najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2021-12-2-232-245najo-370Research ArticleNANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICSНАНОСИСТЕМЫ: ФИЗИКА, ХИМИЯ, МАТЕМАТИКАSynthesis of nanostructured composite materials of MoO3/TiO2–SiO2 with spherical shape prepared with resinsСинтез наноструктурированных композиционных материалов MoO3/TiO2–SiO2 сферической формы, приготовленных на основе смолKuznetsovaS. A.KuznetsovaS. A.

Lenin, 36, Tomsk, 634050 

Lenin, 36, Tomsk, 634050 

onm@mail.tsu.ruKhalipovaA. S.KhalipovaO. S.

Lenin, 36, Tomsk, 634050 

Lenin, 36, Tomsk, 634050 

onm@mail.tsu.ruLisitsaK. V.LisitsaK. V.

Lenin, 36, Tomsk, 634050 

Lenin, 36, Tomsk, 634050 

onm@mail.tsu.ruDittsА. А.DittsА. А.

Lenin, 30, Tomsk, 634050 

Lenin, 30, Tomsk, 634050 

onm@mail.tsu.ruMalchikА. G.MalchikA. G.

Lenin, 30, Tomsk, 634050 

Lenin, 30, Tomsk, 634050 

onm@mail.tsu.ruKozikV. V.KozikV. V.

Lenin, 36, Tomsk, 634050 

Lenin, 36, Tomsk, 634050 

onm@mail.tsu.ruNational Research Tomsk State UniversityNational Research Tomsk State UniversityNational Research Tomsk Polytechnic UniversityNational Research Tomsk Polytechnic University202128072025122232245Copyright © Kuznetsova S.A., Khalipova O.S., Lisitsa K.V., Ditts А.А., Malchik A.G., Kozik V.V., 20252025Kuznetsova S.A., Khalipova A.S., Lisitsa K.V., Ditts А.А., Malchik А.G., Kozik V.V.Kuznetsova S.A., Khalipova O.S., Lisitsa K.V., Ditts А.А., Malchik A.G., Kozik V.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/370

The aim of this work was to synthesize of nanostructured MoO3/TiO2-SiO2 composites with hollow spherical shape by thermal decomposition of anion exchangers saturated with Mo7O6-24 ions and treated with the TBT-TEOS sol. The effect of the kinetics (Kissinger and the Metzger-Horowitz methods) of thermal decomposition of resins of porous and gel structures on the size of MoO3 nanoparticles and the strength of MoO3/TiO2-SiO2 spheres was shown. The formation of dense spherical nanostructured agglomerates of the composite is facilitated by reactions occurring at the interface between the phases of cylindrical and spherical symmetry when using an anion exchange resin with a porous structure. The decomposition reactions of the anion-exchange resin of the gel structure, accompanied by random nucleation, lead to the formation of hollow spherical agglomerates of the composite with cracks on the surface. The materials were characterized by DSC-TGA, XRD and SEM.

Целью работы являлся синтез наноструктурированных композитов MoO3/TiO2–SiO2 полой сферической формы путем термического разложения анионообменников, насыщенных ионами Mo7O6-24 и обработанных золем ТБТ–ТЭОС. Показано влияние кинетики (метод Киссинджера и Метцгера-Горовица) термического разложения смол пористой и гелевой структур на размер наночастиц MoO3 и прочность сфер MoO3/TiO2–SiO2. Образованию плотных сферических наноструктурированных агломератов композита способствуют реакции, протекающие на границе раздела фаз цилиндрической и сферической симметрии при использовании анионообменной смолы с пористой структурой. Реакции разложения анионообменной смолы гелевой структуры, сопровождающиеся случайным зародышеобразованием, приводят к образованию полых сферических агломератов композита с трещинами на поверхности. Материалы были охарактеризованы методами ДСК-ТГА, РФА и СЭМ.

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The authors declare that there are no conflicts of interest present.