najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2023-14-5-584-589najo-296Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХPlanar perovskite solar cells with La2NiMnO6 buffer layerПланарные перовскитные солнечные элементы с буферным слоем на основе La2NiMnO6https://orcid.org/0000-0002-8660-5646КозловС. С.KozlovS. S.

Sergey S. Kozlov

Kosygin St., 4, Moscow, 119334

sergeykozlov1@gmail.comhttps://orcid.org/0000-0002-7430-4133НикольскаяА. Б.NikolskaiaA. B.

Anna B. Nikolskaia

Kosygin St., 4, Moscow, 119334

anickolskaya@mail.ruhttps://orcid.org/0000-0002-6702-5195КарягинаО. К.KaryaginaO. K.

Olga K. Karyagina

Kosygin St., 4, Moscow, 119334

olgakar07@mail.ruhttps://orcid.org/0000-0001-8090-2052КосареваЕ. К.KosarevaE. K.

Ekaterina K. Kosareva

Kosygin St., 4, Moscow, 119991

catherine.kos@yandex.ruhttps://orcid.org/0000-0001-8982-3959АлексееваО. В.AlexeevaO V.

Olga V. Alexeeva

Kosygin St., 4, Moscow, 119334

alexol@yandex.ruhttps://orcid.org/0009-0001-6357-2052ПетроваВ. И.PetrovaV. I.

Vasilisa I. Petrova

Kosygin St., 4, Moscow, 119334

balagur.sh@yandex.ruhttps://orcid.org/0000-0002-6132-4178АльмяшеваО. И.AlmjashevaO. V.

Oksana V. Almjasheva

Professora Popova St., 5, St. Petersburg, 197376

Politekhnicheskaya St., 26, St. Petersburg, 194021

almjasheva@mail.ruhttps://orcid.org/0000-0002-8593-3023ШевалеевскийО. И.ShevaleevskiyO. I.

Oleg I. Shevaleevskiy

Kosygin St., 4, Moscow, 119334

shevale2006@yahoo.comEmanuel Institute of Biochemical Physics, Russian Academy of SciencesRussian FederationN. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of ScienceRussian FederationSt. Petersburg State Electrotechnical University “LETI”; Ioffe Physical-Technical Institute, Russian Academy of SciencesRussian Federation202308062025145584589Copyright © Kozlov S.S., Nikolskaia A.B., Karyagina O.K., Kosareva E.K., Alexeeva O.V., Petrova V.I., Almjasheva O.V., Shevaleevskiy O.I., 20252025Козлов С.С., Никольская А.Б., Карягина О.К., Косарева Е.К., Алексеева О.В., Петрова В.И., Альмяшева О.И., Шевалеевский О.И.Kozlov S.S., Nikolskaia A.B., Karyagina O.K., Kosareva E.K., Alexeeva O.V., Petrova V.I., Almjasheva O.V., Shevaleevskiy O.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/296

Thin films of La2NiMnO6 (LNMO) double perovskite oxide were first used as buffer layers in planar perovskite solar cells (PSCs) with the architecture of glass/FTO/LNMO/CH3NH3PbI3/Spiro-MeOTAD/Au. All PSCs were fabricated under ambient conditions and their photovoltaic parameters were measured under standard illumination (AM1.5G, 1000 W/m2). Power conversion efficiency (PCE) values (10 – 11 %) for the PSCs developed were comparable with those obtained for conventional PSCs with compact TiO2 (cTiO2) layer, but the stability of PSCs with LNMO buffer layer was significantly higher than for cTiO2-based PSCs.

Тонкие пленки двойных перовскитов вида La2NiMnO6 (LNMO) впервые были использованы в качестве буферного слоя в планарных перовскитных солнечных элементах (ПСЭ) со структурой стекло/FTO/LNMO/CH3NH3PbI3/Spiro-MeOTAD/Au. Все образцы ПСЭ были сконструированы на открытом воздухе, и их фотовольтаические параметры были измерены при стандартном освещении (АМ1.5G, 1000 Вт/м2). Полученные значения эффективностей оказались сопоставимы с эффективностями для ПСЭ на основе традиционно используемых блокирующих слоев TiO2, однако стабильность при этом оказалась существенно выше.

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The authors declare that there are no conflicts of interest present.