najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2019-10-4-447-455najo-522Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХInvestigation of physicochemical properties and radiation resistance of fullerene and endohedral metallofullerene derivatives under the ionizing radiation influenceSuyasovaM. V.

Leningradskaya oblast, Gatchina, 1 mkr. Orlova roshcha, 188300

suyasova_mv@pnpi.nrcki.ruBorisenkovaA. A.

Leningradskaya oblast, Gatchina, 1 mkr. Orlova roshcha, 188300

borisenkova_aa@pnpi.nrcki.ruShilinV. A.

Leningradskaya oblast, Gatchina, 1 mkr. Orlova roshcha, 188300Leningradskaya oblast, Gatchina, 1 mkr. Orlova roshcha, 188300

shilin_va@pnpi.nrcki.ruSedovV. P.

Leningradskaya oblast, Gatchina, 1 mkr. Orlova roshcha, 188300

victorsedov61@gmail.comOrlovaD. N.

Leningradskaya oblast, Gatchina, 1 mkr. Orlova roshcha, 188300

orlova_dn@pnpi.nrcki.ruB.P. Konstantinov Petersburg Nuclear Physics Institute, NRC Kurchatov InstituteRussian Federation201905082025104447–455Copyright © Suyasova M.V., Borisenkova A.A., Shilin V.A., Sedov V.P., Orlova D.N., 20252025Suyasova M.V., Borisenkova A.A., Shilin V.A., Sedov V.P., Orlova D.N.Suyasova M.V., Borisenkova A.A., Shilin V.A., Sedov V.P., Orlova D.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/522

The radiation resistances of fullerenes C60 and C70, end metallofullerenes Me@C2n (n = 30 – 50), derivatives C60(OH)(30) and Me@C2n(OH)30−40 (Me = Sm, Eu, Gd, Tb, Ho, Fe, Co), and complexes with biocompatible polymers – polyvinylpyrrolidone and dextrin –

Fe@C60(C6H9NO)n, Sm@C82(C6H9NO)n, Gd@C82(C6H9NO)n and Fe@C60(C6H10O5)n were studied. For the structures irradiated by protons with energies of 100 MeV and 1 GeV, radiation resistance was estimated. The comparison of the results of radiation resistance under irradiation by protons and reactor neutrons at fluencies from 1018 to 1019 cm−2 was carried out. It is shown, that endofullerenols are more stable under the proton and neutron irradiation than initial endofullerenes. The molecules containing Eu, Gd and Sm with large thermal neutron capture cross sections were found to be the most stable under neutron irradiation.The mechanism of rebuilding of secondary endofullerenols Eu, Sm, Gd, as well as other factors’ influence on radiation resistance are discussed.

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The authors declare that there are no conflicts of interest present.