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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2021-12-4-436-441</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-478</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PHYSICS</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ФИЗИКА</subject></subj-group></article-categories><title-group><article-title>Ti3C2Tx thin film as a saturable absorber for passively generating Q-switched pulses in thulium-doped fiber laser cavity</article-title><trans-title-group xml:lang="ru"><trans-title>Тонкая пленка Ti3C2Tx в качестве насыщающегося поглотителя для пассивной генерации импульсов с модуляцией добротности в резонаторе волоконного лазера, легированного тулием</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Buntat</surname><given-names>M. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Buntat</surname><given-names>M. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Hang Tuah Jaya, 76100 Durian Tunggal, Melaka.</p></bio><bio xml:lang="en"><p>Hang Tuah Jaya, 76100 Durian Tunggal, Melaka.</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Rosol</surname><given-names>A. H.A.</given-names></name><name name-style="western" xml:lang="en"><surname>Rosol</surname><given-names>A. H.A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>50603 Kuala Lumpur.</p></bio><bio xml:lang="en"><p>50603 Kuala Lumpur.</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Rusdi</surname><given-names>M. F.M.</given-names></name><name name-style="western" xml:lang="en"><surname>Rusdi</surname><given-names>M. F.M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>50603 Kuala Lumpur.</p></bio><bio xml:lang="en"><p>50603 Kuala Lumpur.</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Latif</surname><given-names>A. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Latif</surname><given-names>A. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Hang Tuah Jaya, 76100 Durian Tunggal, Melaka.</p></bio><bio xml:lang="en"><p>Hang Tuah Jaya, 76100 Durian Tunggal, Melaka.</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Yasin</surname><given-names>M.</given-names></name><name name-style="western" xml:lang="en"><surname>Yasin</surname><given-names>M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Surabaya.</p></bio><bio xml:lang="en"><p>Surabaya.</p></bio><email xlink:type="simple">yasin@fst.unair.ac.id</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Harun</surname><given-names>S. W.</given-names></name><name name-style="western" xml:lang="en"><surname>Harun</surname><given-names>S. W.</given-names></name></name-alternatives><bio xml:lang="ru"><p>50603 Kuala Lumpur.</p></bio><bio xml:lang="en"><p>50603 Kuala Lumpur.</p></bio><email xlink:type="simple">swharun@um.edu.my</email><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Universiti Teknikal Malaysia Melaka, Fakulti Kejuruteraan Elektronik dan Kejuruteraan Komputer<country>Малайзия</country></aff><aff xml:lang="en">Universiti Teknikal Malaysia Melaka, Fakulti Kejuruteraan Elektronik dan Kejuruteraan Komputer<country>Malaysia</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru">University of Malaya, Photonics Engineering Laboratory, Department of Electrical Engineering, Faculty of Engineering<country>Малайзия</country></aff><aff xml:lang="en">University of Malaya, Photonics Engineering Laboratory, Department of Electrical Engineering, Faculty of Engineering<country>Malaysia</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru">Airlangga University, Department of Physics, Faculty of Science and Technology<country>Малайзия</country></aff><aff xml:lang="en">Airlangga University, Department of Physics, Faculty of Science and Technology<country>Malaysia</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2021</year></pub-date><pub-date pub-type="epub"><day>04</day><month>08</month><year>2025</year></pub-date><volume>12</volume><issue>4</issue><fpage>436</fpage><lpage>441</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Buntat M.A., Rosol A.H., Rusdi M.F., Latif A.A., Yasin M., Harun S.W., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Buntat M.A., Rosol A.H., Rusdi M.F., Latif A.A., Yasin M., Harun S.W.</copyright-holder><copyright-holder xml:lang="en">Buntat M.A., Rosol A.H., Rusdi M.F., Latif A.A., Yasin M., Harun S.W.</copyright-holder><license license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/478">https://nanojournal.ifmo.ru/jour/article/view/478</self-uri><abstract><p>We demonstrated a Q-switched thulium-doped fiber laser (TDFL) based on Mxene Ti3C2Tx saturable absorber (SA) as Q-switcher. Ti3C2Tx was obtained using selective etching and embedded into polyvinyl alcohol (PVA) film. As the film was added into a TDFL cavity, a stable Q-switched pulse train operating at 1996 nm was produced within a single mode 1552 nm pump power range from 161.8 to 237.1 mW. When the pump power was varied within this range, the repetition rate increased from 19.6 to 33.3 kHz while the pulse width decreases from 6.71 to 3.55 µs. To the best of our knowledge, this is the first report of a Ti3C2Tx SA for passively generating Q-switched pulses in the 2 µm wavelength region.</p></abstract><trans-abstract xml:lang="ru"><p>Мы продемонстрировали волоконный лазер с модуляцией добротности, легированный тулием (TDFL), на основе насыщающегося поглотителя (SA) Mxene Ti3C2Tx в качестве модулятора добротности. Ti3C2Tx был получен с помощью селективного травления и залит в пленку поливинилового спирта (ПВС). Когда пленка была добавлена в резонатор TDFL, стабильная последовательность импульсов с модуляцией добротности, работающая на длине волны 1996 нм, была получена в одномодовом диапазоне мощности накачки 1552 нм от 161,8 до 237,1 мВт. При изменении мощности накачки в этом диапазоне частота повторения увеличивается с 19,6 до 33,3 кГц, а длительность импульса уменьшается с 6,71 до 3,55 мкс. Насколько нам известно, это первый отчет о Ti3C2Tx SA для пассивной генерации импульсов с модуляцией добротности в диапазоне длин волн 2 мкм.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>MXene Ti3C2Tx</kwd><kwd>модуляция добротности</kwd><kwd>волокно</kwd><kwd>легированное тулием</kwd><kwd>энергоэффективность</kwd></kwd-group><kwd-group xml:lang="en"><kwd>MXene Ti3C2Tx</kwd><kwd>Q-switching</kwd><kwd>thulium doped fiber</kwd><kwd>energy efficiency</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Amini-Nik S., et al. Ultrafast mid-IR laser scalpel: protein signals of the fundamental limits to minimally invasive surgery. PLoS one, 2010, 5 (9), e13053.</mixed-citation><mixed-citation xml:lang="en">Amini-Nik S., et al. Ultrafast mid-IR laser scalpel: protein signals of the fundamental limits to minimally invasive surgery. PLoS one, 2010, 5 (9), e13053.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Werle P., et al. Near-and mid-infrared laser-optical sensors for gas analysis. Optics and lasers in engineering, 2002, 37 (2–3), P. 101–114.</mixed-citation><mixed-citation xml:lang="en">Werle P., et al. Near-and mid-infrared laser-optical sensors for gas analysis. Optics and lasers in engineering, 2002, 37 (2–3), P. 101–114.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Li Z., et al. Thulium-doped fiber amplifier for optical communications at 2 µm. Optics Express, 2013, 21 (8), P. 9289–9297.</mixed-citation><mixed-citation xml:lang="en">Li Z., et al. Thulium-doped fiber amplifier for optical communications at 2 µm. Optics Express, 2013, 21 (8), P. 9289–9297.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Yan D., et al. High-average-power, high-repetition-rate tunable terahertz difference frequency generation with GaSe crystal pumped by 2 µm dual-wavelength intracavity KTP optical parametric oscillator. Photonics Research, 2017, 5 (2), P. 82–87.</mixed-citation><mixed-citation xml:lang="en">Yan D., et al. High-average-power, high-repetition-rate tunable terahertz difference frequency generation with GaSe crystal pumped by 2 µm dual-wavelength intracavity KTP optical parametric oscillator. Photonics Research, 2017, 5 (2), P. 82–87.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Henderson S.W., et al. Coherent laser radar at 2 µm using solid-state lasers. IEEE transactions on geoscience and remote sensing, 1993, 31 (1), P. 4–15.</mixed-citation><mixed-citation xml:lang="en">Henderson S.W., et al. Coherent laser radar at 2 µm using solid-state lasers. IEEE transactions on geoscience and remote sensing, 1993, 31 (1), P. 4–15.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Feaver R., Peterson R., Powers P. Longwave-IR optical parametric oscillator in orientation-patterned GaAs pumped by a 2 µm Tm, Ho: YLF laser. Optics express, 2013, 21 (13), P. 16104–16110.</mixed-citation><mixed-citation xml:lang="en">Feaver R., Peterson R., Powers P. Longwave-IR optical parametric oscillator in orientation-patterned GaAs pumped by a 2 µm Tm, Ho: YLF laser. Optics express, 2013, 21 (13), P. 16104–16110.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang M., et al. Mid-infrared Raman-soliton continuum pumped by a nanotube-mode-locked sub-picosecond Tm-doped MOPFA. Optics express, 2013, 21 (20), P. 23261–23271.</mixed-citation><mixed-citation xml:lang="en">Zhang M., et al. Mid-infrared Raman-soliton continuum pumped by a nanotube-mode-locked sub-picosecond Tm-doped MOPFA. Optics express, 2013, 21 (20), P. 23261–23271.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang H., et al. Multi-wavelength dissipative soliton operation of an erbium-doped fiber laser. Optics express, 2009, 17 (15), P. 12692–12697.</mixed-citation><mixed-citation xml:lang="en">Zhang H., et al. Multi-wavelength dissipative soliton operation of an erbium-doped fiber laser. Optics express, 2009, 17 (15), P. 12692–12697.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Xu X., et al. Passively mode-locking erbium-doped fiber lasers with 0.3 nm Single-Walled Carbon Nanotubes. Scientific reports, 2014, 4, 6761.</mixed-citation><mixed-citation xml:lang="en">Xu X., et al. Passively mode-locking erbium-doped fiber lasers with 0.3 nm Single-Walled Carbon Nanotubes. Scientific reports, 2014, 4, 6761.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Zhou D.-P., et al. Tunable passively-switched erbium-doped fiber laser with carbon nanotubes as a saturable absorber. IEEE Photonics Technology Letters, 2010, 22 (1), P. 9–11.</mixed-citation><mixed-citation xml:lang="en">Zhou D.-P., et al. Tunable passively-switched erbium-doped fiber laser with carbon nanotubes as a saturable absorber. IEEE Photonics Technology Letters, 2010, 22 (1), P. 9–11.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Ismail M., et al. A Q-switched erbium-doped fiber laser with a graphene saturable absorber. Laser Physics Letters, 2013, 10 (2), 025102.</mixed-citation><mixed-citation xml:lang="en">Ismail M., et al. A Q-switched erbium-doped fiber laser with a graphene saturable absorber. Laser Physics Letters, 2013, 10 (2), 025102.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang H., et al. Graphene mode locked, wavelength-tunable, dissipative soliton fiber laser. Applied Physics Letters, 2010, 96 (11), 111112.</mixed-citation><mixed-citation xml:lang="en">Zhang H., et al. Graphene mode locked, wavelength-tunable, dissipative soliton fiber laser. Applied Physics Letters, 2010, 96 (11), 111112.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Ahmad H., et al. 1.5-micron fiber laser passively mode-locked by gold nanoparticles saturable absorber. Optics Communications, 2017, 403, P. 115–120.</mixed-citation><mixed-citation xml:lang="en">Ahmad H., et al. 1.5-micron fiber laser passively mode-locked by gold nanoparticles saturable absorber. Optics Communications, 2017, 403, P. 115–120.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Ismail E., et al. Black phosphorus crystal as a saturable absorber for both a Q-switched and mode-locked erbium-doped fiber laser. RSC advances, 2016, 6 (76), P. 72692–72697.</mixed-citation><mixed-citation xml:lang="en">Ismail E., et al. Black phosphorus crystal as a saturable absorber for both a Q-switched and mode-locked erbium-doped fiber laser. RSC advances, 2016, 6 (76), P. 72692–72697.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Naguib M., et al. Two?dimensional nanocrystals produced by exfoliation of Ti3AlC2. Advanced materials, 2011, 23 (37), P. 4248–4253.</mixed-citation><mixed-citation xml:lang="en">Naguib M., et al. Two?dimensional nanocrystals produced by exfoliation of Ti3AlC2. Advanced materials, 2011, 23 (37), P. 4248–4253.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Ivanovskii A.L., Enyashin A.N. Graphene-like transition-metal nanocarbides and nanonitrides. Russian Chemical Reviews, 2013, 82 (8), P. 735.</mixed-citation><mixed-citation xml:lang="en">Ivanovskii A.L., Enyashin A.N. Graphene-like transition-metal nanocarbides and nanonitrides. Russian Chemical Reviews, 2013, 82 (8), P. 735.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Enyashin A.N., Ivanovskii A.L. Structural and electronic properties and stability of MX enes Ti2C and Ti3C2 functionalized by methoxy groups. The Journal of Physical Chemistry C, 2013, 117 (26), P. 13637–13643.</mixed-citation><mixed-citation xml:lang="en">Enyashin A.N., Ivanovskii A.L. Structural and electronic properties and stability of MX enes Ti2C and Ti3C2 functionalized by methoxy groups. The Journal of Physical Chemistry C, 2013, 117 (26), P. 13637–13643.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Jiang X., et al. Broadband nonlinear photonics in few-layer MXene Ti3C2Tx (T= F, O, or OH). Laser &amp; Photonics Reviews, 2018, 12 (2), 1700229.</mixed-citation><mixed-citation xml:lang="en">Jiang X., et al. Broadband nonlinear photonics in few-layer MXene Ti3C2Tx (T= F, O, or OH). Laser &amp; Photonics Reviews, 2018, 12 (2), 1700229.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Dong Y., et al. Saturable absorption in 2D Ti3C2 MXene thin films for passive photonic diodes. Advanced Materials, 2018, 30 (10), 1705714.</mixed-citation><mixed-citation xml:lang="en">Dong Y., et al. Saturable absorption in 2D Ti3C2 MXene thin films for passive photonic diodes. Advanced Materials, 2018, 30 (10), 1705714.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Jhon Y.I., et al. Metallic MXene saturable absorber for femtosecond mode-locked lasers. Advanced Materials, 2017, 29 (40), 1702496.</mixed-citation><mixed-citation xml:lang="en">Jhon Y.I., et al. Metallic MXene saturable absorber for femtosecond mode-locked lasers. Advanced Materials, 2017, 29 (40), 1702496.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Sakata H., Kimpara K., Takahashi N. Q-switched thulium-doped fibre ring lasers operating at 1.9 µm using multi-walled carbon nanotubes in UV-curing resin. Electronics Letters, 2015, 52 (1), P. 63–64.</mixed-citation><mixed-citation xml:lang="en">Sakata H., Kimpara K., Takahashi N. Q-switched thulium-doped fibre ring lasers operating at 1.9 µm using multi-walled carbon nanotubes in UV-curing resin. Electronics Letters, 2015, 52 (1), P. 63–64.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Ahmad H., et al. Aluminized film as saturable absorber for generating passive Q-switched pulses in the two-micron region. Journal of Lightwave Technology, 2017, 35 (12), P. 2470–2475.</mixed-citation><mixed-citation xml:lang="en">Ahmad H., et al. Aluminized film as saturable absorber for generating passive Q-switched pulses in the two-micron region. Journal of Lightwave Technology, 2017, 35 (12), P. 2470–2475.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Rahman M.F., et al. Q-switched and mode-locked thulium-doped fiber laser with pure Antimony film Saturable absorber. Optics Communications, 2018, 421, P. 99–104.</mixed-citation><mixed-citation xml:lang="en">Rahman M.F., et al. Q-switched and mode-locked thulium-doped fiber laser with pure Antimony film Saturable absorber. Optics Communications, 2018, 421, P. 99–104.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Ibarra-Escamilla B., et al. Passively Q-switched thulium-doped fiber laser using alcohol. IEEE Photonics Technology Letters, 2018, 30 (20), P. 1768–1771.</mixed-citation><mixed-citation xml:lang="en">Ibarra-Escamilla B., et al. Passively Q-switched thulium-doped fiber laser using alcohol. IEEE Photonics Technology Letters, 2018, 30 (20), P. 1768–1771.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
