<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2020-11-3-316-323</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-428</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMISTRY AND MATERIALS SCIENCE</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЯ И НАУКА О МАТЕРИАЛАХ</subject></subj-group></article-categories><title-group><article-title>Near infrared down-conversion luminescence of Ba4Y3F17:Yb3+:Eu3+ nanoparticles under ultraviolet excitation</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Kuznetsov</surname><given-names>S. V.</given-names></name></name-alternatives><email xlink:type="simple">kouznetzovsv@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Nizamutdinov</surname><given-names>A. S.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Madirov</surname><given-names>E. I.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Voronov</surname><given-names>V. V.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Tsoy</surname><given-names>K. S.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Khadiev</surname><given-names>А. R.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Yapryntsev</surname><given-names>A. D.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Ivanov</surname><given-names>V. K.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Kharintsev</surname><given-names>S. S.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Semashko</surname><given-names>V. V.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>Prokhorov General Physics Institute of the Russian Academy of Sciences</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-2"><institution>Kazan Federal University</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-3"><institution>Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2020</year></pub-date><pub-date pub-type="epub"><day>30</day><month>07</month><year>2025</year></pub-date><volume>11</volume><issue>3</issue><elocation-id>316–323</elocation-id><permissions><copyright-statement>Copyright &amp;#x00A9; Kuznetsov S.V., Nizamutdinov A.S., Madirov E.I., Voronov V.V., Tsoy K.S., Khadiev А.R., Yapryntsev A.D., Ivanov V.K., Kharintsev S.S., Semashko V.V., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Kuznetsov S.V., Nizamutdinov A.S., Madirov E.I., Voronov V.V., Tsoy K.S., Khadiev А.R., Yapryntsev A.D., Ivanov V.K., Kharintsev S.S., Semashko V.V.</copyright-holder><copyright-holder xml:lang="en">Kuznetsov S.V., Nizamutdinov A.S., Madirov E.I., Voronov V.V., Tsoy K.S., Khadiev А.R., Yapryntsev A.D., Ivanov V.K., Kharintsev S.S., Semashko V.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/428">https://nanojournal.ifmo.ru/jour/article/view/428</self-uri><abstract><p>The single-phase solid solutions Ba4Y3F17:Yb:Eu with fluorite-type structure were synthesized by co-precipitation from aqueous solution technique. The average particle size was approximately 100 nm without agglomeration. The sensitized down-conversion luminescence of Yb3+ ions was observed under 296 nm excitation. The quantum yield of Yb3+ luminescence was found to reach avalue of 0.4 % for samples with Eu/Yb ratios of 0.1/1.0 and 0.1/10.0.</p></abstract><kwd-group xml:lang="en"><kwd>nanofluoride</kwd><kwd>down-conversion</kwd><kwd>luminescence</kwd></kwd-group><funding-group><funding-statement xml:lang="en">This work was supported by the Russian Science Foundation, grant 17-73-20352. Authors thank to M.N. Mayakova for valuable help in sample preparation.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Weber E.R. Photovoltaics moving into the terawatt age. Proc. SPIE, Next Generation Technologies for Solar Energy Conversion VIII, 2017, 10368, 1036803.</mixed-citation><mixed-citation xml:lang="en">Weber E.R. Photovoltaics moving into the terawatt age. Proc. SPIE, Next Generation Technologies for Solar Energy Conversion VIII, 2017, 10368, 1036803.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Lehr J., Langenhorst M., et al. Energy yield of bifacial textured perovskite/silicon tandem photovoltaic modules. Solar Energy Materials and Solar Cells, 2020, 208, 110367 P. 1–9.</mixed-citation><mixed-citation xml:lang="en">Lehr J., Langenhorst M., et al. Energy yield of bifacial textured perovskite/silicon tandem photovoltaic modules. Solar Energy Materials and Solar Cells, 2020, 208, 110367 P. 1–9.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Im J.-H., Lee C.-R., et al. 6.5 % efficient perovskite quantum-dot-sensitized solar cell. Nanoscale, 2011, 3, P. 4088–4093.</mixed-citation><mixed-citation xml:lang="en">Im J.-H., Lee C.-R., et al. 6.5 % efficient perovskite quantum-dot-sensitized solar cell. Nanoscale, 2011, 3, P. 4088–4093.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Han G., Zhang S., et al. Towards high efficiency thin film solar cells. Prog. Mater. Sci., 2017, 87, P. 246–291.</mixed-citation><mixed-citation xml:lang="en">Han G., Zhang S., et al. Towards high efficiency thin film solar cells. Prog. Mater. Sci., 2017, 87, P. 246–291.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Huang X., Han S., Huang W., Liu X., Enhancing solar cell efficiency: the search for luminescent materials as spectral converters. Chem. Soc. Rev., 2013, 42, P. 173–201.</mixed-citation><mixed-citation xml:lang="en">Huang X., Han S., Huang W., Liu X., Enhancing solar cell efficiency: the search for luminescent materials as spectral converters. Chem. Soc. Rev., 2013, 42, P. 173–201.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Moraitis P., Schropp R.E.I., Sark W.G.J.H.M. Nanoparticles for luminescent solar concentrators – a review. Opt. Mater., 2018, 84, P. 636–645.</mixed-citation><mixed-citation xml:lang="en">Moraitis P., Schropp R.E.I., Sark W.G.J.H.M. Nanoparticles for luminescent solar concentrators – a review. Opt. Mater., 2018, 84, P. 636–645.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Green M.A., Bremner S.P. Energy conversion approaches and materials for high efficiency photovoltaics. Nat. Mater., 2017, 16, P. 23–34.</mixed-citation><mixed-citation xml:lang="en">Green M.A., Bremner S.P. Energy conversion approaches and materials for high efficiency photovoltaics. Nat. Mater., 2017, 16, P. 23–34.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Trupke T., Green M.A., Wurfel P. Improving solar cell efficiencies by down-conversion of high-energy photons.¨ J. Appl. Phys., 2002, 92, P. 1668–1674.</mixed-citation><mixed-citation xml:lang="en">Trupke T., Green M.A., Wurfel P. Improving solar cell efficiencies by down-conversion of high-energy photons.¨ J. Appl. Phys., 2002, 92, P. 1668–1674.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Yu P., Yao Y., et al. Effects of plasmonic metal core-dielectric shell nanoparticles on the broadband light absorption enhancement in thin film solar cells. Sci. Rep., 2017, 7, P. 7696.</mixed-citation><mixed-citation xml:lang="en">Yu P., Yao Y., et al. Effects of plasmonic metal core-dielectric shell nanoparticles on the broadband light absorption enhancement in thin film solar cells. Sci. Rep., 2017, 7, P. 7696.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Fang D., Zhang X., et al. Application of bidirectional (up and down)-conversion luminescence material (GdBO3:Yb3+/Tb3+) in CdSe0.4S0.6 quantum dot-sensitized solar cells. Opt. Mater., 2019, 88, P. 80–90.</mixed-citation><mixed-citation xml:lang="en">Fang D., Zhang X., et al. Application of bidirectional (up and down)-conversion luminescence material (GdBO3:Yb3+/Tb3+) in CdSe0.4S0.6 quantum dot-sensitized solar cells. Opt. Mater., 2019, 88, P. 80–90.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Gu H., Wang J., et al. The core-shell-structured NaYF4:Er3+, Yb3+@NaYF4:Eu3+ nanocrystals as dual-mode and multifunctional luminescent mechanism for high-performance dye-sensitized solar cells. Mater. Res. Bull., 2018, 108, P. 219–225.</mixed-citation><mixed-citation xml:lang="en">Gu H., Wang J., et al. The core-shell-structured NaYF4:Er3+, Yb3+@NaYF4:Eu3+ nanocrystals as dual-mode and multifunctional luminescent mechanism for high-performance dye-sensitized solar cells. Mater. Res. Bull., 2018, 108, P. 219–225.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Buarque J.M.M., Manzani D., et al. SiO2–TiO2 doped with Er3+/Yb3+/Eu3+ photoluminescent material: a spectroscopy and structural study about potential applicationfor improvement of the efficiency on solar cells. Mater. Res. Bull., 2018, 107, P. 295–307.</mixed-citation><mixed-citation xml:lang="en">Buarque J.M.M., Manzani D., et al. SiO2–TiO2 doped with Er3+/Yb3+/Eu3+ photoluminescent material: a spectroscopy and structural study about potential applicationfor improvement of the efficiency on solar cells. Mater. Res. Bull., 2018, 107, P. 295–307.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Rajesh D., Dousti M.R., Amjad R.J., Camargo A.S.S. Quantum cutting and upconversion investigations in Pr3+/Yb3+ co-doped oxyfluorotellurite glasses. J. Non-Cryst. Solids, 2016, 450, P. 149–155.</mixed-citation><mixed-citation xml:lang="en">Rajesh D., Dousti M.R., Amjad R.J., Camargo A.S.S. Quantum cutting and upconversion investigations in Pr3+/Yb3+ co-doped oxyfluorotellurite glasses. J. Non-Cryst. Solids, 2016, 450, P. 149–155.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Kuznetsov S.V., Nizamutdinov A.S., et al. Synthesis and down-conversion luminescence of Ba4Y3F17:Yb:Pr solid solutions for photonics. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10, P. 190–198.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.V., Nizamutdinov A.S., et al. Synthesis and down-conversion luminescence of Ba4Y3F17:Yb:Pr solid solutions for photonics. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10, P. 190–198.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Li T., Li Y., et al. Novel Ba(Gd1−xYx)0.78F5: 20 mol % Yb3+, 2 mol % Tm3+ (0 &lt; x &lt; 1.0) solid solution nanocrystals: A facile hydrothermal controlled synthesis, enhanced upconversion luminescent and paramagnetic properties. J. Alloys Comp., 2018, 740, P. 1204– 1214.</mixed-citation><mixed-citation xml:lang="en">Li T., Li Y., et al. Novel Ba(Gd1−xYx)0.78F5: 20 mol % Yb3+, 2 mol % Tm3+ (0 &lt; x &lt; 1.0) solid solution nanocrystals: A facile hydrothermal controlled synthesis, enhanced upconversion luminescent and paramagnetic properties. J. Alloys Comp., 2018, 740, P. 1204– 1214.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Karbowiak M., Cichos J. Does BaYF5 nanocrystals exist? The BaF2–YF3 solid solution revisited using photoluminescence spectroscopy. Journal of Alloys and Compounds, 2016, 673, P. 258–264.</mixed-citation><mixed-citation xml:lang="en">Karbowiak M., Cichos J. Does BaYF5 nanocrystals exist? The BaF2–YF3 solid solution revisited using photoluminescence spectroscopy. Journal of Alloys and Compounds, 2016, 673, P. 258–264.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P., Kuznetsov S.V., et al. Coprecipitation from aqueous solutions to prepare binary fluorides. Russian J. of Inorg. Chem., 2011, 56, P. 1525–1531.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P., Kuznetsov S.V., et al. Coprecipitation from aqueous solutions to prepare binary fluorides. Russian J. of Inorg. Chem., 2011, 56, P. 1525–1531.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Kuznetsov S.V., Proydakova V.Yu., et al. Synthesis and quantum yield investigations of the Sr1−x−yPrxYbyF2+x+y luminophores for photonics. Nanosystems: Physics, Chemistry, Mathematics, 2018, 9, P. 663–668.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.V., Proydakova V.Yu., et al. Synthesis and quantum yield investigations of the Sr1−x−yPrxYbyF2+x+y luminophores for photonics. Nanosystems: Physics, Chemistry, Mathematics, 2018, 9, P. 663–668.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Kuznetsov S.V., Morozov O.A., et al. Ca1−x−yYbxPryF2+x+y solid solution powders as a promising materials for crystalline silicon solar energetics. Nanosystems: Physics, Chemistry, Mathematics, 2018, 9, P. 259–265.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.V., Morozov O.A., et al. Ca1−x−yYbxPryF2+x+y solid solution powders as a promising materials for crystalline silicon solar energetics. Nanosystems: Physics, Chemistry, Mathematics, 2018, 9, P. 259–265.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Kuznetsov S.V., Nizamutdinov A.S., et al. Synthesis and Luminescence of Sr1−x−yYbxEuyF2+x+y. Solid Solutions for Photonics. Inorganic Materials, 2019, 55, P. 1031–1038.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.V., Nizamutdinov A.S., et al. Synthesis and Luminescence of Sr1−x−yYbxEuyF2+x+y. Solid Solutions for Photonics. Inorganic Materials, 2019, 55, P. 1031–1038.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Yasyrkina D.S., Kuznetsov S.V., et al. Dependence of quantum yield of up-conversion luminescence on the composition of fluorite-type solid solution NaY1−x−yYbxEryF4. Nanosystems: Physics, Chemistry, Mathematics, 2013, 4, P. 648–656.</mixed-citation><mixed-citation xml:lang="en">Yasyrkina D.S., Kuznetsov S.V., et al. Dependence of quantum yield of up-conversion luminescence on the composition of fluorite-type solid solution NaY1−x−yYbxEryF4. Nanosystems: Physics, Chemistry, Mathematics, 2013, 4, P. 648–656.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Kuznetsov S.V., Fedorov P.P., et al. Synthesis of Ba4R3F17 (R stands for Rare-Earth Elements) Powders and Transparent Compacts on Their Base. Russian Journal of Inorganic Chemistry, 2010, 55, P. 484–493.</mixed-citation><mixed-citation xml:lang="en">Kuznetsov S.V., Fedorov P.P., et al. Synthesis of Ba4R3F17 (R stands for Rare-Earth Elements) Powders and Transparent Compacts on Their Base. Russian Journal of Inorganic Chemistry, 2010, 55, P. 484–493.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Semashko V.V. Problems in searching for new solid-state UV- and VUV active media: the role of photodynamic processes. Phys. of Solid State, 2005, 47, P. 1507–1511.</mixed-citation><mixed-citation xml:lang="en">Semashko V.V. Problems in searching for new solid-state UV- and VUV active media: the role of photodynamic processes. Phys. of Solid State, 2005, 47, P. 1507–1511.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Van der Voort D., Dirksen G.J., Blasse G. Luminescence study of Eu3+–O2− associates in fluorides: CaF2, RbCdF3, and RbCaF3. J. Phys. Chem. Solids, 1992, 53, P. 219–225.</mixed-citation><mixed-citation xml:lang="en">Van der Voort D., Dirksen G.J., Blasse G. Luminescence study of Eu3+–O2− associates in fluorides: CaF2, RbCdF3, and RbCaF3. J. Phys. Chem. Solids, 1992, 53, P. 219–225.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Dwivedi Y., Zilio S.C. Infrared cascade and cooperative multicolor upconversion emissions in Y8V2O17:Eu:Yb nanophosphors. Opt. Express, 2013, 21, P. 4717–4727.</mixed-citation><mixed-citation xml:lang="en">Dwivedi Y., Zilio S.C. Infrared cascade and cooperative multicolor upconversion emissions in Y8V2O17:Eu:Yb nanophosphors. Opt. Express, 2013, 21, P. 4717–4727.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
