2015, 103–104, P. 57–62.Korotkova N.A, Petrova K.V., Baranovskaya V.B. Analysis of cerium-substituted yttrium iron garnet by inductively coupled plasma atomic emission spectrometry with preliminary microwave decomposition. Zavodskaya laboratoriya. Diagnostika materialov, 2023, 89(11), P. 24–33.Korotkova N.A, Petrova K.V., Baranovskaya V.B. Analysis of cerium-substituted yttrium iron garnet by inductively coupled plasma atomic emission spectrometry with preliminary microwave decomposition. Zavodskaya laboratoriya. Diagnostika materialov, 2023, 89(11), P. 24–33.Rusanov A.K. Fundamentals of quantitative spectral analysis of ores and minerals, M., Nedra, 1971, 360 p.Rusanov A.K. Fundamentals of quantitative spectral analysis of ores and minerals, M., Nedra, 1971, 360 p.Baranovskaya V.B., Koshel E. Arc atomic emission analysis of rare earth metals and their oxides, M., Technosfera, 132 p.Baranovskaya V.B., Koshel E. Arc atomic emission analysis of rare earth metals and their oxides, M., Technosfera, 132 p.

The authors declare that there are no conflicts of interest present.