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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2022-13-5-514-524</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-264</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>Formation, structure, composition in the dispersed state, and behavior of nanoparticles heated in the Mg(OH)2-Ni(OH)2 system</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Kotova</surname><given-names>M. E.</given-names></name></name-alternatives><email xlink:type="simple">kotovamaria715@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Maslennikova</surname><given-names>T. P.</given-names></name></name-alternatives><email xlink:type="simple">maslennikova.tp@iscras.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Ugolkov</surname><given-names>V. L.</given-names></name></name-alternatives><email xlink:type="simple">ugolkov.52@gmail.com</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Gusarov</surname><given-names>V. V.</given-names></name></name-alternatives><email xlink:type="simple">victor.v.gusarov@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>I. V. Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences; V. I. Ulyanov St. Petersburg State Electrotechnical University “LETI”</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-2"><institution>I. V. Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2022</year></pub-date><pub-date pub-type="epub"><day>06</day><month>06</month><year>2025</year></pub-date><volume>13</volume><issue>5</issue><fpage>514</fpage><lpage>524</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Kotova M.E., Maslennikova T.P., Ugolkov V.L., Gusarov V.V., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Kotova M.E., Maslennikova T.P., Ugolkov V.L., Gusarov V.V.</copyright-holder><copyright-holder xml:lang="en">Kotova M.E., Maslennikova T.P., Ugolkov V.L., Gusarov V.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/264">https://nanojournal.ifmo.ru/jour/article/view/264</self-uri><abstract><p>The effect of nickel content in Mg1-xNix(OH)2 nanoparticles produced by reverse co-precipitation on their structural characteristics, morphology and size parameters of crystallites and particles has been studied. The plate-shaped nanoparticles were shown to be predominantly single crystals. It has been determined that when the nickel content x in the hydroxide solid solution is not less than 0.4, the particle size sharply decreases and the number of stacking faults increases. The dependence of the dehydration temperature of Mg1-xNix(OH)2 nanoparticles on the nickel content has been revealed.</p></abstract><kwd-group xml:lang="en"><kwd>magnesium hydroxide</kwd><kwd>nickel hydroxide</kwd><kwd>layered double hydroxide</kwd><kwd>nanoparticles</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Koverzanova E.V., Usachev S.V., Shilkina N.G., Lomakin S.M., Gumargalieva K.Z., Zaikov G.E. Specific features of thermal degradation of polypropylene in the presence of magnesium hydroxide.Russian Journal of Applied Chemistry, 2004, 77(3), P. 445-448. https://doi.org/10.1023/B:RJAC.0000031288.62488.04</mixed-citation><mixed-citation xml:lang="en">Koverzanova E.V., Usachev S.V., Shilkina N.G., Lomakin S.M., Gumargalieva K.Z., Zaikov G.E. Specific features of thermal degradation of polypropylene in the presence of magnesium hydroxide.Russian Journal of Applied Chemistry, 2004, 77(3), P. 445-448. https://doi.org/10.1023/B:RJAC.0000031288.62488.04</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Saoud Kh.M., Saeed Sh., Al-Soubaihi R.M., Bertino M.F. Microwave assisted preparation of magnesium hydroxide nano-sheets. American Journal of Nanomaterials, 2014, 2(2), P. 21-25.</mixed-citation><mixed-citation xml:lang="en">Saoud Kh.M., Saeed Sh., Al-Soubaihi R.M., Bertino M.F. Microwave assisted preparation of magnesium hydroxide nano-sheets. American Journal of Nanomaterials, 2014, 2(2), P. 21-25.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Korolev V.A., Samarin E.N., Panfilov V.A., Romanova I.V. Sorption properties of brucite and brucite-based clay mixtures. Ecology and Industry of Russia, 2016, 20(1), P. 18-24. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Korolev V.A., Samarin E.N., Panfilov V.A., Romanova I.V. Sorption properties of brucite and brucite-based clay mixtures. Ecology and Industry of Russia, 2016, 20(1), P. 18-24. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Marchenko L.A., Marchenko L.A. Influence in common-besieged hydroxides on sorption ions of heavy metals.Russian Journal of Sorption and chromatography processes, 2009, 9(6), P. 868-876.</mixed-citation><mixed-citation xml:lang="en">Marchenko L.A., Marchenko L.A. Influence in common-besieged hydroxides on sorption ions of heavy metals.Russian Journal of Sorption and chromatography processes, 2009, 9(6), P. 868-876.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Chanda D.K., Mukherjee D., Das P.S., Ghosh C. Toxic heavy metal ion adsorption kinetics of Mg(OH)2 nanostructures with superb efficacies. Materials Research Express, 2018, 5(7), P. 1-23.</mixed-citation><mixed-citation xml:lang="en">Chanda D.K., Mukherjee D., Das P.S., Ghosh C. Toxic heavy metal ion adsorption kinetics of Mg(OH)2 nanostructures with superb efficacies. Materials Research Express, 2018, 5(7), P. 1-23.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Kang J., Schwendeman S.P.Comparison of the effects of Mg(OH)2 and sucrose on the stability of bovine serum albumin encapsulated in injectable poly(d,l-lactide-co-glycolide) implants. Biomaterials, 2002, 23, P. 239.</mixed-citation><mixed-citation xml:lang="en">Kang J., Schwendeman S.P.Comparison of the effects of Mg(OH)2 and sucrose on the stability of bovine serum albumin encapsulated in injectable poly(d,l-lactide-co-glycolide) implants. Biomaterials, 2002, 23, P. 239.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Henrist C., Mathieu J.-P., et al. Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution. J. Cryst. Growth, 2003, 249, P. 321.</mixed-citation><mixed-citation xml:lang="en">Henrist C., Mathieu J.-P., et al. Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution. J. Cryst. Growth, 2003, 249, P. 321.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Matsukevich I.V., Ruchets A.N., Krutko N.P., et al. Synthesis and adsorption properties of nanostructured powders Mg(OH)2 and MgO. Proceedings of the National Academy of Sciences of Belarus, Chemical series, 2017, 53(4), P. 38-44.</mixed-citation><mixed-citation xml:lang="en">Matsukevich I.V., Ruchets A.N., Krutko N.P., et al. Synthesis and adsorption properties of nanostructured powders Mg(OH)2 and MgO. Proceedings of the National Academy of Sciences of Belarus, Chemical series, 2017, 53(4), P. 38-44.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Maslennikova T.P., Kotova M.E., Lomakin M.S., et al. Role of mixing reagent solutions in the formation of morphological features of nanocrystalline particles of magnesium hydroxide and oxide.Russ. J. Inorg. Chem., 2022, 67, P. 810-819.</mixed-citation><mixed-citation xml:lang="en">Maslennikova T.P., Kotova M.E., Lomakin M.S., et al. Role of mixing reagent solutions in the formation of morphological features of nanocrystalline particles of magnesium hydroxide and oxide.Russ. J. Inorg. Chem., 2022, 67, P. 810-819.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Chen Y., Zhou T., Fang H., et al. A novel preparation of nano-sized hexagonal Mg(OH)2. Procedia Engineering, 2015, 102, P. 388-394.</mixed-citation><mixed-citation xml:lang="en">Chen Y., Zhou T., Fang H., et al. A novel preparation of nano-sized hexagonal Mg(OH)2. Procedia Engineering, 2015, 102, P. 388-394.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Kovalenko V.L., Kotok V.A., Malyshev V.V. Electrochemical obtaining of nickel hydroxide from nickel plating waste water for application in the alkali secondary cells. Theoretical and applied ecology, 2019, 2, P. 108-112.</mixed-citation><mixed-citation xml:lang="en">Kovalenko V.L., Kotok V.A., Malyshev V.V. Electrochemical obtaining of nickel hydroxide from nickel plating waste water for application in the alkali secondary cells. Theoretical and applied ecology, 2019, 2, P. 108-112.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Maslennikova T.P., Gatina E.N., Kotova M.E., Ugolkov V.L., Abiev R.Sh., Gusarov V.V. Formation of chrysotile-structured hydrous magnesium silicate nanoscrolls from nanocrystalline magnesium hydroxide and their thermally stimulated transformation. Inorganic Materials, 2022, In press. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Maslennikova T.P., Gatina E.N., Kotova M.E., Ugolkov V.L., Abiev R.Sh., Gusarov V.V. Formation of chrysotile-structured hydrous magnesium silicate nanoscrolls from nanocrystalline magnesium hydroxide and their thermally stimulated transformation. Inorganic Materials, 2022, In press. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Bloise A., Barrese E., Apollaro C. Hydrothermal alteration of Ti-doped forsterite to chrysotile and characterization of the resulting chrysotile fibers. Neues Jahrbuch fu¨r Mineralogie, 2009, 185, P. 297-304.</mixed-citation><mixed-citation xml:lang="en">Bloise A., Barrese E., Apollaro C. Hydrothermal alteration of Ti-doped forsterite to chrysotile and characterization of the resulting chrysotile fibers. Neues Jahrbuch fu¨r Mineralogie, 2009, 185, P. 297-304.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Yousefi S.R., Ghanbari D., Salavati-Niasari M. Hydrothermal synthesis of nickel hydroxide nanostructures and flame retardant poly vinyl alcohol and cellulose acetate nanocomposites. Journal of Nanostructures, 2016, 6(1), P. 80-85.</mixed-citation><mixed-citation xml:lang="en">Yousefi S.R., Ghanbari D., Salavati-Niasari M. Hydrothermal synthesis of nickel hydroxide nanostructures and flame retardant poly vinyl alcohol and cellulose acetate nanocomposites. Journal of Nanostructures, 2016, 6(1), P. 80-85.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">E.V. Polyakov, R.R. Tsukanov, L.Yu. Buldakova, Yu.V. Kuznetsova, I.V. Volkov, V.P. Zhukov, M.A. Maksimova, A.V. Dmitriev, I.V. Baklanova, O.A. Lipina, A.P. Tyutyunnik Chemical bath precipitation and properties of β-Ni(OH)2 films prepared in aqueous ammoniac solutions.Russ. J. Inorg. Chem., 2022, 67(6), P. 912-920.</mixed-citation><mixed-citation xml:lang="en">E.V. Polyakov, R.R. Tsukanov, L.Yu. Buldakova, Yu.V. Kuznetsova, I.V. Volkov, V.P. Zhukov, M.A. Maksimova, A.V. Dmitriev, I.V. Baklanova, O.A. Lipina, A.P. Tyutyunnik Chemical bath precipitation and properties of β-Ni(OH)2 films prepared in aqueous ammoniac solutions.Russ. J. Inorg. Chem., 2022, 67(6), P. 912-920.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Korytkova E.N., Pivovarova L.N., Drozdova I.A., Gusarov V.V. Synthesis of nanotubular nickel hydrosilicates and nickel-magnesium hydrosilicates under hydrothermal conditions. Glass Physics and Chemistry, 2005, 31(6), P. 797-802.</mixed-citation><mixed-citation xml:lang="en">Korytkova E.N., Pivovarova L.N., Drozdova I.A., Gusarov V.V. Synthesis of nanotubular nickel hydrosilicates and nickel-magnesium hydrosilicates under hydrothermal conditions. Glass Physics and Chemistry, 2005, 31(6), P. 797-802.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Oliva P., Leonardi J., Laurent J.F., Delmas C., Braconnier J.J., Figlarz M., Fievet F., de Guibert A. Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides. J. Power Sources., 1982, 8, P. 229-255.</mixed-citation><mixed-citation xml:lang="en">Oliva P., Leonardi J., Laurent J.F., Delmas C., Braconnier J.J., Figlarz M., Fievet F., de Guibert A. Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides. J. Power Sources., 1982, 8, P. 229-255.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Yan Z., Yu X., Zhang Y., Jia H., Sun Z., Du P. Enhanced visible light-driven hydrogen production from water by a noble-metal-free system containing organic dye-sensitized titanium dioxide loaded with nickel hydroxide as the cocatalyst. Applied Catalysis B: Environmental, 2014, 160-161, P 173-178.</mixed-citation><mixed-citation xml:lang="en">Yan Z., Yu X., Zhang Y., Jia H., Sun Z., Du P. Enhanced visible light-driven hydrogen production from water by a noble-metal-free system containing organic dye-sensitized titanium dioxide loaded with nickel hydroxide as the cocatalyst. Applied Catalysis B: Environmental, 2014, 160-161, P 173-178.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Vidotti M., Torresi R., De Torresi S.I.C. Nickel hydroxide modified electrodes: a review study concerning its structural and electrochemical properties aiming the application in electrocatalysis, electrochromism and secondary batteries. Quim. Nova, 2010, 33, P. 2176-2186.</mixed-citation><mixed-citation xml:lang="en">Vidotti M., Torresi R., De Torresi S.I.C. Nickel hydroxide modified electrodes: a review study concerning its structural and electrochemical properties aiming the application in electrocatalysis, electrochromism and secondary batteries. Quim. Nova, 2010, 33, P. 2176-2186.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Aghazadeh M., Ghaemi M., Sabour B., Dalvand S. Electrochemical preparation of α-Ni(OH)2 ultrafine nanoparticles for high-performance super-capacitors. J. Solid State Electrochem, 2014, 18, P. 1569-1584.</mixed-citation><mixed-citation xml:lang="en">Aghazadeh M., Ghaemi M., Sabour B., Dalvand S. Electrochemical preparation of α-Ni(OH)2 ultrafine nanoparticles for high-performance super-capacitors. J. Solid State Electrochem, 2014, 18, P. 1569-1584.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Gao M., Sheng W., Zhuang Z., Fang Q., Gu S., Jiang J., Yan Y. Efficient water oxidation using nanostructured α-nickel-hydroxide as an electro-catalyst. J. Am. Chem. Soc, 2014, 136, P. 7077-7084.</mixed-citation><mixed-citation xml:lang="en">Gao M., Sheng W., Zhuang Z., Fang Q., Gu S., Jiang J., Yan Y. Efficient water oxidation using nanostructured α-nickel-hydroxide as an electro-catalyst. J. Am. Chem. Soc, 2014, 136, P. 7077-7084.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Cheng H., Su A.D., Li S., Nguyen S.T., Lu L., Lim C.Y.H., Duong H.M. Facile synthesis and advanced performance of Ni(OH)2/CNTs nanoflake composites on supercapacitor applications. Chem. Phys. Lett, 2014, 601, P. 168-173.</mixed-citation><mixed-citation xml:lang="en">Cheng H., Su A.D., Li S., Nguyen S.T., Lu L., Lim C.Y.H., Duong H.M. Facile synthesis and advanced performance of Ni(OH)2/CNTs nanoflake composites on supercapacitor applications. Chem. Phys. Lett, 2014, 601, P. 168-173.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Bode H., Dehmelt K., Witte J. Zur kenntnis der nickelhydroxidelektrode-I.U¨ber das nickel (II)-hydroxidhydrat. Electrochim. Acta, 1966, 11, P. 1079-1087.</mixed-citation><mixed-citation xml:lang="en">Bode H., Dehmelt K., Witte J. Zur kenntnis der nickelhydroxidelektrode-I.U¨ber das nickel (II)-hydroxidhydrat. Electrochim. Acta, 1966, 11, P. 1079-1087.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">McEwen R.S. Crystallographic studies on nickel hydroxide and the higher nickel oxides. J. Phys. Chem, 1971, 75, P. 1782-1789.</mixed-citation><mixed-citation xml:lang="en">McEwen R.S. Crystallographic studies on nickel hydroxide and the higher nickel oxides. J. Phys. Chem, 1971, 75, P. 1782-1789.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Desgranges L., Calvarin G., Chevrier G.Interlayer interactions in Mg(OH)2: A Neutron Diffraction Study of Mg(OH)2. Acta Cryst, 1996, B52, P. 82-86.</mixed-citation><mixed-citation xml:lang="en">Desgranges L., Calvarin G., Chevrier G.Interlayer interactions in Mg(OH)2: A Neutron Diffraction Study of Mg(OH)2. Acta Cryst, 1996, B52, P. 82-86.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Hall D.S., Lockwood D.J., Bock C., MacDougall B.R. Nickel hydroxides and related materials: a review of their structures, synthesis and properties. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 2014, 471 (2174), P. 20140792-20140792.</mixed-citation><mixed-citation xml:lang="en">Hall D.S., Lockwood D.J., Bock C., MacDougall B.R. Nickel hydroxides and related materials: a review of their structures, synthesis and properties. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 2014, 471 (2174), P. 20140792-20140792.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Rall J.D., Seehra M.S., Shah N., Huffman G.P.Comparison of the nature of magnetism in α-Ni(OH)2 and β-Ni(OH)2. J. Appl. Phys, 2010, 107(9), 09B511.</mixed-citation><mixed-citation xml:lang="en">Rall J.D., Seehra M.S., Shah N., Huffman G.P.Comparison of the nature of magnetism in α-Ni(OH)2 and β-Ni(OH)2. J. Appl. Phys, 2010, 107(9), 09B511.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Wallner H., Gatterer K. Growth of Pure Ni(OH)2 Single Crystals from Solution - Control of the Crystal Size. Anorg. Allg. Chem., 2002, 628, P. 2818-2820.</mixed-citation><mixed-citation xml:lang="en">Wallner H., Gatterer K. Growth of Pure Ni(OH)2 Single Crystals from Solution - Control of the Crystal Size. Anorg. Allg. Chem., 2002, 628, P. 2818-2820.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Casas-Cabanas M., Palac´ın M.R., Rodr´ıguez-Carvajal J. Microstructural analysis of nickel hydroxide: Anisotropic size versus stacking faults. Powder Diffraction, 2005, 20(4), P. 334-344.</mixed-citation><mixed-citation xml:lang="en">Casas-Cabanas M., Palac´ın M.R., Rodr´ıguez-Carvajal J. Microstructural analysis of nickel hydroxide: Anisotropic size versus stacking faults. Powder Diffraction, 2005, 20(4), P. 334-344.</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Wehrens-Dijksma M., Notten P.H.L. Electrochemical quartz microbalance characterization of Ni(OH)2-based thin film electrodes. Electrochimica Acta, 2006, 51(18), P. 3609-3621.</mixed-citation><mixed-citation xml:lang="en">Wehrens-Dijksma M., Notten P.H.L. Electrochemical quartz microbalance characterization of Ni(OH)2-based thin film electrodes. Electrochimica Acta, 2006, 51(18), P. 3609-3621.</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Ramesh T.N., Kamath P.V. Synthesis of nickel hydroxide:Effect of precipitation conditions on phase selectivity and structural disorder. J. Power Sources, 2006, 156, P. 655-661.</mixed-citation><mixed-citation xml:lang="en">Ramesh T.N., Kamath P.V. Synthesis of nickel hydroxide:Effect of precipitation conditions on phase selectivity and structural disorder. J. Power Sources, 2006, 156, P. 655-661.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Rajamathi M., Kamatha P.V., Seshadrib P. Polymorphism in nickel hydroxide: role of interstratication. J. Mater. Chem, 2000, 10, P. 503-506.</mixed-citation><mixed-citation xml:lang="en">Rajamathi M., Kamatha P.V., Seshadrib P. Polymorphism in nickel hydroxide: role of interstratication. J. Mater. Chem, 2000, 10, P. 503-506.</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Faure C., Delmas C., Fouassier M. J. Characterization of a turbostratic α-nickel hydroxide quantitatively obtained from an NiSO4 solution. Power Sources, 1991, 35(3), P. 279-290.</mixed-citation><mixed-citation xml:lang="en">Faure C., Delmas C., Fouassier M. J. Characterization of a turbostratic α-nickel hydroxide quantitatively obtained from an NiSO4 solution. Power Sources, 1991, 35(3), P. 279-290.</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Hall D.S., Lockwood D.J., Poirier S., Bock C., MacDougall B.R. Raman and Infrared spectroscopy of α and β phases of thin nickel hydroxide films electrochemically formed on nickel. J. Phys. Chem. A, 2012, 116(25), P. 6771-6784.</mixed-citation><mixed-citation xml:lang="en">Hall D.S., Lockwood D.J., Poirier S., Bock C., MacDougall B.R. Raman and Infrared spectroscopy of α and β phases of thin nickel hydroxide films electrochemically formed on nickel. J. Phys. Chem. A, 2012, 116(25), P. 6771-6784.</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Delmas C., Tessier C. Stacking faults in the structure of nickel hydroxide: a rationale of its high electrochemical activity. J. Mater. Chem, 1997, 7, P. 1439-1443.</mixed-citation><mixed-citation xml:lang="en">Delmas C., Tessier C. Stacking faults in the structure of nickel hydroxide: a rationale of its high electrochemical activity. J. Mater. Chem, 1997, 7, P. 1439-1443.</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Tessier C., Haumesser P.H., Bernard P., Delmas C. The structure of Ni(OH)2: from the ideal material to the electrochemically active one. J. Electrochem. Soc, 1999, 146, P. 2059-2067.</mixed-citation><mixed-citation xml:lang="en">Tessier C., Haumesser P.H., Bernard P., Delmas C. The structure of Ni(OH)2: from the ideal material to the electrochemically active one. J. Electrochem. Soc, 1999, 146, P. 2059-2067.</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Ramesh T.N., Jayashree R.S., Kamath P.V. Disorder in layered hydroxides: DIFFaX simulation of the X-Ray powder diffraction patterns of nickel hydroxide. Clays Clay Miner, 2003, 51, P. 570-576.</mixed-citation><mixed-citation xml:lang="en">Ramesh T.N., Jayashree R.S., Kamath P.V. Disorder in layered hydroxides: DIFFaX simulation of the X-Ray powder diffraction patterns of nickel hydroxide. Clays Clay Miner, 2003, 51, P. 570-576.</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Ramesh T.N., Kamath P.V. The effect of stacking faults on the electrochemical performance of nickel hydroxide electrodes. Mater. Res. Bull, 2008, 43, P. 2827-2832.</mixed-citation><mixed-citation xml:lang="en">Ramesh T.N., Kamath P.V. The effect of stacking faults on the electrochemical performance of nickel hydroxide electrodes. Mater. Res. Bull, 2008, 43, P. 2827-2832.</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">de Oliveira E.F., Hase Y. Infrared study of magnesium-nickel hydroxide solid solutions. Vib. Spectros., 2003, 31, P. 19-24.</mixed-citation><mixed-citation xml:lang="en">de Oliveira E.F., Hase Y. Infrared study of magnesium-nickel hydroxide solid solutions. Vib. Spectros., 2003, 31, P. 19-24.</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Batsanov S.S. Structural chemistry. Facts and dependencies. M.: Dialog-MGU, 2000, 292 p. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Batsanov S.S. Structural chemistry. Facts and dependencies. M.: Dialog-MGU, 2000, 292 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Almjasheva O.V., Gusarov V.V. Metastable clusters and aggregative nucleation mechanism. Nanosystems: Physics, Chemistry, Mathematics, 2014, 5(3), P. 405-417.</mixed-citation><mixed-citation xml:lang="en">Almjasheva O.V., Gusarov V.V. Metastable clusters and aggregative nucleation mechanism. Nanosystems: Physics, Chemistry, Mathematics, 2014, 5(3), P. 405-417.</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Gusarov V.V., Almjasheva O.V. The role of non-autonomous state of matter in the formation of structure and properties of nanomaterials. Chapter13 in the book Nanomaterials: properties and promising applications. Ed. A.B. Yaroslavtsev, Scientific World Publishing House, Moscow, 2014, P. 378-403.</mixed-citation><mixed-citation xml:lang="en">Gusarov V.V., Almjasheva O.V. The role of non-autonomous state of matter in the formation of structure and properties of nanomaterials. Chapter13 in the book Nanomaterials: properties and promising applications. Ed. A.B. Yaroslavtsev, Scientific World Publishing House, Moscow, 2014, P. 378-403.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
