najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2021-12-2-188-198najo-359Research ArticleNANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICSНАНОСИСТЕМЫ: ФИЗИКА, ХИМИЯ, МАТЕМАТИКАComparative study of synthesis and structural by using different precursors of copper oxide nanoparticles and their application in the adsorption capacityСравнительное исследование синтеза и структуры наночастиц оксида меди при использовании различных прекурсоров и анализ возможности применение их в качестве адсорбентовBahga-SalehBahga-Saleh.

Aurangabad (MS)

Aurangabad (MS)

yshaikh@gmail.comFatemaSamreenFatemaSamreen

Aurangabad (MS)

Aurangabad (MS)

yshaikh@gmail.comFarooquiMazharFarooquiMazhar

Aurangabad (MS)

Aurangabad (MS)

yshaikh@gmail.comYusufShaikhYusufShaikh

Kannad (MS)

Kannad (MS)

yshaikh@gmail.comMaulana Azad College of Arts, Science and CommerceMaulana Azad College of Arts, Science and CommerceShivaji CollegeShivaji College202128072025122188198Copyright © Bahga-Saleh .., Fatema S., Farooqui M., Yusuf S., 20252025Bahga-Saleh .., Fatema S., Farooqui M., Yusuf S.Bahga-Saleh .., Fatema S., Farooqui M., Yusuf S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/359

Copper oxide nanoparticles were prepared by five sol-gel methods. The comparative study was made by the characterization such as FTIR, SEMEDX, XRD. Out of these protocols, method five is more suitable and gives more accurate and appropriate results. From the data of EDX it is also found that method five gives higher yields of copper oxide nanoparticles. The efficiency of these nanoparticles as low cost adsorbent for the removal of methylene blue (MB) capacity from aqueous solutions was investigated. The effect of different parameters such as amount of adsorbent, concentration of dye, contact time, pH, temperature were studied the adsorption capacity and adsorption behavior of nanoparticles under various conditions. The experimental isotherm data has been studied. The kinetic study of the adsorption obeys Pseudo-first order model. The thermodynamic parameters namely Gibbs free energy, enthalpy, and entropy have revealed that the adsorption of methylene blue on the nanoparticles are feasible, spontaneous and exothermic.

Наночастицы оксида меди были получены пятью золь-гель методами. Сравнительное исследование было выполнено с помощью таких методов, как FTIR, SEMEDX, XRD. На основании анализа результатов выявлено, что пятый метод является более подходящим и дает более точные и правильные результаты. Из данных EDX также установлено, что пятый метод дает более высокие выходы наночастиц оксида меди. Исследована эффективность этих наночастиц в качестве недорогого адсорбента для удаления метиленового синего (МС) из водных растворов. Было изучено влияние различных параметров, таких как количество адсорбента, концентрация красителя, время контакта, рН, температура, на адсорбционную способность и адсорбционное поведение наночастиц в различных условиях. Изучены экспериментальные изотермические данные. Кинетическое исследование адсорбции подчиняется модели псевдопервого порядка. Термодинамические параметры, а именно свободная энергия Гиббса, энтальпия и энтропия, показали, что адсорбция метиленового синего на наночастицах возможна, спонтанна и экзотермична.

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The authors declare that there are no conflicts of interest present.