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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2022-13-1-115-127</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-223</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>A new approach to function-structure modeling of the surface modified polymers</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Doronin</surname><given-names>F. A.</given-names></name></name-alternatives><email xlink:type="simple">f.a.doronin@mospolytech.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Evdokimov</surname><given-names>A. G.</given-names></name></name-alternatives><email xlink:type="simple">evdokag@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Rudyak</surname><given-names>Yu. V.</given-names></name></name-alternatives><email xlink:type="simple">rudyak@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Rytikov</surname><given-names>G. O.</given-names></name></name-alternatives><email xlink:type="simple">gr-yandex@yandex.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Taranets</surname><given-names>I. P.</given-names></name></name-alternatives><email xlink:type="simple">qwerty818@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Nazarov</surname><given-names>V. G.</given-names></name></name-alternatives><email xlink:type="simple">110505n@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="en">Moscow Polytechnic University<country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="en">Moscow Polytechnic University; State university of management<country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2022</year></pub-date><pub-date pub-type="epub"><day>06</day><month>06</month><year>2025</year></pub-date><volume>13</volume><issue>1</issue><fpage>115</fpage><lpage>127</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Doronin F.A., Evdokimov A.G., Rudyak Y.V., Rytikov G.O., Taranets I.P., Nazarov V.G., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Doronin F.A., Evdokimov A.G., Rudyak Y.V., Rytikov G.O., Taranets I.P., Nazarov V.G.</copyright-holder><copyright-holder xml:lang="en">Doronin F.A., Evdokimov A.G., Rudyak Y.V., Rytikov G.O., Taranets I.P., Nazarov V.G.</copyright-holder><license license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/223">https://nanojournal.ifmo.ru/jour/article/view/223</self-uri><abstract><p>We introduce a novel approach to function-structure modeling of the polymer materials. It’s based on mathematical and statistical processing of the images obtained by scanning electron microscopy (SEM) of the corresponding surfaces. We studied the correlation-rotational anisotropy, the degrees of planar and contour heterogeneity and the morphological spectra of the SEM images to characterize the function-structure relationships quantitatively. The introduced quantitative characteristics will allow to rationalize the choice of chemical compositions of the modifying gas mixtures (for example, helium-fluorine-oxygen) that provide the maximum possible wetting edge angles for the materials under consideration with reference polar and non-polar liquids.</p></abstract><kwd-group xml:lang="en"><kwd>oxyfluorination</kwd><kwd>scanning electron microscopy</kwd><kwd>modification</kwd><kwd>morphology</kwd><kwd>correlation</kwd><kwd>polymer substrate</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang X., Shi F., et al. Superhydrophobic surfaces: From structural control to functional application. J. Mater. Chem., 2008, 18, P. 621-633.</mixed-citation><mixed-citation xml:lang="en">Zhang X., Shi F., et al. Superhydrophobic surfaces: From structural control to functional application. J. Mater. 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