najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2022-13-2-212-219najo-232Research ArticleСтатьиMechanism of formation of nanocrystalline particles with core-shell structure based on titanium oxynitrides with nickel in the process of plasma-chemical synthesis of TiNi in a low-temperature nitrogen plasmaAvdeevaYu. A.y-avdeeva@list.ruLuzhkovaI. V.key703@yandex.ruErmakovA. N.ermakovihim@yandex.ruInstitute of Solid State ChemistryRussian Federation202206062025132212219Copyright © Avdeeva Y.A., Luzhkova I.V., Ermakov A.N., 20252025Avdeeva Y.A., Luzhkova I.V., Ermakov A.N.Avdeeva Y.A., Luzhkova I.V., Ermakov A.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/232

This paper presents the results of experiments, structural and morphological certification and modeling of ultrafine and nanocrystalline TiN-Ni “core-shell“ structures obtained during plasma-chemical synthesis of industrially manufactured microcrystalline TiNi. Experiments on plasma-chemical synthesis were carried out by recondensation of ultrafine and nanocrystalline powders in a rotating cylinder of gaseous nitrogen. X- ray phase analysis and high-resolution transmission electron microscopy (HR TEM) showed the presence of refractory titanium compounds with nitrogen and metallic nickel, which are part of the core-shell structures, including the metastable, highly deformed complex nitride Ti0.7Ni0 . 3N of hexagonal modification. HR TEM studies showed the localization of phases determined by X-ray diffraction and confirmed the “core-shell” structure on the example of nanocrystalline TiN-Ni fraction. Based on the experimental results, we have developed a model of crystallization of TiN-Ni “core-shell“ structures under the conditions of a rotating cylinder of gaseous nitrogen, where the crystallization rate is 105 ◦C/s.

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The authors declare that there are no conflicts of interest present.