najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2021-12-6-792-798najo-578Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХEffect of fuel type on solution combustion synthesis and photocatalytic activity of NiFe2O4 nanopowdersВлияние вида топлива на синтез растворного горения и фотокаталитическую активность нанопорошков NiFe2O4MartinsonK. D.MartinsonK. D.

St. Petersburg, 194021.

martinsonkirill@mail.ruBelyakV. E.BelyakV. E.

26, Moskovsky prospect, St. Petersburg, 190013.

SakhnoD. D.SakhnoD. D.

26, Moskovsky prospect, St. Petersburg, 190013.

KiryanovN. V.KiryanovN. V.

26, Moskovsky prospect, St. Petersburg, 190013.

ChebanenkoM. I.ChebanenkoM. I.

St. Petersburg 194021.

PopkovV. I.PopkovV. I.

St. Petersburg 194021.

Ioffe InstituteRussian FederationSaint Petersburg State Institute of TechnologyRussian Federation202107082025126792798Copyright © Martinson K.D., Belyak V.E., Sakhno D.D., Kiryanov N.V., Chebanenko M.I., Popkov V.I., 20252025Martinson K.D., Belyak V.E., Sakhno D.D., Kiryanov N.V., Chebanenko M.I., Popkov V.I.Martinson K.D., Belyak V.E., Sakhno D.D., Kiryanov N.V., Chebanenko M.I., Popkov V.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/578

Nickel ferrite nanopowders were obtained under conditions of solution combustion with the addition of various types of organic fuels (glycine, ascorbic acid, oxalic acid, and malic acid) and studied as photocatalysts in the photodegradation of methylene blue. Photocatalytic measurements were carried out under the action of visible light in model dye solutions. The highest photocatalytic activity was found in the case of a sample synthesized using malic acid as a fuel and in which the largest specific surface area (128.1 m2/g) and the smallest particle size (18 nm) were observed. The obtained dependences of the photocatalytic activity of the synthesized samples demonstrate its strong dependence on morphological and structural parameters. Thus, with an increase in the particle size and a decrease in the specific surface area, a decrease in the efficiency of a photocatalyst based on nickel ferrite is observed. In addition, the use of various types of fuels made it possible to obtain aggregates of various shapes and sizes up to several tens of micrometers. The resulting rate constants were established to vary from 0.00756 to 0.00867 min−1.

Нанопорошки феррита никеля были получены в условиях растворного горения с использованием различных видов органического топлива (глицин, аскорбиновая, щавелевая и яблочная кислоты) и исследованы в качестве фотокатализаторов фотодеградации метиленового синего. Фотокаталитические измерения проводились под действием видимого света в модельных растворах красителей. Наибольшая фотокаталитическая активность была обнаружена у образца, синтезированного с использованием яблочной кислоты в качестве топлива и у которого наблюдались наибольшая удельная поверхность (128,1 м2/г) и наименьший размер частиц (18 нм). Характер полученных зависимостей фотокаталитической активности синтезированных образцов свидетельствует о ее сильной зависимости от морфологических и структурных параметров. Таким образом установлено, что с увеличением размера частиц и уменьшением удельной поверхности наблюдается снижение эффективности фотокатализатора на основе феррита никеля. Кроме того, использование различных видов топлива позволило получить агрегаты различной формы и размеров до нескольких десятков микрометров. Установлено, что полученные константы скорости изменяются от 0,00756 до 0,00867 мин-1.

феррит никелярастворное горениенанокристаллыфотокатализметиленовый синийnickel ferritesolution combustion synthesisnanocrystalsphotocatalystsmethylene blueReferencesKurian M., Thankachan S., Structural diversity and applications of spinel ferrite core-shell nanostructures – a review. Open Ceramics, 2021, 8, P. 100179.Kurian M., Thankachan S., Structural diversity and applications of spinel ferrite core-shell nanostructures – a review. Open Ceramics, 2021, 8, P. 100179.Ranga R., Kumar A, Kumari P, Singh P., Madaan V., Kumar K., Ferrite application as an electrochemical sensor: a review. Materials Characterization, 2021, 178, P. 111269.Ranga R., Kumar A, Kumari P, Singh P., Madaan V., Kumar K., Ferrite application as an electrochemical sensor: a review. Materials Characterization, 2021, 178, P. 111269.Houbi A., Aldashevich Z.A., Atassi Y., Telmanovna Z.B., Saule M., Kubanych K., Microwave absorbing properties of ferrites and their composites: a review. Journal of Magnetism and Magnetic Materials, 2021, 529, P. 167839.Houbi A., Aldashevich Z.A., Atassi Y., Telmanovna Z.B., Saule M., Kubanych K., Microwave absorbing properties of ferrites and their composites: a review. Journal of Magnetism and Magnetic Materials, 2021, 529, P. 167839.Almessiere M.A., Slimani Y., Trukhanov A.V., Sadaqat A., Korkmaz A.D., Algarou N.A., Aydin H., Baykal A., Toprak M.S., Review on functional bi-component nanocomposites based on hard/soft ferrites: structural, magnetic, electric and microwave absorption properties. Nano-Structures and Nano-Objects, 2021, 26, P. 100728.Almessiere M.A., Slimani Y., Trukhanov A.V., Sadaqat A., Korkmaz A.D., Algarou N.A., Aydin H., Baykal A., Toprak M.S., Review on functional bi-component nanocomposites based on hard/soft ferrites: structural, magnetic, electric and microwave absorption properties. Nano-Structures and Nano-Objects, 2021, 26, P. 100728.Harris V.G., Geiler A., Chen Y., Yoon S.D., Wu M., Yang A., Chen Z., He P., Parimi P.V., Zuo X., Patton C.E., Abe M., Acher O., Vittoria C., Recent advances in processing and applications of microwave ferrites. Journal of Magnetism and Magnetic Materials, 2009, 321, P. 2035– 2047.Harris V.G., Geiler A., Chen Y., Yoon S.D., Wu M., Yang A., Chen Z., He P., Parimi P.V., Zuo X., Patton C.E., Abe M., Acher O., Vittoria C., Recent advances in processing and applications of microwave ferrites. Journal of Magnetism and Magnetic Materials, 2009, 321, P. 2035– 2047.Petrila I., Tudorache F., Effects of sintering temperature on the microstructure, electrical and magnetic characteristics of copper-zinc spinel ferrite with possibility use as humidity sensors. Sensors and Actuators A: Physical, 2021, 332, P. 113060.Petrila I., Tudorache F., Effects of sintering temperature on the microstructure, electrical and magnetic characteristics of copper-zinc spinel ferrite with possibility use as humidity sensors. Sensors and Actuators A: Physical, 2021, 332, P. 113060.Rana G., Dhiman P., Kumar A., Vo D.-V. N., Sharma G., Sharma S., Naushad M., Recent advances on nickel nano-ferrite: a review on processing techniques, properties and diverse applications. Chemical Engineering Research and Design, 2021, 175, P. 182–208.Rana G., Dhiman P., Kumar A., Vo D.-V. N., Sharma G., Sharma S., Naushad M., Recent advances on nickel nano-ferrite: a review on processing techniques, properties and diverse applications. Chemical Engineering Research and Design, 2021, 175, P. 182–208.Tikhanova S.M., Lebedev L.A., Martinson K.D., Chebanenko M.I., Buryanenko I.V., Semenov V.G., Nevedomskiy V.N., Popkov V.I., The synthesis of novel heterojunction h-YbFeO3/o-YbFeO3 photocatalyst with enhanced Fenton-like activity under visible-light. New Journal of Chemistry, 2021, 45, P. 1541–1550.Tikhanova S.M., Lebedev L.A., Martinson K.D., Chebanenko M.I., Buryanenko I.V., Semenov V.G., Nevedomskiy V.N., Popkov V.I., The synthesis of novel heterojunction h-YbFeO3/o-YbFeO3 photocatalyst with enhanced Fenton-like activity under visible-light. New Journal of Chemistry, 2021, 45, P. 1541–1550.Amiri M., Eskandari K., Salavati-Niasari M., Magneticxally retrievable ferrite nanoparticles in the catalysis application. Advances in Colloid and Interface Science, 2019, 271, P. 101982.Amiri M., Eskandari K., Salavati-Niasari M., Magneticxally retrievable ferrite nanoparticles in the catalysis application. Advances in Colloid and Interface Science, 2019, 271, P. 101982.Kalam A., Al-Sehemi A.G., Assiri M., Gaohui D., Ahmad T., Ahmad I., Pannipara M., Modified solvothermal synthesis of cobalt ferrite (CoFe2O4) magnetic nanoparticles photocatalysts for degradation of methylene blue with H2O2/visible light. Results in Physics, 2018, 8, P. 1046–1053.Kalam A., Al-Sehemi A.G., Assiri M., Gaohui D., Ahmad T., Ahmad I., Pannipara M., Modified solvothermal synthesis of cobalt ferrite (CoFe2O4) magnetic nanoparticles photocatalysts for degradation of methylene blue with H2O2/visible light. Results in Physics, 2018, 8, P. 1046–1053.Irfan S., Zhuanghao Z., Li F., Chen Y.-X., Liang G.-X., Luo J.-T., Ping F., Critical review: bismuth ferrite as an emerging visible light active nanostructured photocatalyst. Journal of Materials Research and Technology, 2019, 8, P. 6375–6389.Irfan S., Zhuanghao Z., Li F., Chen Y.-X., Liang G.-X., Luo J.-T., Ping F., Critical review: bismuth ferrite as an emerging visible light active nanostructured photocatalyst. Journal of Materials Research and Technology, 2019, 8, P. 6375–6389.Shih Y.-J., Su C.-C., Chen C.-W., Dong C.-D., Synthesis of magnetically recoverable ferrite (MFe2O4, M = Co, Ni and Fe)-supported TiO2 photocatalysts for decolorization of methylene blue. Catalysis Communications, 2015, 72, P. 127–132.Shih Y.-J., Su C.-C., Chen C.-W., Dong C.-D., Synthesis of magnetically recoverable ferrite (MFe2O4, M = Co, Ni and Fe)-supported TiO2 photocatalysts for decolorization of methylene blue. Catalysis Communications, 2015, 72, P. 127–132.Sonu, Sharma S., Dutta V., Raizada P., Hosseini-Bandegharaei A., Thakur V., Nguyen V.-H., VanLe Q., Singh P., An overview of heterojunctioned ZnFe2O4 photocatalyst for enhanced oxidative water purification. Journal of Environmental Chemical Engineering, 2021, 9, P. 105812.Sonu, Sharma S., Dutta V., Raizada P., Hosseini-Bandegharaei A., Thakur V., Nguyen V.-H., VanLe Q., Singh P., An overview of heterojunctioned ZnFe2O4 photocatalyst for enhanced oxidative water purification. Journal of Environmental Chemical Engineering, 2021, 9, P. 105812.Sansenya T., Masri N., Chankhanittha T., Senasu T., Piriyanon J., Mukdasai S., Nanan S., Hydrothermal synthesis of ZnO photocatalyst for detoxification of anionic azo dyes and antibiotic. Journal of Physics and Chemistry of Solids, 2022, 160, P. 110353.Sansenya T., Masri N., Chankhanittha T., Senasu T., Piriyanon J., Mukdasai S., Nanan S., Hydrothermal synthesis of ZnO photocatalyst for detoxification of anionic azo dyes and antibiotic. Journal of Physics and Chemistry of Solids, 2022, 160, P. 110353.Reddy K.M., Devaraju J., Kinetics of Photo Fenton Process and Ag-TiO2 photocatalyst under UV-light. Materials Today: Proceedings, 2019, 17, P. 234–238.Reddy K.M., Devaraju J., Kinetics of Photo Fenton Process and Ag-TiO2 photocatalyst under UV-light. Materials Today: Proceedings, 2019, 17, P. 234–238.Song C., Wang L.-J., Sun S.M., Wu Y., Xu L.-J., Gan L., Preparation of visible-light photocatalysts of Bi2O3/Bi embedded in porous carbon from Bi-based metal-organic frameworks for highly efficient Rhodamine B removal from water. New Carbon Materials, 2020, 35, P. 609–618.Song C., Wang L.-J., Sun S.M., Wu Y., Xu L.-J., Gan L., Preparation of visible-light photocatalysts of Bi2O3/Bi embedded in porous carbon from Bi-based metal-organic frameworks for highly efficient Rhodamine B removal from water. New Carbon Materials, 2020, 35, P. 609–618.Atacan K., Guy N., Cakar S., Ozacar M., Efficiency of glucose oxidase immobilized on tannin modified NiFe2O4 nanoparticles on decolorization of dye in the Fenton and photo-biocatalytic processes. Journal of Photochemistry and Photobiology A: Chemistry, 2019, 382, P. 111935.Atacan K., Guy N., Cakar S., Ozacar M., Efficiency of glucose oxidase immobilized on tannin modified NiFe2O4 nanoparticles on decolorization of dye in the Fenton and photo-biocatalytic processes. Journal of Photochemistry and Photobiology A: Chemistry, 2019, 382, P. 111935.Shokri A., Using NiFe2O4 as a nano photocatalyst for degradation of polyvinyl alcohol in synthetic wastewater. Environmental Challenges, 2021, 5, P. 100332.Shokri A., Using NiFe2O4 as a nano photocatalyst for degradation of polyvinyl alcohol in synthetic wastewater. Environmental Challenges, 2021, 5, P. 100332.Cvejic Z., Durdic E., Ivandekic G.I., Bajac B., Postolache P., Mitoseriu L., Srdic V.V., Rakic S., The effect of annealing on microstructure and cation distribution of NiFe2O4. Journal of Alloys and Compounds, 2015, 649, P. 1231–1238.Cvejic Z., Durdic E., Ivandekic G.I., Bajac B., Postolache P., Mitoseriu L., Srdic V.V., Rakic S., The effect of annealing on microstructure and cation distribution of NiFe2O4. Journal of Alloys and Compounds, 2015, 649, P. 1231–1238.Dumitrescu A.M., Samoila P.M., Nica V., Doroftei F., Iordan A.R., Palamaru M.N., Study of the chelating/fuel agents influence on NiFe2O4 samples with potential catalytic properties. Powder Technology, 2013, 243, P. 9–17.Dumitrescu A.M., Samoila P.M., Nica V., Doroftei F., Iordan A.R., Palamaru M.N., Study of the chelating/fuel agents influence on NiFe2O4 samples with potential catalytic properties. Powder Technology, 2013, 243, P. 9–17.Majid F., Rauf J., Ata S., Bibi I., Malik A., Ibrahim S.M., Ali A., Iqbal M., Synthesis and characterization of NiFe2O4 ferrite: sol-gel and hydrothermal synthesis routes effect on magnetic, structural and dielectric characteristics. Materials Chemistry and Physics, 2021, 258, P. 123888.Majid F., Rauf J., Ata S., Bibi I., Malik A., Ibrahim S.M., Ali A., Iqbal M., Synthesis and characterization of NiFe2O4 ferrite: sol-gel and hydrothermal synthesis routes effect on magnetic, structural and dielectric characteristics. Materials Chemistry and Physics, 2021, 258, P. 123888.Kesavan G., Nataraj N., Chen S.-M., Lin L.-H., Hydrothermal synthesis of NiFe2O4 nanoparticles as an efficient electrocatalyst for the electrochemical detection of bisphenol A. New Journal of Chemistry, 2020, 44, P. 7698–7707.Kesavan G., Nataraj N., Chen S.-M., Lin L.-H., Hydrothermal synthesis of NiFe2O4 nanoparticles as an efficient electrocatalyst for the electrochemical detection of bisphenol A. New Journal of Chemistry, 2020, 44, P. 7698–7707.Martinson K.D., Cherepkova I.A., Panteleev I.B., Popkov V.I., Single-step solution-combustion synthesis of magnetically soft NiFe2O4 nanopowders with controllable parameters. International Journal of Self-Propagating High-Temperature Synthesis, 2019, 28, P. 266–270.Martinson K.D., Cherepkova I.A., Panteleev I.B., Popkov V.I., Single-step solution-combustion synthesis of magnetically soft NiFe2O4 nanopowders with controllable parameters. International Journal of Self-Propagating High-Temperature Synthesis, 2019, 28, P. 266–270.Yang H., Zhang X., Ao W., Qiu G., Formation of NiFe2O4 nanoparticles by mechanochemical reaction. Materials Research Bulletin, 2004, 39, P. 833–837.Yang H., Zhang X., Ao W., Qiu G., Formation of NiFe2O4 nanoparticles by mechanochemical reaction. Materials Research Bulletin, 2004, 39, P. 833–837.Hajalilou A., Mazlan S.A., A review on preparation techniques for synthesis of nanocrystalline soft magnetic ferrites and investigation on the effects of microstructure features on magnetic properties. Applied Physics A, 2016, 122, P. 680.Hajalilou A., Mazlan S.A., A review on preparation techniques for synthesis of nanocrystalline soft magnetic ferrites and investigation on the effects of microstructure features on magnetic properties. Applied Physics A, 2016, 122, P. 680.Martinson K.D., Cherepkova I.A., Sokolov V.V., Formation of cobalt ferrite nanoparticles via glycine-nitrate combustion and their magnetic properties. Glass Physics and Chemistry, 2018, 44, P. 21–25.Martinson K.D., Cherepkova I.A., Sokolov V.V., Formation of cobalt ferrite nanoparticles via glycine-nitrate combustion and their magnetic properties. Glass Physics and Chemistry, 2018, 44, P. 21–25.Aruna S.T., Mukasyan A.S., Combustion synthesis and nanomaterials. Current Opinion in Solid State and Materials Science, 2008, 12, P. 44–50.Aruna S.T., Mukasyan A.S., Combustion synthesis and nanomaterials. Current Opinion in Solid State and Materials Science, 2008, 12, P. 44–50.Martinson K.D., Panteleev I.B., Shevchik A.P., Popkov V.I., Effect of the Red/Ox ratio on the structure and magnetic behavior of Li0.5Fe2.5O4 nanocrystals synthesized by solution combustion approach. Letters on Materials, 2019, 9, P. 475–479.Martinson K.D., Panteleev I.B., Shevchik A.P., Popkov V.I., Effect of the Red/Ox ratio on the structure and magnetic behavior of Li0.5Fe2.5O4 nanocrystals synthesized by solution combustion approach. Letters on Materials, 2019, 9, P. 475–479.Khort A., Roslyakov S., Loginov P., Solution combustion synthesis of single-phase bimetallic nanomaterials. Nano-Structures & NanoObjects, 2021, 26, P. 100727.Khort A., Roslyakov S., Loginov P., Solution combustion synthesis of single-phase bimetallic nanomaterials. Nano-Structures & NanoObjects, 2021, 26, P. 100727.Lazarova T., Georgieva M., Tzankov D., Voykova D., Aleksandrov L., Cherkezova-Zheleva Z., Kovacheva D., Influence of the type of fuel used for the solution combustion synthesis on the structure, morphology and magnetic properties of nanosized NiFe2O4. Journal of Alloys and Compounds, 2017, 700, P. 272–283.Lazarova T., Georgieva M., Tzankov D., Voykova D., Aleksandrov L., Cherkezova-Zheleva Z., Kovacheva D., Influence of the type of fuel used for the solution combustion synthesis on the structure, morphology and magnetic properties of nanosized NiFe2O4. Journal of Alloys and Compounds, 2017, 700, P. 272–283.Kharisov B.I., Dias H.V.R., Kharissova O.V., Mini-review: ferrite nanoparticles in the catalysis. Arabian Journal of Chemistry, 2019, 12, P. 1234–1246.Kharisov B.I., Dias H.V.R., Kharissova O.V., Mini-review: ferrite nanoparticles in the catalysis. Arabian Journal of Chemistry, 2019, 12, P. 1234–1246.Popkov V.I., Martinson K.D., Kondrashkova I.S., Enikeeva M.O., Nevedomskiy V.N., Panchuk V.V., Semenov V.G., Volkov M.P., Pleshakov I.V., SCS-assisted production of EuFeO3 core-shell nanoparticles: formation process, structural features and magnetic behavior. Journal of Alloys and Compounds, 2021, 859, P. 157812.Popkov V.I., Martinson K.D., Kondrashkova I.S., Enikeeva M.O., Nevedomskiy V.N., Panchuk V.V., Semenov V.G., Volkov M.P., Pleshakov I.V., SCS-assisted production of EuFeO3 core-shell nanoparticles: formation process, structural features and magnetic behavior. Journal of Alloys and Compounds, 2021, 859, P. 157812.Martinson K.D., Ivanov A.A., Panteleev I.B., Popkov V.I., Effect of sintering temperature on the synthesis of LiZnMnFe microwave ceramics with controllable electro/magnetic properties. Ceramics International, 2021, 47, P. 30071–30081.Martinson K.D., Ivanov A.A., Panteleev I.B., Popkov V.I., Effect of sintering temperature on the synthesis of LiZnMnFe microwave ceramics with controllable electro/magnetic properties. Ceramics International, 2021, 47, P. 30071–30081.Martinson K.D., Sakhno D.D., Belyak V.E., Kondrashkova I.S., Ni0.4Zn0.6Fe2O4 nanopowders by solution-combustion synthesis: influence of Red/Ox ratio on their morphology, structure, and magnetic properties. International Journal of High-Temperature Synthesis, 2020, 29, P. 202–207.Martinson K.D., Sakhno D.D., Belyak V.E., Kondrashkova I.S., Ni0.4Zn0.6Fe2O4 nanopowders by solution-combustion synthesis: influence of Red/Ox ratio on their morphology, structure, and magnetic properties. International Journal of High-Temperature Synthesis, 2020, 29, P. 202–207.Martinson K.D., Kozyritskaya S.S., Panteleev I.B., Popkov V.I., Low coercivity microwave ceramics based on LiZnMn ferrite synthesized via glycine-nitrate combustion. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10, P. 313–317.Martinson K.D., Kozyritskaya S.S., Panteleev I.B., Popkov V.I., Low coercivity microwave ceramics based on LiZnMn ferrite synthesized via glycine-nitrate combustion. Nanosystems: Physics, Chemistry, Mathematics, 2019, 10, P. 313–317.Amulya M.A.S., Nagaswarupa H.P., Kumar M.R.A., Ravikumar C.R., Prashantha S.C., Kusuma K.B., Sonochemical synthesis of NiFe2O4 nanoparticles: characterization and their photocatalytic and electrochemical applications. Applied Surface Science Advances, 2020, 1, P. 100023.Amulya M.A.S., Nagaswarupa H.P., Kumar M.R.A., Ravikumar C.R., Prashantha S.C., Kusuma K.B., Sonochemical synthesis of NiFe2O4 nanoparticles: characterization and their photocatalytic and electrochemical applications. Applied Surface Science Advances, 2020, 1, P. 100023.

The authors declare that there are no conflicts of interest present.