najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2022-13-5-503-508najo-262Research ArticleСтатьиOptical anisotropy in fullerene-containing polymer composites induced by magnetic fieldPleshakovI. V.ivanple@yandex.ruProskurinaO. V.proskurinaov@mail.ruGerasimovV. I.viger53@rambler.ruKuz’MinYu. I.iourk@yandex.ruIoffe InstituteRussian FederationIoffe Institute; St. Petersburg State Institute of Technology (Technical University)Russian FederationPeter the Great St. Petersburg Polytechnic UniversityRussian Federation202206062025135503508Copyright © Pleshakov I.V., Proskurina O.V., Gerasimov V.I., Kuz’Min Y.I., 20252025Pleshakov I.V., Proskurina O.V., Gerasimov V.I., Kuz’Min Y.I.Pleshakov I.V., Proskurina O.V., Gerasimov V.I., Kuz’Min Y.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/262

Using water-soluble hydrated fullerenes embedded in a polyvinyl alcohol matrix, samples were obtained that demonstrated the presence of optical anisotropy when they were formed in a magnetic field. Its existence was established in experiments on light scattering in films containing C60(OH)n and C70(OH)m molecules. The mechanism of the effect is presumably associated with the anisotropy of the shape of these molecules.

carbon-containing compositespolymer matricesfullerenefullerenollight scatteringReferencesLiming Dai, Albert W.H. Mau, Xiaoqing Zhang. Synthesis of fullerene- and fullerol-containing polymers. J. Mater. Chem., 1998, 8(2), P. 325-330.Liming Dai, Albert W.H. Mau, Xiaoqing Zhang. Synthesis of fullerene- and fullerol-containing polymers. J. Mater. Chem., 1998, 8(2), P. 325-330.Changchun Wang, Zhi-Xin Guo, Shoukuan Fu, Wei Wu, Daoben Zhu. Polymers containing fullerene or carbon nanotube structures. Prog. Polym. Sci., 2004, 29(11), P. 1079-1141.Changchun Wang, Zhi-Xin Guo, Shoukuan Fu, Wei Wu, Daoben Zhu. Polymers containing fullerene or carbon nanotube structures. Prog. Polym. Sci., 2004, 29(11), P. 1079-1141.Eletskii A.V., Knizhnik A.A., Potapkin B.V., Kenny J.M. Electrical characteristics of carbon nanotube doped composites. Phys. Usp., 2015, 185(3), P. 225-270.Eletskii A.V., Knizhnik A.A., Potapkin B.V., Kenny J.M. Electrical characteristics of carbon nanotube doped composites. Phys. Usp., 2015, 185(3), P. 225-270.Penkova A.V., Acquah S.F.A., Sokolova M.P., Dmitrenko M.E., Toikka A.M. Polyvinyl alcohol membranes modified by low-hydroxylated fullerenol C60(OH)12. J. Memb. Sci., 2015, 491, P. 22-27.Penkova A.V., Acquah S.F.A., Sokolova M.P., Dmitrenko M.E., Toikka A.M. Polyvinyl alcohol membranes modified by low-hydroxylated fullerenol C60(OH)12. J. Memb. Sci., 2015, 491, P. 22-27.Dmitrenko M., Liamin V., Kuzminova A., Mazur A., Lahderanta E., Ermakov S., Penkova A. Novel mixed matrix sodium alginate-fullerenol membranes: development, characterization, and study in pervaporation dehydration of isopropanol. Polymers, 12(4), P. 2020864.Dmitrenko M., Liamin V., Kuzminova A., Mazur A., Lahderanta E., Ermakov S., Penkova A. Novel mixed matrix sodium alginate-fullerenol membranes: development, characterization, and study in pervaporation dehydration of isopropanol. Polymers, 12(4), P. 2020864.Karpunin A.E., Gerasimov V.I., Mazur A.S., Pleshakov I.V., Fofanov Ya.A., Proskurina O.V. NMR investigation of composite material, formed by fullerenol in polymer matrix of polyvinyl alcohol. Proceeding of “International Conference on Electrical Engineering and Photonics (EExPolytech)”. Saint Petersburg (Russia), 22-23 Oct. 2018, IEEE, 2018, P. 168.Karpunin A.E., Gerasimov V.I., Mazur A.S., Pleshakov I.V., Fofanov Ya.A., Proskurina O.V. NMR investigation of composite material, formed by fullerenol in polymer matrix of polyvinyl alcohol. Proceeding of “International Conference on Electrical Engineering and Photonics (EExPolytech)”. Saint Petersburg (Russia), 22-23 Oct. 2018, IEEE, 2018, P. 168.Karpunin A.E., Pleshakov I.V., Proskurina O.V., Gerasimov V.I., Nechitailov A.A., Glebova N.V., Varlamov A.V., Parfenov M.V. Optical study of composite material with nanosized fullerenol inclusions. Journal of Physics: Conference Series, 2019, 1236, P. 012012.Karpunin A.E., Pleshakov I.V., Proskurina O.V., Gerasimov V.I., Nechitailov A.A., Glebova N.V., Varlamov A.V., Parfenov M.V. Optical study of composite material with nanosized fullerenol inclusions. Journal of Physics: Conference Series, 2019, 1236, P. 012012.Li J., Takeuchi A., Ozawa M., Li X., Saigo K., Kitazawa K. C60 fullerol formation catalysed by quaternary ammonium hydroxides. J. Chem. Soc. Chem.Commun., 1993, 23, P. 1784-1785.Li J., Takeuchi A., Ozawa M., Li X., Saigo K., Kitazawa K. C60 fullerol formation catalysed by quaternary ammonium hydroxides. J. Chem. Soc. Chem.Commun., 1993, 23, P. 1784-1785.Bohren C.F., Huffman D.R. Absorption and scattering of light by small particles. John Wiley & Sons, Inc., NY, 1998, 544 p.Bohren C.F., Huffman D.R. Absorption and scattering of light by small particles. John Wiley & Sons, Inc., NY, 1998, 544 p.Keshri S., Tembe B.L. Thermodynamics of hydration of fullerols [C60(OH)n] and hydrogen bond dynamics in their hydration shells. J. Chem. Phys., 2017, 146(7), P. 074501.Keshri S., Tembe B.L. Thermodynamics of hydration of fullerols [C60(OH)n] and hydrogen bond dynamics in their hydration shells. J. Chem. Phys., 2017, 146(7), P. 074501.Pleshakov I.V., Prokof’ev A.V., Bibik E.E., Kuz’min Yu.I. Investigation of structures formed by magnetic fluid nanoparticles in polymer matrices by static light scattering. Nanosystems: Phys. Chem. Math., 2022, 13(3), P. 285-289.Pleshakov I.V., Prokof’ev A.V., Bibik E.E., Kuz’min Yu.I. Investigation of structures formed by magnetic fluid nanoparticles in polymer matrices by static light scattering. Nanosystems: Phys. Chem. Math., 2022, 13(3), P. 285-289.Thomas D., Cebe P. Self-nucleation and crystallization of polyvinyl alcohol. J. Therm. Anal. Calorim., 2017, 127, P. 885-894.Thomas D., Cebe P. Self-nucleation and crystallization of polyvinyl alcohol. J. Therm. Anal. Calorim., 2017, 127, P. 885-894.

The authors declare that there are no conflicts of interest present.