najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2020-11-5-529-536najo-393Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХA facile low-temperature deposition of Sn-rich tin (II) monosulfide colloid particlesKozhevnikovaN. S.

Pervomayskaya, 91, Ekaterinburg, 620990

kozhevnikova@ihim.uran.ruMaskaevaL. N.

Mira, 9, Ekaterinburg, 620002

Mira str. 22, 620062, Ekaterinburg 

larisamaskaeva@yandex.ruLekomtsevaE. E.

Mira, 9, Ekaterinburg, 620002

danserkatya13@mail.ruPasechnikL. A.

Pervomayskaya, 91, Ekaterinburg, 620990

pasechnik@ihim.uran.ruChufarovA. Yu.

Pervomayskaya, 91, Ekaterinburg, 620990

circulchufa@gmail.comLipinaO. A.

Pervomayskaya, 91, Ekaterinburg, 620990

lipinaolgaa@yandex.ruEnyashinA. N.

Pervomayskaya, 91, Ekaterinburg, 620990

enyashin@ihim.uran.ruMarkovV. F.

Mira, 9, Ekaterinburg, 620002

Mira str. 22, 620062, Ekaterinburg 

v.f.markov@urfu.ruInstitute of Solid State Chemistry of Ural Branch of the Russian Academy of SciencesRussian FederationUral Federal University named B. N. Yeltsin; Ural Institute of State Fire Service of EMERCOM of RussiaRussian FederationUral Federal University named B. N. YeltsinRussian Federation202029072025115529–536Copyright © Kozhevnikova N.S., Maskaeva L.N., Lekomtseva E.E., Pasechnik L.A., Chufarov A.Y., Lipina O.A., Enyashin A.N., Markov V.F., 20252025Kozhevnikova N.S., Maskaeva L.N., Lekomtseva E.E., Pasechnik L.A., Chufarov A.Y., Lipina O.A., Enyashin A.N., Markov V.F.Kozhevnikova N.S., Maskaeva L.N., Lekomtseva E.E., Pasechnik L.A., Chufarov A.Y., Lipina O.A., Enyashin A.N., Markov V.F.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/393

A novel, eco-friendly and low temperature synthesis of tin (II) monosulfide colloid particles is described. Chemical bath deposition was successfully applied for the deposition of polynanocrystalline SnS from acidic aqueous solutions. The characterization of the prepared samples was accomplished through elemental analysis, scanning electron microscopy, X-ray powder diffraction, and optical spectroscopy. The composition of tin (II) monosulfide colloids assembled of nanoparticles was found to be Sn-rich. Several simple scenarios for Sn surplus within SnS lattice (Svacancies at S-sublattice, Sn-atoms intercalated between SnS layers and Sn-doping of S-sites) have been analyzed by means of quantum chemical calculations. The potential application of the Sn1+xS colloid particles in solar cells as absorber material and as photocatalyst was demonstrated by measuring the optical properties.

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The authors declare that there are no conflicts of interest present.