najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2024-15-4-498-509najo-42Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХKinetic of colloidal-chemical transformations during the decomposition of ammonia complexes of Zn(II) in alkaline solutions.Кинетика коллоидно-химических превращений при разложении аммиачных комплексов Zn(II) в щелочных растворахhttps://orcid.org/0009-0004-2807-2222МаксимоваМ. А.MaksimovaM. A.

Maria A. Maksimova

91, Pervomaiskaya str., 620108, Ekaterinburg

msalimova1993@gmail.comhttps://orcid.org/0000-0001-7432-994XПоляковЕ. В.PolyakovE. V.

Evgeny V. Polyakov

91, Pervomaiskaya str., 620108, Ekaterinburg

polyakov@ihim.uran.ruhttps://orcid.org/0000-0001-8009-952XВолковИ. В.VolkovI. V.

Ilya V. Volkov

91, Pervomaiskaya str., 620108, Ekaterinburg

https://orcid.org/0000-0002-6394-4514ТютюнникА. П.TyutyunnikA. P.

Aleksandr P. Tyutyunnik 

91, Pervomaiskaya str., 620108, Ekaterinburg

https://orcid.org/0009-0008-4679-1836ИошинА. А.IoshinA. A.

Alexey A. Ioshin

91, Pervomaiskaya str., 620108, Ekaterinburg

aaioshin@yandex.ruISSC UB RASRussian Federation202431052025154498509Copyright © Maksimova M.A., Polyakov E.V., Volkov I.V., Tyutyunnik A.P., Ioshin A.A., 20252025Максимова М.А., Поляков Е.В., Волков И.В., Тютюнник А.П., Иошин А.А.Maksimova M.A., Polyakov E.V., Volkov I.V., Tyutyunnik A.P., Ioshin A.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/42

For the closed system (Σ): Zn2+–NH3,aq –NH3,gas, H+–OH−–N2,gas, experimental data on the change in the concentration of in the composition of the ammonia complex Zn(NH3)2+ 4 in solution, colloidal particles Zn(OH)2/ZnO in solution and growing film on the reactor walls are presented depending on the synthesis time, zinc concentration and synthesis temperature Ts in the range of 50 –99 ◦C. It has been established that up to 95 ◦C the ion-molecular growth of Zn(OH)2/ZnO clusters in solution (Σ) proceeds in a diffusion-controlled mode of homogeneous growth until reaching of their critical size. Further growth of ther critical clusters is followed by aggregation and coalescence of critical sized clusters into microcrystals with the formation of a film on a glass substrate of various morphologies. The solubility of such a film is determined by the size of critical clusters, which preserves in the growing polycrystal in the form of coherent scattering region (CSR). With an increase in the synthesis temperature to 99 ◦C, the aggregation mechanism is replaced by a faster diffusion-controlled attachment of Zn (II) ammonia complex to the end surface of the growing microcrystals simultaneously in colloid solution and in the film.

Для замкнутой системы (S): “Zn2+ - NH3,aq - NH3,gas, H+ - OH- - N2,gas представлены экспериментальные данные по изменению концентрации Zn(II) в составе аммиачного комплекса Zn(NH3)42+ в растворе, коллоидных частиц Zn(OH)2/ZnO в растворе и растущей плёнки на стенках реактора в зависимости от времени синтеза, концентрации цинка и температуры синтеза Ts в диапазоне 50 - 99 °С. Установлено, что до 95 °С ионно-молекулярный рост кластеров Zn(OH)2/ZnO в растворе (S) протекает в диффузионно-контролируемом режиме гомогенного роста до достижения их критического размера. Дальнейший рост критических кластеров сопровождается агрегацией и слиянием кластеров критического размера в микрокристаллы с образованием на стеклянной подложке плёнки различной морфологии. Растворимость такой плёнки определяется размерами критических кластеров, которые сохраняются в растущем поликристалле в виде областей когерентного рассеяния (ОКР). При повышении температуры синтеза до 99°С механизм агрегации сменяется более быстрым диффузионно-контролируемым присоединением аммиачного комплекса Zn (II) к торцевой поверхности растущих микрокристаллов одновременно в коллоидном растворе и в плёнке.

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The authors declare that there are no conflicts of interest present.