najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2023-14-5-549-553najo-292Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХNanoparticles in titanite oreНаночастицы в CaTiSiO5 рудеhttps://orcid.org/0000-0001-9229-6758ДорошеваИ. Б.DoroshevaI. B.

Ирина Борисовна Дорошева

Irina B. Dorosheva

620016 Yekaterinburg

dorosheva1993@mail.ruhttps://orcid.org/0000-0002-0543-9982РемпельА. А.RempelA. A.

Андрей Андреевич Ремпель

Andrey A. Rempel

620016 Yekaterinburg

rempel.imet@mail.ruhttps://orcid.org/0000-0002-4857-0884КалашниковаГ. О.KalashnikovaG. O.

Галина Олеговна Калашникова

Galina O. Kalashnikova

Fersmana str., 14, 184209 Apatity

g.kalashnikova@ksc.ruЯковенчукВ. Н.YakovenchukV. N.

Виктор Нестерович Яковенчук

Victor N. Yakovenchuk

Fersmana str., 14, 184209 Apatity

yakovenchuk@geoksc.apatity.ruInstitute of Metallurgy of the Ural Branch of the Russian Academy of SciencesRussian FederationNanomaterials Research Centre, Kola Science Centre, Russian Academy of SciencesRussian Federation202308062025145549553Copyright © Dorosheva I.B., Rempel A.A., Kalashnikova G.O., Yakovenchuk V.N., 20252025Дорошева И.Б., Ремпель А.А., Калашникова Г.О., Яковенчук В.Н.Dorosheva I.B., Rempel A.A., Kalashnikova G.O., Yakovenchuk V.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/292

Nanoparticles in titanite CaTiSiO5 were found using transmission electron microscopy. Chemical and XPS analyzes of the nanoparticles were performed. The study showed the content of the elements Si, Ti and Ca to be about 19, 14 and 12 % in the ore, respectively, belonging to the titanite phase. Based on TEM images, it was established that titanite exhibits a disordered lamellar structure with a diameter of 3 to 5 nm and an interplanar distance of about 6.3 A° .

Наночастицы в титаните CaTiSiO5 были обнаружены с помощью просвечивающей электронной микроскопии. Был проведен химический анализ и съемка рентгеновской фотоэлектронной спектроскопии. Исследование показало, что содержание элементов Si, Ti и Ca в руде, относящейся к титанитовой фазе, составляет около 19, 14 и 12 % соответственно. На основании ПЭМ-изображений установлено, что титанит имеет неупорядоченную пластинчатую структуру с диаметром частиц от 3 до 5 нм и межплоскостным расстоянием около 6,3 А.

Титанитнаночастицыпросвечивающая электронная микроскопия (ПЭМ)рентгеновская фотоэлектронная спектроскопия (РФЭС)titanitenanoparticlestransmission electron microscopy (TEM)X-ray photoelectron spectroscopy (XPS)This work was supported by the Russian Science Foundation [grant number 21–73- 20039].ReferencesGerasimova L.G., Maslova M.V. Titanium Hydroxides and Compositions on Their Basis. Production and Application. Moscow, LKM-press Publ., 2011, 100 p. (In Russian)Gerasimova L.G., Maslova M.V. Titanium Hydroxides and Compositions on Their Basis. Production and Application. Moscow, LKM-press Publ., 2011, 100 p. (In Russian)Oleksiienko O., Wolkersdorfer C., Sillanp¨a¨a M. Titanosilicates in Cation Adsorption and Cation Exchange – A Review. Chemical Engineering J., 2017, P. 570–585.Oleksiienko O., Wolkersdorfer C., Sillanp¨a¨a M. Titanosilicates in Cation Adsorption and Cation Exchange – A Review. Chemical Engineering J., 2017, P. 570–585.Milyutin V.V., Nekrasova N.A., Yanicheva N.Y., Kalashnikova G.O., Ganicheva Y.Y. Sorption of Cesium and Strontium Radionuclides onto Crystalline Alkali Metal Titanosilicates. Radiochemistry, 2017, 59 (1), P. 65–69.Milyutin V.V., Nekrasova N.A., Yanicheva N.Y., Kalashnikova G.O., Ganicheva Y.Y. Sorption of Cesium and Strontium Radionuclides onto Crystalline Alkali Metal Titanosilicates. Radiochemistry, 2017, 59 (1), P. 65–69.Samburov G.O., Kiselev Yu.G. Improving the technology for producing titanium compounds from enriched sphenite ore. Materials of the Federal Research Centre “KSC” of the RAS, 2018, 9 (6), P. 51–56 (in Russian).Samburov G.O., Kiselev Yu.G. Improving the technology for producing titanium compounds from enriched sphenite ore. Materials of the Federal Research Centre “KSC” of the RAS, 2018, 9 (6), P. 51–56 (in Russian).Yakovenchuk V.N., Ivanyuk G.Y., Pakhomovsky Y.A., Men’shikov Y.P. Khibiny, Laplandia Minerals, Apatity, 2005.Yakovenchuk V.N., Ivanyuk G.Y., Pakhomovsky Y.A., Men’shikov Y.P. Khibiny, Laplandia Minerals, Apatity, 2005.Nikolaev A.I., Samburov G.O., Kiselev Yu.G., Gerasimova L.G. Sphenite ores – raw materials for the implementation of the titanium compounds technology. Bulletin of the Academy of Sciences of the U.S.S.R. Physical series, 2018, P. 83–86 (in Russian).Nikolaev A.I., Samburov G.O., Kiselev Yu.G., Gerasimova L.G. Sphenite ores – raw materials for the implementation of the titanium compounds technology. Bulletin of the Academy of Sciences of the U.S.S.R. Physical series, 2018, P. 83–86 (in Russian).Melnikov N.N., Busyrev V.M. The concept of resource-balanced development of the mineral resource base. Mineral Resources of Russia: Economics and Management, 2005, 2, P. 58–64 (in Russian).Melnikov N.N., Busyrev V.M. The concept of resource-balanced development of the mineral resource base. Mineral Resources of Russia: Economics and Management, 2005, 2, P. 58–64 (in Russian).Luan Z., Maes E. M., Van Der Heide P.A.W., Zhao D., Czernuszewicz R.S., Kevan L. Incorporation of Titanium, into Mesoporous Silica Molecular Sieve SBA-15. Chemistry of Materials, 1999, 11 (12), P. 3680–3686.Luan Z., Maes E. M., Van Der Heide P.A.W., Zhao D., Czernuszewicz R.S., Kevan L. Incorporation of Titanium, into Mesoporous Silica Molecular Sieve SBA-15. Chemistry of Materials, 1999, 11 (12), P. 3680–3686.Hasegawa Y., Ayame A. Investigation of Oxidation States of Titanium in Titanium Silicalite-1 by X-Ray Photoelectron Spectroscopy. Catalysis Today, 2001, 71 (1–2), P. 177–187.Hasegawa Y., Ayame A. Investigation of Oxidation States of Titanium in Titanium Silicalite-1 by X-Ray Photoelectron Spectroscopy. Catalysis Today, 2001, 71 (1–2), P. 177–187.Finetti P., Sedona F., Rizzi G.A., Mick U., Sutara F., Svec M., Matolin V., Schierbaum K., Granozzi G. Core and Valence Band Photoemission Spectroscopy of Well-Ordered Ultrathin TiOx Films on Pt(111). J. of Physical Chemistry C, 2007, 111 (2), P. 869–876.Finetti P., Sedona F., Rizzi G.A., Mick U., Sutara F., Svec M., Matolin V., Schierbaum K., Granozzi G. Core and Valence Band Photoemission Spectroscopy of Well-Ordered Ultrathin TiOx Films on Pt(111). J. of Physical Chemistry C, 2007, 111 (2), P. 869–876.Kaichev V.V., Popova G.Y., Chesalov Y.A., Saraev A.A., Zemlyanov D.Y., Beloshapkin S.A., Knop-Gericke A., Schl¨ogl R., Andrushkevich T.V., Bukhtiyarov V.I. Selective Oxidation of Methanol to Form Dimethoxymethane and Methyl Formate over a Monolayer V2O5/TiO2 Catalyst. J. of Catalysis, 2014, 311, P. 59–70.Kaichev V.V., Popova G.Y., Chesalov Y.A., Saraev A.A., Zemlyanov D.Y., Beloshapkin S.A., Knop-Gericke A., Schl¨ogl R., Andrushkevich T.V., Bukhtiyarov V.I. Selective Oxidation of Methanol to Form Dimethoxymethane and Methyl Formate over a Monolayer V2O5/TiO2 Catalyst. J. of Catalysis, 2014, 311, P. 59–70.Kaichev V.V., Chesalov Y.A., Saraev A.A., Klyushin A.Y., Knop-Gericke A., Andrushkevich T.V., Bukhtiyarov V.I. Redox Mechanism for Selective Oxidation of Ethanol over Monolayer V2O5/TiO2 Catalysts. J. of Catalysis, 2016, 338, P. 82–93.Kaichev V.V., Chesalov Y.A., Saraev A.A., Klyushin A.Y., Knop-Gericke A., Andrushkevich T.V., Bukhtiyarov V.I. Redox Mechanism for Selective Oxidation of Ethanol over Monolayer V2O5/TiO2 Catalysts. J. of Catalysis, 2016, 338, P. 82–93.MaiW.,Wen F., Xie D., Leng Y., Mu Z. Structure and Composition Study of Carbon-Doped Titanium Oxide Film Combined with First Principles. J. of Advanced Ceramics, 2014, 3 (1), P. 49–55.MaiW.,Wen F., Xie D., Leng Y., Mu Z. Structure and Composition Study of Carbon-Doped Titanium Oxide Film Combined with First Principles. J. of Advanced Ceramics, 2014, 3 (1), P. 49–55.Larina T.V., Dovlitova L.S., Kaichev V.V., Malakhov V.V., Glazneva T.S., Paukshtis E.A., Bal’Zhinimaev B.S. Influence of the Surface Layer of Hydrated Silicon on the Stabilization of Co2+ Cations in Zr–Si Fiberglass Materials According to XPS, UV-Vis DRS, and Differential Dissolution Phase Analysis. RSC Advances, 2015, 5 (97), P. 79898–79905.Larina T.V., Dovlitova L.S., Kaichev V.V., Malakhov V.V., Glazneva T.S., Paukshtis E.A., Bal’Zhinimaev B.S. Influence of the Surface Layer of Hydrated Silicon on the Stabilization of Co2+ Cations in Zr–Si Fiberglass Materials According to XPS, UV-Vis DRS, and Differential Dissolution Phase Analysis. RSC Advances, 2015, 5 (97), P. 79898–79905.Foucaud Y., Badawi M., Filippov L.O., Barres O., Filippova I.V., Leb`egue S. Synergistic Adsorptions of Na2CO3 and Na2SiO3 on Calcium Minerals Revealed by Spectroscopic and: Ab Initio Molecular Dynamics Studies. Chemical Science, 2019, 10 (43), P. 9928–9940.Foucaud Y., Badawi M., Filippov L.O., Barres O., Filippova I.V., Leb`egue S. Synergistic Adsorptions of Na2CO3 and Na2SiO3 on Calcium Minerals Revealed by Spectroscopic and: Ab Initio Molecular Dynamics Studies. Chemical Science, 2019, 10 (43), P. 9928–9940.Eby R.K., Ewing R.C. Alpha-Recoil Damage in Titanite (CaTiSiO5): Direct Observation and Annealing Study Using High Resolution Transmission Electron Microscopy. J. of Materials Research, 1991, 6 (3), P. 560–564.Eby R.K., Ewing R.C. Alpha-Recoil Damage in Titanite (CaTiSiO5): Direct Observation and Annealing Study Using High Resolution Transmission Electron Microscopy. J. of Materials Research, 1991, 6 (3), P. 560–564.

The authors declare that there are no conflicts of interest present.