najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2017-8-6-798-803najo-675Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХPorous polypropylene membrane contactors for dehumidification of gasesPorous polypropylene membrane contactors for dehumidification of gasesPetukhovD. I.PetukhovD. I.

1-73 Leninskiye gory, Moscow, 119991

1-73 Leninskiye gory, Moscow, 119991

di.petukhov@gmail.comEliseevAr. A.EliseevAr. A.

1-73 Leninskiye gory, Moscow, 119991

1-73 Leninskiye gory, Moscow, 119991

eliseev@inorg.chem.msu.ruPoyarkovA. A.PoyarkovA. A.

1-73 Leninskiye gory, Moscow, 119991

1-73 Leninskiye gory, Moscow, 119991

LukashinA. V.LukashinA. V.

1-73 Leninskiye gory, Moscow, 119991

1-73 Leninskiye gory, Moscow, 119991

EliseevAn. A.EliseevAn. A.

1-73 Leninskiye gory, Moscow, 119991

1-73 Leninskiye gory, Moscow, 119991

Department of Materials Science, Lomonosov Moscow State UniversityDepartment of Materials Science, Lomonosov Moscow State University20171208202586798803Copyright © Petukhov D.I., Eliseev A.A., Poyarkov A.A., Lukashin A.V., Eliseev A.A., 20252025Petukhov D.I., Eliseev A.A., Poyarkov A.A., Lukashin A.V., Eliseev A.A.Petukhov D.I., Eliseev A.A., Poyarkov A.A., Lukashin A.V., Eliseev A.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/675

We report the application of porous polypropylene hollow fiber membranes with 100×500 nm slit pores in membrane contactor for air dehumidification using triethylene glycol (TEG) as an absorbent. Experiment geometry with gas flow through the lumen of fiber and absorbent circulated on the shell side was utilized to enhance water vapor stage cut. The influence of gas flow rate, liquid circulation rate and water content in triethylene glycol solution on the performance of membrane contactor was studied. The obtained results reveal that the limiting step of water vapor absorption for lumen gas flow configuration is the diffusion of water into TEG volume. Using dry TEG solution and high circulation rate the dew point of feed gas can be decreased down to ∼ −30 ◦C for the membrane contactor performance of 30 – 60 l/(m2h), while with reducing dew point requirements to −10 ◦C the performance of the contactor over 1 m3/(m2h) is achievable.

We report the application of porous polypropylene hollow fiber membranes with 100×500 nm slit pores in membrane contactor for air dehumidification using triethylene glycol (TEG) as an absorbent. Experiment geometry with gas flow through the lumen of fiber and absorbent circulated on the shell side was utilized to enhance water vapor stage cut. The influence of gas flow rate, liquid circulation rate and water content in triethylene glycol solution on the performance of membrane contactor was studied. The obtained results reveal that the limiting step of water vapor absorption for lumen gas flow configuration is the diffusion of water into TEG volume. Using dry TEG solution and high circulation rate the dew point of feed gas can be decreased down to ∼ −30 ◦C for the membrane contactor performance of 30 – 60 l/(m2h), while with reducing dew point requirements to −10 ◦C the performance of the contactor over 1 m3/(m2h) is achievable.

dehumidificationmembrane contactorpolypropylene membranegas-liquid contactordehumidificationmembrane contactorpolypropylene membranegas-liquid contactorThe work is supported by the Ministry of education and science of the Russian Federation within a Federal Targeted Programme for “Research and Development in Priority Areas of Development of the Russian Scientific and Technological Complex for 2014 – 2020” (Agreement No. 14.604.21.0177, unique Project Identification RFMEFI60417X0177).ReferencesOwen M.S. Handbook: Fundamentals, American Society of Heating, Refrigerating, and Air-Conditioning Engineers. ASHRAE, Atlanta, 2005, 544 p.Owen M.S. Handbook: Fundamentals, American Society of Heating, Refrigerating, and Air-Conditioning Engineers. ASHRAE, Atlanta, 2005, 544 p.Pyatkov E.S., Surtaev V.N., et al. Conditioning of associated petroleum gas using capillary condensation technique with asymmetric microporous anodic alumina membranes. Oil Industry, 2016, 5, P. 82–85.Pyatkov E.S., Surtaev V.N., et al. Conditioning of associated petroleum gas using capillary condensation technique with asymmetric microporous anodic alumina membranes. Oil Industry, 2016, 5, P. 82–85.Petukhov D.I., Berekchiian M.V., et al. Experimental and Theoretical Study of Enhanced Vapor Transport through Nanochannels of Anodic Alumina Membranes in a Capillary Condensation Regime. Journal of Physical Chemistry C, 2016, 120 (20), P. 10982–10990.Petukhov D.I., Berekchiian M.V., et al. Experimental and Theoretical Study of Enhanced Vapor Transport through Nanochannels of Anodic Alumina Membranes in a Capillary Condensation Regime. Journal of Physical Chemistry C, 2016, 120 (20), P. 10982–10990.Öberg V., Goswami D.Y. Experimental Study of the Heat and Mass Transfer in a Packed Bed Liquid Desiccant Air Dehumidifier. Journal of Solar Energy Engineering, 1998, 120, P. 289–297.Öberg V., Goswami D.Y. Experimental Study of the Heat and Mass Transfer in a Packed Bed Liquid Desiccant Air Dehumidifier. Journal of Solar Energy Engineering, 1998, 120, P. 289–297.Wang W., Wu L., et al. An Overview of Adsorbents in the Rotary Desiccant Dehumidifier for Air Dehumidification. Drying Technology, 2013, 31, P. 1334–1345.Wang W., Wu L., et al. An Overview of Adsorbents in the Rotary Desiccant Dehumidifier for Air Dehumidification. Drying Technology, 2013, 31, P. 1334–1345.Lin H., Thompson S.M., et al. Dehydration of natural gas using membranes. Part I: Composite membranes. Journal of Membrane Science, 2012, 413–414, P. 70–81.Lin H., Thompson S.M., et al. Dehydration of natural gas using membranes. Part I: Composite membranes. Journal of Membrane Science, 2012, 413–414, P. 70–81.Rafique M.M., Gandhidasan P., Bahaidarah H.M.S. Liquid desiccant materials and dehumidifiers – A review. Renewable & Sustainable Energy Reviews, 2016, 56, P. 179–195.Rafique M.M., Gandhidasan P., Bahaidarah H.M.S. Liquid desiccant materials and dehumidifiers – A review. Renewable & Sustainable Energy Reviews, 2016, 56, P. 179–195.Liu X.-H., Yi X.-Q., Jiang Y. Mass transfer performance comparison of two commonly used liquid desiccants: LiBr and LiCl aqueous solutions. Energy Conversion and Management, 2011, 52, P. 180–190.Liu X.-H., Yi X.-Q., Jiang Y. Mass transfer performance comparison of two commonly used liquid desiccants: LiBr and LiCl aqueous solutions. Energy Conversion and Management, 2011, 52, P. 180–190.Kohl A.L., Nielsen R. Richard B. Gas purification, Gulf Pub, Oxford, 1997, 900 p.Kohl A.L., Nielsen R. Richard B. Gas purification, Gulf Pub, Oxford, 1997, 900 p.Petukhov D.I., Poyarkov A.A., et al. Removal of acidic components of associated petroleum gas by pertraction on microporous membranes. Oil Industry, 2016, 11, P. 55–58.Petukhov D.I., Poyarkov A.A., et al. Removal of acidic components of associated petroleum gas by pertraction on microporous membranes. Oil Industry, 2016, 11, P. 55–58.Ovcharova A.A., Vasilevsky V.P., et al. Porous hollow fiber membranes with varying hydrophobic–hydrophilic surface properties for gas–liquid membrane contactors. Petroleum Chemistry, 2016, 56 (11), P. 1066–1073.Ovcharova A.A., Vasilevsky V.P., et al. Porous hollow fiber membranes with varying hydrophobic–hydrophilic surface properties for gas–liquid membrane contactors. Petroleum Chemistry, 2016, 56 (11), P. 1066–1073.Ovcharova A., Vasilevsky V., et al. Polysulfone porous hollow fiber membranes for ethylene-ethane separation in gas-liquid membrane contactor. Separation and Purification Technology, 2017, 183, P. 162–172.Ovcharova A., Vasilevsky V., et al. Polysulfone porous hollow fiber membranes for ethylene-ethane separation in gas-liquid membrane contactor. Separation and Purification Technology, 2017, 183, P. 162–172.Nieves-Remacha M.J., Kulkarni A.A., Jensen K.F. Gas–Liquid Flow and Mass Transfer in an Advanced-Flow Reactor. Industrial & Engineering Chemistry Research, 2013, 52, P. 8996–9010.Nieves-Remacha M.J., Kulkarni A.A., Jensen K.F. Gas–Liquid Flow and Mass Transfer in an Advanced-Flow Reactor. Industrial & Engineering Chemistry Research, 2013, 52, P. 8996–9010.Isetti C., Nannei Enrico M.A. On the application of a membrane air – liquid contactor for air dehumidification. Energy and Buildings, 1997, 25, P. 185–193.Isetti C., Nannei Enrico M.A. On the application of a membrane air – liquid contactor for air dehumidification. Energy and Buildings, 1997, 25, P. 185–193.Huang S.-M., Zhang L.-Z. Researches and trends in membrane-based liquid desiccant air dehumidification. Renewable & Sustainable Energy Reviews, 2013, 28, P. 425–440.Huang S.-M., Zhang L.-Z. Researches and trends in membrane-based liquid desiccant air dehumidification. Renewable & Sustainable Energy Reviews, 2013, 28, P. 425–440.Huang S.-M., Zhang L.-Z., Tang K., Pei L.-X. Fluid flow and heat mass transfer in membrane parallel-plates channels used for liquid desiccant air dehumidification. International Journal of Heat and Mass Transfer, 2012, 55, P. 2571–2580.Huang S.-M., Zhang L.-Z., Tang K., Pei L.-X. Fluid flow and heat mass transfer in membrane parallel-plates channels used for liquid desiccant air dehumidification. International Journal of Heat and Mass Transfer, 2012, 55, P. 2571–2580.Huang S.-M., Zhang L.-Z., Pei L.-X. Transport Phenomena in a Cross-Flow Hollow Fibre Membrane Bundle Used for Liquid Desiccant Air Dehumidification. Indoor and Built Environment, 2013, 22, P. 559–574.Huang S.-M., Zhang L.-Z., Pei L.-X. Transport Phenomena in a Cross-Flow Hollow Fibre Membrane Bundle Used for Liquid Desiccant Air Dehumidification. Indoor and Built Environment, 2013, 22, P. 559–574.Usachov V.V, Teplyakov V.V, Okunev A.Y., Laguntsov N.I. Membrane contactor air conditioning system: Experience and prospects. Separation and Purification Technology, 2007, 57, P. 502–506.Usachov V.V, Teplyakov V.V, Okunev A.Y., Laguntsov N.I. Membrane contactor air conditioning system: Experience and prospects. Separation and Purification Technology, 2007, 57, P. 502–506.Fakharnezhad A., Keshavarz P. Experimental investigation of gas dehumidification by tri-ethylene glycol in hollow fiber membrane contactors. Journal of Industrial and Engineering Chemistry, 2016, 34, P. 390–396.Fakharnezhad A., Keshavarz P. Experimental investigation of gas dehumidification by tri-ethylene glycol in hollow fiber membrane contactors. Journal of Industrial and Engineering Chemistry, 2016, 34, P. 390–396.Stull D.R. Vapor Pressure of Pure Substances. Organic and Inorganic Compounds. Industrial & Engineering Chemistry, 1947, 39, P. 517– 540.Stull D.R. Vapor Pressure of Pure Substances. Organic and Inorganic Compounds. Industrial & Engineering Chemistry, 1947, 39, P. 517– 540.Bridgeman O.C., Aldrich E.W. Vapor Pressure Tables for Water. Journal of Heat Transfer, 1964, 86, P. 279–286.Bridgeman O.C., Aldrich E.W. Vapor Pressure Tables for Water. Journal of Heat Transfer, 1964, 86, P. 279–286.Petukhov D.I., Eliseev A.A. Gas permeation through nanoporous membranes in the transitional flow region. Nanotechnology, 2016, 27, 085707.Petukhov D.I., Eliseev A.A. Gas permeation through nanoporous membranes in the transitional flow region. Nanotechnology, 2016, 27, 085707.Yan S.-P., Fang M.-X., et al. Experimental study on the separation of CO2 from flue gas using hollow fiber membrane contactors without wetting. Fuel Processing Technology, 2007, 88, P. 501–511.Yan S.-P., Fang M.-X., et al. Experimental study on the separation of CO2 from flue gas using hollow fiber membrane contactors without wetting. Fuel Processing Technology, 2007, 88, P. 501–511.

The authors declare that there are no conflicts of interest present.