najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2020-11-2-205-213najo-446Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХCryometry and excess thermodynamic functions in water soluble of the fullerenol C60(OH)24CharykovN. A.

Moskovsky prospect, 26 Saint-Petersburg, 190013

ul. Professora Popova 5, 197376 St. Petersburg

SemenovK. N.

Moskovsky prospect, 26 Saint-Petersburg, 190013

7/9 Universitetskaya emb., Saint-Petersburg, 199034

L’va Tolstogo str. 6-8 Saint Petersburg, 197022

KeskinovV. A.

Moskovsky prospect, 26 Saint-Petersburg, 190013

keskinov@mail.ruKulenovaV. A.

A.K. Protozanov Street, 69, Ust-Kamenogorsk city, 070004

ShaimardanovZ. K.

A.K. Protozanov Street, 69, Ust-Kamenogorsk city, 070004

ShaimardanovaB. K.

A.K. Protozanov Street, 69, Ust-Kamenogorsk city, 070004

GerasimovaL. V.

Moskovsky prospect, 26 Saint-Petersburg, 190013

KanbarAyat

Moskovsky prospect, 26 Saint-Petersburg, 190013

LetenkoD. G.

2-nd Krasnoarmeiskaya St. 4, 190005 St. Petersburg

St. Petersburg State Technological Institute (Technical University); St. Petersburg Electrotechnical University “LETI”Russian FederationSt. Petersburg State Technological Institute (Technical University); St. Petersburg State University; Pavlov First Saint Petersburg State Medical UniversityRussian FederationSt. Petersburg State Technological Institute (Technical University)Russian FederationD. Serikbayev East Kazakhstan state technical universityKazakhstanSt. Petersburg State University of Architecture and Civil Engineering (SPSUACE)Russian Federation202030072025112205–213Copyright © Charykov N.A., Semenov K.N., Keskinov V.A., Kulenova V.A., Shaimardanov Z.K., Shaimardanova B.K., Gerasimova L.V., Kanbar A., Letenko D.G., 20252025Charykov N.A., Semenov K.N., Keskinov V.A., Kulenova V.A., Shaimardanov Z.K., Shaimardanova B.K., Gerasimova L.V., Kanbar A., Letenko D.G.Charykov N.A., Semenov K.N., Keskinov V.A., Kulenova V.A., Shaimardanov Z.K., Shaimardanova B.K., Gerasimova L.V., Kanbar A., Letenko D.G.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/446

The temperature of water-ice crystallization initiation decreases (∆T) were determined in the binary water solutions of water soluble fullerenol: C60(OH)24 − H2O at 272.85–273.15 K. Solution concentrations (in molar fractions) vary over a wide range xnano−cluster = 5.0 · 10−6 ÷ 1.6 · 10−4 a.un. Liquidus temperatures were determined with the help of Beckman thermometer with a linear resolution of the device scale ∆T ≈ 0.01 K/mm (h – height of Hg capillary raising). For the thermodynamic description of the discussed systems, we have elaborated an ∆h original semi-empirical model, the virial decomposition asymmetric model (VD-AS), with assistance from partial molar functions of nano-clusters (activities and activity coefficients) were calculated. The Gibbs energies for the solutions and miscibility gap concentration regions were calculated. VD-AS model excellently describes pre-delamination or micro-heterogeneous-structure formation in the considered solutions. These calculations are confirmed by the dynamic light scattering data.

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The authors declare that there are no conflicts of interest present.