najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2018-9-5-586-596najo-668Research ArticlePHYSICSФИЗИКАInfluence of copper nanoparticle film processing temperature on their structure and electrical propertiesBegletsovaN. N.

Astrakhanskaya, 83, Saratov, 410012; Bolshaya Sadovaya, 239, Saratov, 410005

nadya-beg98@yandex.ruAl-AlwaniA. J. K.

Astrakhanskaya, 83, Saratov, 410012;  Babylon, Iraq

ammarhamlet2013@yahoo.comAtkinA. S.

Astrakhanskaya, 83, Saratov, 410012

ceba91@list.ruSevostyanovV. P.

Bolshaya Sadovaya, 239, Saratov, 410005

vsevp@mail.ruGlukhovskoyE. G.

Astrakhanskaya, 83, Saratov, 410012; Bolshaya Sadovaya, 239, Saratov, 410005

glukhovskoy@gmail.comSaratov State University; Scientifc Research Institute of Technology of Organic, Inorganic Chemistry and BiotechnologyRussian FederationSaratov State University; Babylon University,Russian FederationSaratov State UniversityRussian FederationScientifc Research Institute of Technology of Organic, Inorganic Chemistry and BiotechnologyRussian Federation20181208202595586596Copyright © Begletsova N.N., Al-Alwani A., Atkin A.S., Sevostyanov V.P., Glukhovskoy E.G., 20252025Begletsova N.N., Al-Alwani A., Atkin A.S., Sevostyanov V.P., Glukhovskoy E.G.Begletsova N.N., Al-Alwani A., Atkin A.S., Sevostyanov V.P., Glukhovskoy E.G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/668

This work is devoted to the study of the influence of the additional processing at 100, 200 and 300 ◦C on the morphology, microrelief, elemental composition of the surface and the electrophysical properties of glass/ITO/copper nanoparticle film structures. Studies have shown that with an increase in the processing temperature of the investigating samples reduces the amount of organic matter protecting the copper particles from oxidation. The conductivity of copper nanoparticles increases. The morphology of the surface and the elemental composition of the samples were studied by scanning electron microscopy. The microrelief of the surface and the measurement of the copper nanoparticles current-voltage characteristics were carried out using a scanning probe microscope in atomic force and scanning tunneling microscopy modes. 

Copper nanoparticlessurface morphology and microreliefelemental compositioncurrent-voltage characteristicsThis work was supported by RFBR grant No. 17-07-00407-aReferencesEastman A., Choi S.U.S., Li S., et al. Anomalously increased effective thermal conductivities of ethylene glycolbased nanofluids containing copper nanoparticles. Appl. Phys. Lett., 2001, 78 (6), P. 718–720.Eastman A., Choi S.U.S., Li S., et al. Anomalously increased effective thermal conductivities of ethylene glycolbased nanofluids containing copper nanoparticles. Appl. Phys. Lett., 2001, 78 (6), P. 718–720.Yabuki A., Arriffin N. Electrical conductivity of copper nanoparticle thin films annealed at low temperature. Thin Solid Films, 2010, 518 (23), P. 7033–7037.Yabuki A., Arriffin N. Electrical conductivity of copper nanoparticle thin films annealed at low temperature. Thin Solid Films, 2010, 518 (23), P. 7033–7037.Singh P., Katyal A., Kalra R., et al. Copper nanoparticles in an ionic liquid: an efficient catalyst for the synthesis of bis-(4-hydroxy-2- oxothiazolyl)methanes. Tetrahedron Lett., 2008, 49 (4), P. 727–730.Singh P., Katyal A., Kalra R., et al. Copper nanoparticles in an ionic liquid: an efficient catalyst for the synthesis of bis-(4-hydroxy-2- oxothiazolyl)methanes. Tetrahedron Lett., 2008, 49 (4), P. 727–730.Dragoi B., Ungureanu A., Chirieac A., et al. Structural and catalytic properties of mono- and bimetallic Nickel-Copper nanoparticles derived from MgNi(Cu)Al-LDHs under reductive conditions. Applied Catalysis A: General, 2015, 504, P. 92–102.Dragoi B., Ungureanu A., Chirieac A., et al. Structural and catalytic properties of mono- and bimetallic Nickel-Copper nanoparticles derived from MgNi(Cu)Al-LDHs under reductive conditions. Applied Catalysis A: General, 2015, 504, P. 92–102.Begletsova N.N., Shinkarenko O.A., Chumakov A.S., et al. Copper nanoparticles obtained by chemical reduction stabilized by micelles of various surfactants. Journal of Physics: Conf. Series, 2017, 917, 092014.Begletsova N.N., Shinkarenko O.A., Chumakov A.S., et al. Copper nanoparticles obtained by chemical reduction stabilized by micelles of various surfactants. Journal of Physics: Conf. Series, 2017, 917, 092014.Granata G., Yamaoka T., Pagnanelli F., et al. Study of the synthesis of copper nanoparticles: the role of capping and kinetic towards control of particle size and stability. J. Nanopart. Res., 2016, 18 (133), 12 p.Granata G., Yamaoka T., Pagnanelli F., et al. Study of the synthesis of copper nanoparticles: the role of capping and kinetic towards control of particle size and stability. J. Nanopart. Res., 2016, 18 (133), 12 p.Li W., Chen M., Wei J., et al. Synthesis and characterization of air-stable Cu nanoparticles for conductive pattern drawing directly on paper substrates. J. Nanopart. Res., 2013, 15 (1949), 10 p.Li W., Chen M., Wei J., et al. Synthesis and characterization of air-stable Cu nanoparticles for conductive pattern drawing directly on paper substrates. J. Nanopart. Res., 2013, 15 (1949), 10 p.Zhou J., Wu Z., Zhang Z., et al. Tribological behavior and lubricating mechanism of Cu nanoparticles in oil. Tribol. Lett., 2000, 8 (4), P. 213–218.Zhou J., Wu Z., Zhang Z., et al. Tribological behavior and lubricating mechanism of Cu nanoparticles in oil. Tribol. Lett., 2000, 8 (4), P. 213–218.Komeily-Nia Z., Montazer M., Latifi M. Synthesis of nano copper/nylon composite using ascorbic acid and CTAB. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2013, 439, P. 167–175.Komeily-Nia Z., Montazer M., Latifi M. Synthesis of nano copper/nylon composite using ascorbic acid and CTAB. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2013, 439, P. 167–175.Huang K.M., Tsukamoto H., Yong Y., et al. Stabilization of the thermal decomposition process of self-reducible copper ion ink for direct printed conductive patterns. RSC Adv., 2017, 7 (40), P. 25095–25100.Huang K.M., Tsukamoto H., Yong Y., et al. Stabilization of the thermal decomposition process of self-reducible copper ion ink for direct printed conductive patterns. RSC Adv., 2017, 7 (40), P. 25095–25100.Parveen F., Sannakki B., Mandke M.V., et al. Copper nanoparticles: Synthesis methods and its light harvesting performance. Solar Energy Materials and Solar Cells, 2016, 144, P. 371–382.Parveen F., Sannakki B., Mandke M.V., et al. Copper nanoparticles: Synthesis methods and its light harvesting performance. Solar Energy Materials and Solar Cells, 2016, 144, P. 371–382.Xu B., Zhou J., Ni Z., et al. Synthesis of novel microencapsulated phase change materials with copper and copper oxide for solar energy storage and photo-thermal conversion. Solar Energy Materials and Solar Cells, 2018, 179, P. 87–94.Xu B., Zhou J., Ni Z., et al. Synthesis of novel microencapsulated phase change materials with copper and copper oxide for solar energy storage and photo-thermal conversion. Solar Energy Materials and Solar Cells, 2018, 179, P. 87–94.Ko Y., Kwon M., Bae W.K., et al. Flexible supercapacitor electrodes based on real metal-like cellulose papers. Nature Communications, 2017, 8 (536), 11 p.Ko Y., Kwon M., Bae W.K., et al. Flexible supercapacitor electrodes based on real metal-like cellulose papers. Nature Communications, 2017, 8 (536), 11 p.Uschakov A.V., Karpov I.V., Lepeshev A.A., et al. The influence of oxygen concentration on the formation of CuO and Cu2O crystalline phases during the synthesis in the plasma of low pressure arc discharge. Vacuum, 2016, 128, P. 123–127.Uschakov A.V., Karpov I.V., Lepeshev A.A., et al. The influence of oxygen concentration on the formation of CuO and Cu2O crystalline phases during the synthesis in the plasma of low pressure arc discharge. Vacuum, 2016, 128, P. 123–127.Fedorov L.Yu., Karpov I.V., Ushakov A.V., et al. Study of Phase Composition of CuO/Cu2O Nanoparticles Produced in the Plasma of a Low-Pressure Arc Discharge. Inorganic Materials: Applied Research, 2018, 9 (2), P. 323–328.Fedorov L.Yu., Karpov I.V., Ushakov A.V., et al. Study of Phase Composition of CuO/Cu2O Nanoparticles Produced in the Plasma of a Low-Pressure Arc Discharge. Inorganic Materials: Applied Research, 2018, 9 (2), P. 323–328.Lin B., Bohanon T.M., Shih M.C., et al. X-ray Diffraction Studies of the Effects of Ca2+ and Cu2+ on Langmuir Monolayers of Heneicosanoic Acid. Langmuir, 1990, 6, P. 1665–1667.Lin B., Bohanon T.M., Shih M.C., et al. X-ray Diffraction Studies of the Effects of Ca2+ and Cu2+ on Langmuir Monolayers of Heneicosanoic Acid. Langmuir, 1990, 6, P. 1665–1667.Khomutov G.B., Yakovenko S.A., Yurova T.V., et al. Effect of compression of a stearic acid monolayer on interfacial binding of copper ions and cluster formation. Supramolecular Science, 1997, 4, P. 349–355.Khomutov G.B., Yakovenko S.A., Yurova T.V., et al. Effect of compression of a stearic acid monolayer on interfacial binding of copper ions and cluster formation. Supramolecular Science, 1997, 4, P. 349–355.Begletsova N., Selifonova E., Chumakov A., et al. Chemical synthesis of copper nanoparticles in aqueous solutions in the presence of anionic surfactant sodium dodecyl sulfate. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 552, P. 75–80.Begletsova N., Selifonova E., Chumakov A., et al. Chemical synthesis of copper nanoparticles in aqueous solutions in the presence of anionic surfactant sodium dodecyl sulfate. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 552, P. 75–80.Kosolapova K., Al-Alwani A., Gorbachev I., et al. Purification non-aqueous solution of quantum dots CdSe- CdS-ZnS from excess organic substance-stabilizer by use PE-HD membrane. Journal of Physics: Conference Series, 2015, 643, 012084.Kosolapova K., Al-Alwani A., Gorbachev I., et al. Purification non-aqueous solution of quantum dots CdSe- CdS-ZnS from excess organic substance-stabilizer by use PE-HD membrane. Journal of Physics: Conference Series, 2015, 643, 012084.Kumar R., Kumar M. Effect of size on cohesive energy, melting temperature and Debye temperature of nanomaterials. Indian J. Pure Appl. Phys., 2012, 50, P. 329–334.Kumar R., Kumar M. Effect of size on cohesive energy, melting temperature and Debye temperature of nanomaterials. Indian J. Pure Appl. Phys., 2012, 50, P. 329–334.Mikhailov A.I., Kabanov V.F., Gorbachev I.A., et al. Study of the properties of II-VI and III–V semiconductor quantum dots. Semiconductors, 2018, 52 (6), P. 750–754.Mikhailov A.I., Kabanov V.F., Gorbachev I.A., et al. Study of the properties of II-VI and III–V semiconductor quantum dots. Semiconductors, 2018, 52 (6), P. 750–754.Srivastava S., Kumar M., Agrawal A., et al. Synthesis and characterisation of copper oxide nanoparticles. Journal of Applied Physics, 2013, 5 (4), P. 61–65.Srivastava S., Kumar M., Agrawal A., et al. Synthesis and characterisation of copper oxide nanoparticles. Journal of Applied Physics, 2013, 5 (4), P. 61–65.

The authors declare that there are no conflicts of interest present.