najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2017-8-3-397-405najo-619Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХCryometry data and excess thermodynamic functions in the binary system: water soluble bis-adduct of light fullerene C70 with lysine. Assymmetrical thermodynamic model of virtual gibbs energy decomposition – VD-ASCharykovN. A.

Moskovsky prospect, 26 Saint Petersburg, 190013; ul. Professora Popova 5, 197376 Saint Petersburg

SemenovK. N.

7/9 Universitetskaya emb., Saint Petersburg, 199034

KeskinovV. V.

Moskovsky prospect, 26 Saint Petersburg, 190013

GaramovaP. V.

Moskovsky prospect, 26 Saint Petersburg, 190013

TyurinD. P.

Moskovsky prospect, 26 Saint Petersburg, 190013

SemenyukI. V.

Moskovsky prospect, 26 Saint Petersburg, 190013

PetrenkoV. V.

Moskovsky prospect, 26 Saint Petersburg, 190013

KurilenkoA. V.

Moskovsky prospect, 26 Saint Petersburg, 190013

MatuzenkoM. Yu.

Moskovsky prospect, 26 Saint Petersburg, 190013

KulenovaN. A.

A. K. Protozanov Street, 69, Ust-Kamenogorsk city, 070004

ZolotarevA. A.

Moskovsky prospect, 26 Saint Petersburg, 190013

LetenkoD. G.

2-nd Krasnoarmeiskaya St. 4, 190005 Saint Petersburg

Saint Petersburg State Technological Institute (Technical University); Saint Petersburg Electrotechnical University “LETI”Russian FederationSaint Petersburg State UniversityRussian FederationSaint Petersburg State Technological Institute (Technical University)Russian FederationSaint Petersburg State Technological Institute (Technical University),Russian FederationD. Serikbayev East Kazakhstan state technical universityKazakhstanSaint Petersburg State University of Architecture and Civil Engineering (SPSUACE)Russian Federation20171108202583397405Copyright © Charykov N.A., Semenov K.N., Keskinov V.V., Garamova P.V., Tyurin D.P., Semenyuk I.V., Petrenko V.V., Kurilenko A.V., Matuzenko M.Y., Kulenova N.A., Zolotarev A.A., Letenko D.G., 20252025Charykov N.A., Semenov K.N., Keskinov V.V., Garamova P.V., Tyurin D.P., Semenyuk I.V., Petrenko V.V., Kurilenko A.V., Matuzenko M.Y., Kulenova N.A., Zolotarev A.A., Letenko D.G.Charykov N.A., Semenov K.N., Keskinov V.V., Garamova P.V., Tyurin D.P., Semenyuk I.V., Petrenko V.V., Kurilenko A.V., Matuzenko M.Y., Kulenova N.A., Zolotarev A.A., Letenko D.G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/619

The temperature of water-ice crystallization initiation decreases (∆T) were determined in the binary water solutions of water soluble derivative of light fullerene C70 with amino-acid lysine at 272.99 – 273.15 K. Partial molar excess functions for H2O were calculated. For the thermodynamic description of our systems, we have elaborated an original semi-empirical model VD-AS (Virial Decomposition Asymmetric Model), based on the virial decomposition of the molar Gibbs energy of the component molar fractions in the solution. With the help of the VD-AS model, partial molar functions of nano-clusters were calculated. Excess and full average Gibbs energies for the solutions and miscibility gaps concentration regions (with the help of diffusional instability equations) were calculated. Thus, the VD-AS model excellently describes pre-delamination or micro-heterogeneous-structure formation in the considered solutions. These calculations were accordingly confirmed by dynamic light scattering data.

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The authors declare that there are no conflicts of interest present.