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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2024-15-2-170-183</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-32</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PHYSICS</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ФИЗИКА</subject></subj-group></article-categories><title-group><article-title>Photon antibunching in sixth harmonic generation</article-title><trans-title-group xml:lang="ru"><trans-title>Антигруппировка фотонов в генерации шестой гармоники</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0009-3184-3274</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Сингх</surname><given-names>Рупеш</given-names></name><name name-style="western" xml:lang="en"><surname>Singh</surname><given-names>Rupesh</given-names></name></name-alternatives><bio xml:lang="en"><p>Koylanagar, Dhanbad, Jharkhand</p></bio><email xlink:type="simple">rupesh.dav2021@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-2721-5055</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Гири</surname><given-names>Дилип Кумар</given-names></name><name name-style="western" xml:lang="en"><surname>Giri</surname><given-names>Dilip Kumar</given-names></name></name-alternatives><bio xml:lang="en"><p>Dhanbad, Jharkhand</p></bio><email xlink:type="simple">dilipkumargiri@gmail.com</email><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>Department of Physics, D.A.V. Public School</institution><country>India</country></aff><aff xml:lang="en" id="aff-2"><institution>University Department of Physics, Binod Bihari Mahto Koyalanchal University</institution><country>India</country></aff><pub-date pub-type="collection"><year>2024</year></pub-date><pub-date pub-type="epub"><day>31</day><month>05</month><year>2025</year></pub-date><volume>15</volume><issue>2</issue><fpage>170</fpage><lpage>183</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Singh R., Giri D.K., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Сингх Р., Гири Д.К.</copyright-holder><copyright-holder xml:lang="en">Singh R., Giri D.K.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/32">https://nanojournal.ifmo.ru/jour/article/view/32</self-uri><abstract><p>We studied photon antibunching in the pump and the harmonic modes of the sixth harmonic generation process. The generalized interaction Hamiltonian is solved for several particular cases in the Heisenberg picture, and the possibility of observing photon antibunching is investigated using the short-time approximation technique. It is shown that the photon antibunching in the pump field depends on the number of pump photons, the interaction time, and the coupling of the field between the modes. With the same amount of pump photons, we deduced that third-order photon antibunching is more nonclassical than second- and first-order photon antibunching. In this process, the effect of photon antibunching is not seen in the harmonic mode over pump mode. It is shown that photon antibunching is more noticeable with shorter interaction times as the depth of nonclassicality increases and the second-order correlation function decreases. The first-order Hamiltonian interaction, which stimulates both pump and harmonic fields, is demonstrated to be more nonclassical than the second-order Hamiltonian interaction. It is clear that the coherent state, or vacuum state, of a pump field with a nonzero harmonic field creates photon clusters because the pump field causes interaction, which leads to bunching effects. It is interpreted that the degree of photon antibunching is maximum in the regions where the second correlation function is minimum. Photon antibunching has been shown to be one of the quantum properties of light.</p></abstract><trans-abstract xml:lang="ru"><p>Изучен эффект антигруппировки фотонов в моде накачки и гармонических модах в процессе генерации шестой гармоники. Для нескольких частных случаев в картине Гейзенберга получен обобщенный гамильтониан взаимодействия и с помощью метода временной теории возмущений исследована возможность наблюдения антигруппировки фотонов. Показано, что антигруппировка фотонов в поле накачки зависит от числа фотонов накачки, времени взаимодействия и параметра межмодового взаимодействия. При одинаковом количестве фотонов накачки мы пришли к выводу, что антигруппировка фотонов третьего порядка более неклассическая, чем антигруппировка фотонов второго и первого порядка. В этом процессе эффект антигруппировки фотонов менее выражен в гармонических модах по сравнению с модой накачки. Показано, что антигруппировка фотонов более заметна при меньших временах взаимодействия по мере увеличения глубины неклассичности и уменьшения корреляционной функции второго порядка. Показано, что гамильтоново взаимодействие первого порядка, которое стимулирует как поля накачки, так и гармонические поля, создает большую неклассичность, чем гамильтоново взаимодействие второго порядка. Найдено, что когерентное состояние, или вакуумное состояние поля накачки с ненулевым гармоническим полем создает кластеры фотонов, поскольку поле накачки вызывает взаимодействие, приводящее к эффектам группировки. Интерпретируется, что степень антигруппировки фотонов максимальна в областях, где вторая корреляционная функция минимальна. Было показано, что антигруппировка фотонов является одним из квантовых свойств света.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>антигруппировка фотонов</kwd><kwd>антигруппировка высших порядков</kwd><kwd>генерация шестой гармоники</kwd><kwd>оператор числа фотонов</kwd><kwd>кратковременное приближение</kwd></kwd-group><kwd-group xml:lang="en"><kwd>photon antibunching</kwd><kwd>higher-order antibunching</kwd><kwd>sixth harmonic generation</kwd><kwd>photon number operator</kwd><kwd>short-time approximation</kwd></kwd-group><funding-group><funding-statement xml:lang="en">We would like to thank the referee for his comments and valuable suggestions.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Stoler D. Photon antibunching and possible ways to observe it. Phys. Rev. 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