najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2023-14-5-554-559najo-293Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХSILD synthesis of porous manganese oxide nanocoatings as electroactive materials for pseudocapacitorsПослойный синтез пористых нанопокрытий оксида марганца, как электроактивного материала для псевдоконденсаторовhttps://orcid.org/0000-0001-5930-2087ЛобинскийА. А.LobinskyA. A.

Artem A. Lobinsky

Saint Petersburg, 194021

lobinski.a@mail.ruhttps://orcid.org/0000-0003-2816-7059КаневаМ. В.KanevaM. V.

Maria V. Kaneva

Saint Petersburg, 194021

skt94@bk.ruhttps://orcid.org/0000-0001-7015-1435БачинаА. К.BachinaA. K.

Anastasia K. Bachina

Saint Petersburg, 194021

ТеневичМ. И.TenevichM. I.

Maxim I. Tenevich

Saint Petersburg, 194021

mtenevich@gmail.comIoffe InstituteRussian Federation202308062025145554559Copyright © Lobinsky A.A., Kaneva M.V., Bachina A.K., Tenevich M.I., 20252025Лобинский А.А., Канева М.В., Бачина А.К., Теневич М.И.Lobinsky A.A., Kaneva M.V., Bachina A.K., Tenevich M.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/293

In present work the porous nanocoating of manganese oxide were obtained via successive ionic layer deposition from aqueous solutions of potassium permanganate and DMSO. The morphology, phase and chemical composition of the synthesized nanocoatings were characterized by XRD, SEM, EDX and Raman spectroscopy. The possibility of controlled changes in the morphology of the resulting compounds was demonstrated by changing the concentration of reagents and the number of processing cycles in order to obtain optimal electrochemical characteristics. Electrodes based on nickel foam and coated with films of porous manganese oxide showed high specific capacity (1324 and 297 F/g at a current density of 1 A/g in 1 M NaOH and 1 M Na2SO4, respectively), both in neutral and in aqueous alkaline electrolytes.

В настоящей работе пористое нанопокрытие из оксида марганца было получено путем ионного наслаивания из водных растворов перманганата калия и ДМСО. Морфология, фазовый и химический состав синтезированных нанопокрытий были охарактеризованы методами РФА, СЭМ, ЭДС и КР-спектроскопии. Возможность контролируемого изменения морфологии полученных соединений была продемонстрирована путем изменения концентрации реагентов и количества циклов обработки с целью получения оптимальных электрохимических характеристик. Электроды на основе вспененного никеля, покрытые пленками пористого оксида марганца, показали высокую удельную емкость (1324 Ф/г и 297 Ф/г при плотности тока 1 А/г в 1M NaOH и 1M Na2SO4, соответственно) как в нейтральном, так и в щелочном электролите.

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The authors declare that there are no conflicts of interest present.