najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2021-12-2-246-251najo-371Research ArticleNANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICSНАНОСИСТЕМЫ: ФИЗИКА, ХИМИЯ, МАТЕМАТИКАHigh performance tandem perovskite-silicon solar cells with very large bandgap photoelectrodesВысокопроизводительные тандемные перовскит-кремниевые солнечные элементы с фотоэлектродами с очень большой шириной запрещенной зоныNikolskaiaA. B.NikolskaiaA. B.

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

VildanovaM. F.VildanovaM. F.

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

KozlovS. S.KozlovS. S.

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

AlmjashevaO. V.AlmjashevaO. V.

Saint-Petersburg, Professora Popova St., 5, Saint Petersburg, 19737

Saint-Petersburg, Professora Popova St., 5, Saint Petersburg, 19737

GusarovV. V.GusarovV. V.

Saint-Petersburg, Professora Popova St., 5, Saint Petersburg, 197376,

Politekhnicheskaya St., 26, Saint Petersburg, 194021

Saint-Petersburg, Professora Popova St., 5, Saint Petersburg, 197376,

Politekhnicheskaya St., 26, Saint Petersburg, 194021

victor.v.gusarov@gmail.comShevaleevskiyО. I.ShevaleevskiyO. I.

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

Department of Solar Photovoltaics

Kosygin St. 4, Moscow, 119334

shevale2006@yahoo.comInstitute of Biochemical Physics RASInstitute of Biochemical Physics RASSaint Petersburg Electrotechnical University “LETISaint Petersburg Electrotechnical University “LETISaint Petersburg Electrotechnical University “LETI”; Ioffe Physical-Technical Institute RASSaint Petersburg Electrotechnical University “LETI”; Ioffe Physical-Technical Institute RAS202128072025122246251Copyright © Nikolskaia A.B., Vildanova M.F., Kozlov S.S., Almjasheva O.V., Gusarov V.V., Shevaleevskiy O.I., 20252025Nikolskaia A.B., Vildanova M.F., Kozlov S.S., Almjasheva O.V., Gusarov V.V., Shevaleevskiy О.I.Nikolskaia A.B., Vildanova M.F., Kozlov S.S., Almjasheva O.V., Gusarov V.V., Shevaleevskiy O.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/371

Nanostructured layers of metal oxides with very large bandgaps (Eg > 5 eV), such as ZrO2 and HfO2, were used as photoelectrodes in semitransparent perovskite solar cells (PSCs) with the device architecture of glass/FTO/c-TiO2/ZrO2 (or HfO2)/CH3NH3PbI3/PTAA/PEDOT:PSS/FTO/glass. The obtained PSCs were used as top elements for manufacturing high-performance four-terminal tandem perovskite-silicon solar cells. The comparative analysis of photovoltaic parameters measured for PSCs, crystalline silicon (c-Si) solar cells and tandem PSC/c-Si solar cells demonstrated that the application of very large-bandgap materials allows to improve the PSC performance and to increase the efficiency of tandem PSC/c-Si solar cell up to ~24% in comparison with a standalone c-Si solar cell.

Наноструктурированные слои оксидов металлов с очень большой шириной запрещенной зоны (Eg > 5 эВ), таких как ZrO2 и HfO2, использовались в качестве фотоэлектродов в полупрозрачных перовскитных солнечных элементах (ПСК) с архитектурой устройства стекло/FTO/c-TiO2/ZrO2 (или HfO2)/CH3NH3PbI3/PTAA/PEDOT:PSS/FTO/стекло. Полученные ПСК использовались в качестве топовых элементов для изготовления высокоэффективных четырехвыводных тандемных перовскит-кремниевых солнечных элементов. Сравнительный анализ фотоэлектрических параметров, измеренных для ПСК, солнечных элементов на основе кристаллического кремния (c-Si) и тандемных солнечных элементов ПСК /c-Si, показал, что применение материалов с очень большой шириной запрещенной зоны позволяет улучшить характеристики ПСК и повысить эффективность тандемный солнечный элемент ПСК /c-Si до ~24% по сравнению с автономным солнечным элементом c-Si.

 

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The authors declare that there are no conflicts of interest present.