najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2024-15-4-548-557najo-54Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХhe control of by-product formation rates in photocatalytic hydrogen evolution reaction from organic substances over Pt/g–C3N4Контроль скорости образования побочных продуктов в реакции фотокаталитического выделения водорода из органических соединений в присутствии Pt/g-C3N4https://orcid.org/0000-0002-7868-3409ПотапенкоК. О.PotapenkoK. O.

Ksenia O. Potapenko

Novosibirsk, 630090

potapenko@catalysis.ruhttps://orcid.org/0000-0002-7730-7655АйдаковЕ. Е.AydakovE. E.

Egor E. Aydakov

Novosibirsk, 630090

e.ajdakov@g.nsu.ruhttps://orcid.org/0000-0002-3230-3335ГерасимовЕ. Ю.GerasimovE. Y.

Evgeny Y. Gerasimov

Novosibirsk, 630090

gerasimov@catalysis.ruhttps://orcid.org/0000-0001-8944-7666КозловаЕ. А.KozlovaE. A.

Ekaterina A. Kozlova

Novosibirsk, 630090

kozlova@catalysis.ruBoreskov Institute of Catalysis, SB RASRussian Federation202431052025154548557Copyright © Potapenko K.O., Aydakov E.E., Gerasimov E.Y., Kozlova E.A., 20252025Потапенко К.О., Айдаков Е.Е., Герасимов Е.Ю., Козлова Е.А.Potapenko K.O., Aydakov E.E., Gerasimov E.Y., Kozlova E.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/54

The results on the photocatalytic activity of 0 – 2 wt.% Pt/g-C3N4 in the hydrogen evolution reaction under visible light (430 nm) are presented. Triethanolamine (TEOA), glycerol, glucose and cellulose were used as electron donor. During the reaction, not only the target product, hydrogen, but also by-products of the reaction in the gas phase, namely CO and CO2, were controlled. In order to study the chemical composition, microstructure and optical properties, the samples were investigated by XPS, TEM and diffuse reflection methods. The maximum hydrogen evolution rate obtained for 1 % Pt/g-C3N4 from TEOA solution was 3.96 μmol·min−1, with a selectivity of 100 %. The use of glycerol and cellulose resulted in the production of syngas, and varying the platinum content allowed the selectivity of the process to vary (42.4 to 100 %). Glucose using led to the formation of a mixture of CO2 and H2 with a selectivity of 90 % or higher. In general, hydrogen-containing mixtures obtained using organic substrates can be further used in various applications.

В работе представлены результаты исследования фотокаталитической активности 0-2 мас.% Pt/g-C3N4 в реакции выделения водорода под действием видимого света (430 нм). В качестве донора электронов использовали водные растворы триэтаноламина (TЭOA), глицерина, глюкозы и целлюлозы. В ходе реакции контролировали не только целевой продукт - водород, но и побочные продукты реакции в газовой фазе, а именно CO и CO2. Для изучения химического состава, микроструктуры и оптических свойств образцы были исследованы методами РФЭС, ПЭМ и электронной спектроскопии диффузного отражения. Максимальная скорость выделения водорода, полученная для 1% Pt/g-C3N4 из раствора TЭOA, составила 3,96 мкмоль мин-1 при селективности 100%. Использование глицерина и целлюлозы приводило к получению синтез газа, а варьирование содержания платины позволяло изменять селективность процесса (от 42,4 до 100 %). Использование глюкозы приводило к образованию смеси CO2 и H2 с селективностью 90 % и выше. В целом водородсодержащие смеси, полученные с использованием органических субстратов, могут в дальнейшем использоваться в различных приложениях.

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The authors declare that there are no conflicts of interest present.