najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2021-12-1-118-127najo-376Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХYoung’s modulus of phyllosilicate nanoscrolls measured by the AFM and by the in-situ TEM indentationМодуль Юнга наносвитков на основе филлосиликатов, измеренный с помощью АСМ и ПЭМ-индентирования in situKhalisovM. M.KhalisovM. M.

Politekhnicheskaya, 26, Saint-Petersburg 194021; Makarova emb., 6, Saint-Petersburg, 199034

Politekhnicheskaya, 26, Saint-Petersburg 194021; Makarova emb., 6, Saint-Petersburg, 199034

LebedevV. A.LebedevV. A.

Limerick, V94 T9PX

Limerick, V94 T9PX

PoluboyarinovA. S.PoluboyarinovA. S.

GSP-1, Leninskie Gory, Moscow, 119991

GSP-1, Leninskie Gory, Moscow, 119991

GarshevA. V.GarshevA. V.

GSP-1, Leninskie Gory, Moscow, 119991

GSP-1, Leninskie Gory, Moscow, 119991

KhrapovaE. K.KhrapovaE. K.

Politekhnicheskaya, 26, Saint-Petersburg 194021

Politekhnicheskaya, 26, Saint-Petersburg 194021

KrasilinA. A.KrasilinA. A.

Politekhnicheskaya, 26, Saint-Petersburg 194021

Politekhnicheskaya, 26, Saint-Petersburg 194021

AnkudinovA. V.AnkudinovA. V.

Politekhnicheskaya, 26, Saint-Petersburg 194021

Politekhnicheskaya, 26, Saint-Petersburg 194021

Alexander.ankudinov@mail.ioffe.ruIoffe Institute; Pavlov Institute of Physiology, Russian Academy of SciencesIoffe Institute; Pavlov Institute of Physiology, Russian Academy of SciencesUniversity of LimerickUniversity of LimerickLomonosov Moscow State UniversityLomonosov Moscow State UniversityIoffe InstituteIoffe Institute202128072025121118127Copyright © Khalisov M.M., Lebedev V.A., Poluboyarinov A.S., Garshev A.V., Khrapova E.K., Krasilin A.A., Ankudinov A.V., 20252025Khalisov M.M., Lebedev V.A., Poluboyarinov A.S., Garshev A.V., Khrapova E.K., Krasilin A.A., Ankudinov A.V.Khalisov M.M., Lebedev V.A., Poluboyarinov A.S., Garshev A.V., Khrapova E.K., Krasilin A.A., Ankudinov A.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/376

Ni3Si2O5(OH)4 phyllosilicate nanoscrolls were investigated by two techniques: the bending-based test method of AFM and the indentation method with visual control in STEM. In the first case, the average measured Young’s modulus, about 200 GPa, turned out to be significantly higher than in the second one, 40 GPa. The reasons for this discrepancy are analyzed.

Гидросиликатные наносвитки Ni3Si2O5(OH)4 исследованы двумя методами: методом АСМ на изгиб и методом вдавливания с визуальным контролем в ПЭМ. В первом случае средний измеренный модуль Юнга, около 200 ГПа, оказался значительно выше, чем во втором, 40 ГПа. Анализируются причины такого несоответствия.

АСМПЭМ in situнаномеханикаиндентированиемодуль ЮнгаAFMin-situ TEMnanomechanicsindentationYoung’s modulusThis work was supported by the Russian Science Foundation grant 19-13-00151. An access to the Libra 200 TEM and Hysitron PI-95 in-situ picoindenter was provided by the M.V. Lomonosov Moscow State University Program of Development.ReferencesKrasilin A.A., Khrapova E.K., Maslennikova T.P. Cation Doping Approach for Nanotubular Hydrosilicates Curvature Control and Related Applications. Crystals, 2020, 10(8), P. 654(1–41).Krasilin A.A., Khrapova E.K., Maslennikova T.P. Cation Doping Approach for Nanotubular Hydrosilicates Curvature Control and Related Applications. Crystals, 2020, 10(8), P. 654(1–41).Krasilin A.A. Energy modeling of competition between tubular and platy morphologies of chrysotile and halloysite layers. Clays Clay Miner., 2020, 68, P. 436–445.Krasilin A.A. Energy modeling of competition between tubular and platy morphologies of chrysotile and halloysite layers. Clays Clay Miner., 2020, 68, P. 436–445.Prinz V.Ya., Seleznev V.A., Gutakovsky A.K., Chehovskiy A.V., Preobrazhenskii V.V., Putyato M.A., Gavrilova T.A. Free-standing and overgrown InGaAs/GaAs nanotubes, nanohelices and their arrays. Physica E: Low-dimensional Systems and Nanostructures, 2000, 6, P. 828– 831.Prinz V.Ya., Seleznev V.A., Gutakovsky A.K., Chehovskiy A.V., Preobrazhenskii V.V., Putyato M.A., Gavrilova T.A. Free-standing and overgrown InGaAs/GaAs nanotubes, nanohelices and their arrays. Physica E: Low-dimensional Systems and Nanostructures, 2000, 6, P. 828– 831.Gulina L.B., Tolstoy V.B., Lobinsky A.A., Petrov Yu.V. Formation of Fe and Fe2O Microspirals via Interfacial Synthesis. Part. Part. Syst. Charact., 2018, 35, P. 1800186Gulina L.B., Tolstoy V.B., Lobinsky A.A., Petrov Yu.V. Formation of Fe and Fe2O Microspirals via Interfacial Synthesis. Part. Part. Syst. Charact., 2018, 35, P. 1800186Scarfato P., Avallone E., Incarnato L., Di Maio L. Development and evaluation of halloysite nanotube-based carrier for biocide activity in construction materials protection. Appl. Clay Sci., 2016, 132, P. 336–342.Scarfato P., Avallone E., Incarnato L., Di Maio L. Development and evaluation of halloysite nanotube-based carrier for biocide activity in construction materials protection. Appl. Clay Sci., 2016, 132, P. 336–342.Cavallaro G., Danilushkina A., Evtugyn V., Lazzara G., Milioto S., Parisi F., Rozhina E., Fakhrullin R. Halloysite Nanotubes: Controlled Access and Release by Smart Gates. Nanomaterials, 2017, 7(8), 199, P. 1–12.Cavallaro G., Danilushkina A., Evtugyn V., Lazzara G., Milioto S., Parisi F., Rozhina E., Fakhrullin R. Halloysite Nanotubes: Controlled Access and Release by Smart Gates. Nanomaterials, 2017, 7(8), 199, P. 1–12.Krasilin A.A., Danilovich D.P., Yudina E.B., Bruyere S., Ghanbaja J., Ivanov V.K. Crystal violet adsorption by oppositely twisted heat-treated halloysite and pecoraite nanoscrolls. Appl. Clay Sci., 2019, 173, P. 1–11.Krasilin A.A., Danilovich D.P., Yudina E.B., Bruyere S., Ghanbaja J., Ivanov V.K. Crystal violet adsorption by oppositely twisted heat-treated halloysite and pecoraite nanoscrolls. Appl. Clay Sci., 2019, 173, P. 1–11.Zhang C., Zhu W., Li S., Wu G., Ma X., Wang X., Gong J. Sintering-resistant Ni-based reforming catalysts obtained via the nanoconfinement effect. Chem. Commun., 2013, 49, P. 9383(1–3).Zhang C., Zhu W., Li S., Wu G., Ma X., Wang X., Gong J. Sintering-resistant Ni-based reforming catalysts obtained via the nanoconfinement effect. Chem. Commun., 2013, 49, P. 9383(1–3).Ashok J., Bian Z., Wang Z., Kawi S. Ni-phyllosilicate structure derived Ni–SiO2–MgO catalysts for bi-reforming applications: acidity, basicity and thermal stability. Catal. Sci. Technol., 2018, 8(6), P. 1730–1742.Ashok J., Bian Z., Wang Z., Kawi S. Ni-phyllosilicate structure derived Ni–SiO2–MgO catalysts for bi-reforming applications: acidity, basicity and thermal stability. Catal. Sci. Technol., 2018, 8(6), P. 1730–1742.Bian Z., Kawi S. Highly carbon-resistant Ni–Co/SiO2 catalysts derived from phyllosilicates for dry reforming of methane. J. CO2 Util., 2017, 18, P. 345–352.Bian Z., Kawi S. Highly carbon-resistant Ni–Co/SiO2 catalysts derived from phyllosilicates for dry reforming of methane. J. CO2 Util., 2017, 18, P. 345–352.Krasilin A.A., Straumal E.A., Yurkova L.L., Khrapova E.K., Tomkovich M.V., Shunina I.G., Vasil’eva L.P., Lermontov S.A., Ivanov V.K. Sulfated Halloysite Nanoscrolls as Superacid Catalysts for Oligomerization of Hexene-1. Russ. J. Appl. Chem., 2019, 92(9), P. 1251–1257.Krasilin A.A., Straumal E.A., Yurkova L.L., Khrapova E.K., Tomkovich M.V., Shunina I.G., Vasil’eva L.P., Lermontov S.A., Ivanov V.K. Sulfated Halloysite Nanoscrolls as Superacid Catalysts for Oligomerization of Hexene-1. Russ. J. Appl. Chem., 2019, 92(9), P. 1251–1257.Park J.C., Kang S.W., Kim J.-C., Kwon J.I., Jang S., Rhim G.B., Kim M., Chun D.H., Lee H.-T., Jung H., et al. Synthesis of Co/SiO2 hybrid nanocatalyst via twisted Co3Si2O5(OH)4 nanosheets for high-temperature Fischer–Tropsch reaction. Nano Res., 2017, 10(3), P. 1044–1055.Park J.C., Kang S.W., Kim J.-C., Kwon J.I., Jang S., Rhim G.B., Kim M., Chun D.H., Lee H.-T., Jung H., et al. Synthesis of Co/SiO2 hybrid nanocatalyst via twisted Co3Si2O5(OH)4 nanosheets for high-temperature Fischer–Tropsch reaction. Nano Res., 2017, 10(3), P. 1044–1055.Liu Y., Liu M. Conductive carboxylated styrene butadiene rubber composites by incorporation of polypyrrole-wrapped halloysite nanotubes. Compos. Sci. Technol., 2017, 143, P. 56–66.Liu Y., Liu M. Conductive carboxylated styrene butadiene rubber composites by incorporation of polypyrrole-wrapped halloysite nanotubes. Compos. Sci. Technol., 2017, 143, P. 56–66.Afanas’eva N.V., Gubanova G.N., Romashkova K.A., Sapegin D.A., Kononova S.V. Relaxation processes in an aromatic polyamide-imide and composites on its basis with hydrosilicate nanoparticles. Polym. Sci. Ser. A, 2016, 58(6), P. 956–967.Afanas’eva N.V., Gubanova G.N., Romashkova K.A., Sapegin D.A., Kononova S.V. Relaxation processes in an aromatic polyamide-imide and composites on its basis with hydrosilicate nanoparticles. Polym. Sci. Ser. A, 2016, 58(6), P. 956–967.Mo H., Yang K., Li S., Jiang P. High thermal conductivity and high impact strength of epoxy nanodielectrics with functionalized halloysite nanotubes. RSC Adv., 2016, 6(73), P. 69569–69579.Mo H., Yang K., Li S., Jiang P. High thermal conductivity and high impact strength of epoxy nanodielectrics with functionalized halloysite nanotubes. RSC Adv., 2016, 6(73), P. 69569–69579.Roy K., Debnath S.C., Pongwisuthiruchte A., Potiyaraj P. Up-to-date review on the development of high performance rubber composites based on halloysite nanotube. Appl. Clay Sci., 2019, 183, P. 105300(1–15).Roy K., Debnath S.C., Pongwisuthiruchte A., Potiyaraj P. Up-to-date review on the development of high performance rubber composites based on halloysite nanotube. Appl. Clay Sci., 2019, 183, P. 105300(1–15).Binnig G., Quate C.F., Gerber Ch. Atomic Force Microscope. Phys. Rev. Lett., 1986, 56(9), P. 930–933.Binnig G., Quate C.F., Gerber Ch. Atomic Force Microscope. Phys. Rev. Lett., 1986, 56(9), P. 930–933.Wong E.W., Sheehan P.E., Lieber C.M. Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes. Science, 1997, 277(5334), P. 1971–1975.Wong E.W., Sheehan P.E., Lieber C.M. Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes. Science, 1997, 277(5334), P. 1971–1975.Bhushan B. edd. Nanotribology and Nanomechanics - An Introduction. Springer-Verlag Berlin Heidelberg, 2005, 1148 p.Bhushan B. edd. Nanotribology and Nanomechanics - An Introduction. Springer-Verlag Berlin Heidelberg, 2005, 1148 p.Salvetat J.-P., Kulik A.J., Bonard J.-M., Briggs G.A.D., Stockli T., Me´te´nier K., Bonnamy S., Be´guin F., Burnham N.A., Forro´ L. Elastic Modulus of Ordered and Disordered Multiwalled Carbon Nanotubes. Adv. Mater., 1999, 11(2), P. 161–165.Salvetat J.-P., Kulik A.J., Bonard J.-M., Briggs G.A.D., Stockli T., Me´te´nier K., Bonnamy S., Be´guin F., Burnham N.A., Forro´ L. Elastic Modulus of Ordered and Disordered Multiwalled Carbon Nanotubes. Adv. Mater., 1999, 11(2), P. 161–165.Salvetat J.-P., Bonard J.-M., Thomson N.H., Kulik A.J., Forro´ L., Benoit W., Zuppiroli L. Mechanical properties of carbon nanotubes. Appl. Phys. A, 1999, 69(3), P. 255–260.Salvetat J.-P., Bonard J.-M., Thomson N.H., Kulik A.J., Forro´ L., Benoit W., Zuppiroli L. Mechanical properties of carbon nanotubes. Appl. Phys. A, 1999, 69(3), P. 255–260.Zheng X.-P., Cao Y.-P., Li B., Feng X.-Q., Wang G.-F. Surface effects in various bending-based test methods for measuring the elastic property of nanowires. Nanotechnology, 2010, 21(20), P. 205702(1–6).Zheng X.-P., Cao Y.-P., Li B., Feng X.-Q., Wang G.-F. Surface effects in various bending-based test methods for measuring the elastic property of nanowires. Nanotechnology, 2010, 21(20), P. 205702(1–6).Timoshenko S., Goodier J.N. Theory of elasticity. McGraw-Hill, New York, 1970, 567 p.Timoshenko S., Goodier J.N. Theory of elasticity. McGraw-Hill, New York, 1970, 567 p.Landau L.D., Lifshitz E.M. Theory of Elasticity. Pergamon Press Ltd., Oxford, 1970, 165 p.Landau L.D., Lifshitz E.M. Theory of Elasticity. Pergamon Press Ltd., Oxford, 1970, 165 p.Cuenot S., Demoustuer-Champagne S., Nysten B. Elastic modulus of polypyrrole nanotubes. Phys. Rev. Lett., 2000, 85(8), P. 1690–1693.Cuenot S., Demoustuer-Champagne S., Nysten B. Elastic modulus of polypyrrole nanotubes. Phys. Rev. Lett., 2000, 85(8), P. 1690–1693.Kis S. Mechanical properties of mesoscopic objects. Thesis. Ecole Polytechnique Federale de Lausanne, 2003, 166 p.Kis S. Mechanical properties of mesoscopic objects. Thesis. Ecole Polytechnique Federale de Lausanne, 2003, 166 p.Bruker Hysitron nanomechanical test instruments. URL: https://www.bruker.com/products/surface-and-dimensional-analysis/nanomechanical-test-instruments.htmlBruker Hysitron nanomechanical test instruments. URL: https://www.bruker.com/products/surface-and-dimensional-analysis/nanomechanical-test-instruments.htmlKhrapova E.K., Ugolkov V.L., et al. Thermal behavior of Mg-Ni-phyllosilicate nanoscrolls and performance of the resulting composites in hexane-1 and acetone hydrogenation. Chem. Nano. Mat., 2020, P. 1–14.Khrapova E.K., Ugolkov V.L., et al. Thermal behavior of Mg-Ni-phyllosilicate nanoscrolls and performance of the resulting composites in hexane-1 and acetone hydrogenation. Chem. Nano. Mat., 2020, P. 1–14.Ankudinov A.V. A New Algorithm for Measuring the Young’s Modulus of Suspended Nanoobjects by the Bending-Based Test Method of Atomic Force Microscopy. Semiconductors, 2019, 53(14), P. 1891–1899.Ankudinov A.V. A New Algorithm for Measuring the Young’s Modulus of Suspended Nanoobjects by the Bending-Based Test Method of Atomic Force Microscopy. Semiconductors, 2019, 53(14), P. 1891–1899.Ankudinov A.V., Khalisov M.M. Contact Stiffness Measurements with an Atomic Force Microscope. Technical Physics, 2020, 65(11), P. 1866–1872.Ankudinov A.V., Khalisov M.M. Contact Stiffness Measurements with an Atomic Force Microscope. Technical Physics, 2020, 65(11), P. 1866–1872.Nečas D., Klapetek P. Gwyddion: an open-source software for SPM data analysis. Cent. Eur. J. Phys., 2012, 10(1), P. 181–188.Nečas D., Klapetek P. Gwyddion: an open-source software for SPM data analysis. Cent. Eur. J. Phys., 2012, 10(1), P. 181–188.Sader J.E., Chon J.W.M., Mulvaney P. Calibration of rectangular atomic force microscope cantilever. Rev. Sci. Instrum., 1999, 70, P. 3967–3969Sader J.E., Chon J.W.M., Mulvaney P. Calibration of rectangular atomic force microscope cantilever. Rev. Sci. Instrum., 1999, 70, P. 3967–3969Brewe D.E., Hamrock B.J. Simplified solution for elliptical contact deformation between two elastic solids. J. Lubrication Technology, 1977, 99 (4), P. 485–487.Brewe D.E., Hamrock B.J. Simplified solution for elliptical contact deformation between two elastic solids. J. Lubrication Technology, 1977, 99 (4), P. 485–487.Popov V.L., Heß M., Willert E. Handbook of Contact Mechanics. Exact Solutions of Axisymmetric Contact Problems. Translation from the German Language edition: Popov et al: Handbuch der Kontaktmechanik. Springer-Verlag GmbH Deutschland, 2018, 347 p.Popov V.L., Heß M., Willert E. Handbook of Contact Mechanics. Exact Solutions of Axisymmetric Contact Problems. Translation from the German Language edition: Popov et al: Handbuch der Kontaktmechanik. Springer-Verlag GmbH Deutschland, 2018, 347 p.

The authors declare that there are no conflicts of interest present.