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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2017-8-6-830-834</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-683</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMISTRY AND MATERIALS SCIENCE</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЯ И НАУКА О МАТЕРИАЛАХ</subject></subj-group></article-categories><title-group><article-title>The solubility of sodium and potassium fluorides in strontium fluoride</article-title><trans-title-group xml:lang="ru"><trans-title>The solubility of sodium and potassium fluorides in strontium fluoride</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Fedorov</surname><given-names>P. P.</given-names></name><name name-style="western" xml:lang="en"><surname>Fedorov</surname><given-names>P. P.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Moscow, 119991; Saransk, 430005</p></bio><bio xml:lang="en"><p>Moscow, 119991; Saransk, 430005</p></bio><email xlink:type="simple">ppfedorov@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Mayakova</surname><given-names>M. N.</given-names></name><name name-style="western" xml:lang="en"><surname>Mayakova</surname><given-names>M. N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Moscow, 119991</p></bio><bio xml:lang="en"><p>Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Maslov</surname><given-names>V. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Maslov</surname><given-names>V. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Moscow, 119991</p></bio><bio xml:lang="en"><p>Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Baranchikov</surname><given-names>A. E.</given-names></name><name name-style="western" xml:lang="en"><surname>Baranchikov</surname><given-names>A. E.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Moscow, 119991</p></bio><bio xml:lang="en"><p>Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Ivanov</surname><given-names>V. K.</given-names></name><name name-style="western" xml:lang="en"><surname>Ivanov</surname><given-names>V. K.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Moscow, 119991</p></bio><bio xml:lang="en"><p>Moscow, 119991</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Pynenkov</surname><given-names>A. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Pynenkov</surname><given-names>A. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Saransk, 430005</p></bio><bio xml:lang="en"><p>Saransk, 430005</p></bio><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Uslamina</surname><given-names>M. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Uslamina</surname><given-names>M. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Saransk, 430005</p></bio><bio xml:lang="en"><p>Saransk, 430005</p></bio><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Nishchev</surname><given-names>K. N.</given-names></name><name name-style="western" xml:lang="en"><surname>Nishchev</surname><given-names>K. N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Saransk, 430005</p></bio><bio xml:lang="en"><p>Saransk, 430005</p></bio><xref ref-type="aff" rid="aff-4"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Prokhorov General Physics Institute, Russian Academy of Sciences; Ogarev Mordovia State University</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Prokhorov General Physics Institute, Russian Academy of Sciences; Ogarev Mordovia State University</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Prokhorov General Physics Institute, Russian Academy of Sciences</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Prokhorov General Physics Institute, Russian Academy of Sciences</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-4"><aff xml:lang="ru"><institution>Ogarev Mordovia State University</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Ogarev Mordovia State University</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2017</year></pub-date><pub-date pub-type="epub"><day>12</day><month>08</month><year>2025</year></pub-date><volume>8</volume><issue>6</issue><fpage>830</fpage><lpage>834</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Fedorov P.P., Mayakova M.N., Maslov V.A., Baranchikov A.E., Ivanov V.K., Pynenkov A.A., Uslamina M.A., Nishchev K.N., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Fedorov P.P., Mayakova M.N., Maslov V.A., Baranchikov A.E., Ivanov V.K., Pynenkov A.A., Uslamina M.A., Nishchev K.N.</copyright-holder><copyright-holder xml:lang="en">Fedorov P.P., Mayakova M.N., Maslov V.A., Baranchikov A.E., Ivanov V.K., Pynenkov A.A., Uslamina M.A., Nishchev K.N.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/683">https://nanojournal.ifmo.ru/jour/article/view/683</self-uri><abstract><p>The phase diagram of the NaF–SrF2 system was studied by thermal analysis and X-ray powder diffraction analysis with the determination of the chemical composition. The system was found to be of the eutectic type. The eutectic co-ordinates are 853 ◦C, 32 mol % SrF2. A narrow range of the existence of solid solution Sr1−xNaxF2−x was established. The NaF solubility reaches a maximal value of x = 0.035 at eutectic temperature. The solubility of KF in SrF2 is very low.</p></abstract><trans-abstract xml:lang="ru"><p>The phase diagram of the NaF–SrF2 system was studied by thermal analysis and X-ray powder diffraction analysis with the determination of the chemical composition. The system was found to be of the eutectic type. The eutectic co-ordinates are 853 ◦C, 32 mol % SrF2. A narrow range of the existence of solid solution Sr1−xNaxF2−x was established. The NaF solubility reaches a maximal value of x = 0.035 at eutectic temperature. The solubility of KF in SrF2 is very low.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>strontium fluoride</kwd><kwd>sodium fluoride</kwd><kwd>potassium fluoride</kwd><kwd>nanofluorides</kwd><kwd>NaF-SrF2 phase diagram</kwd><kwd>solid solution</kwd></kwd-group><kwd-group xml:lang="en"><kwd>strontium fluoride</kwd><kwd>sodium fluoride</kwd><kwd>potassium fluoride</kwd><kwd>nanofluorides</kwd><kwd>NaF-SrF2 phase diagram</kwd><kwd>solid solution</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The authors express their appreciation V.V. Voronov for his kind assistance in the X-ray diffraction experiments. The authors also wish to thank E.V. Chernova for her help in the preparation of the present manuscript. This work was partially supported by RFBR 15-08-02481-a grant.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P., Maykova M.N., et al. Phase diagram of the NaF-CaF2 system and the electrical conductivity of a CaF2-based solid solution. Russian J. Inorg. Chem., 2016, 61 (11), P. 1472–1478.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P., Maykova M.N., et al. Phase diagram of the NaF-CaF2 system and the electrical conductivity of a CaF2-based solid solution. Russian J. Inorg. Chem., 2016, 61 (11), P. 1472–1478.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Sobolev B.P. The Rare Earth Trifluorides. P.1. The High-Temperature Chemistry of the Rare Earth Trifluorides. Barcelona 2000, 520 pp.</mixed-citation><mixed-citation xml:lang="en">Sobolev B.P. The Rare Earth Trifluorides. P.1. The High-Temperature Chemistry of the Rare Earth Trifluorides. Barcelona 2000, 520 pp.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P., Osiko V.V. Crystal Growth of Fluorides. In Bulk Crystal Growth of Electronic, Optical and Optoelectronic Materials. John Wiley &amp; Son, Ltd. 2005, P. 339–356.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P., Osiko V.V. Crystal Growth of Fluorides. In Bulk Crystal Growth of Electronic, Optical and Optoelectronic Materials. John Wiley &amp; Son, Ltd. 2005, P. 339–356.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Basiev T.T., Orlovskii Yu.V., et al. Continuous tunable cw lasing near 2.75 m in diode-pumped Er3+:SrF2 and Er3+:CaF2 crystals. Quantum Electronics, 2006, 36 (7), P. 591–594.</mixed-citation><mixed-citation xml:lang="en">Basiev T.T., Orlovskii Yu.V., et al. Continuous tunable cw lasing near 2.75 m in diode-pumped Er3+:SrF2 and Er3+:CaF2 crystals. Quantum Electronics, 2006, 36 (7), P. 591–594.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Alimov O.K., Basiev T.T., et al. Investigation of Nd3+ ions spectroscopic and laser properties in SrF2 fluoride single crystal. Optical Materials, 2012, 34 (5), P. 799–802.</mixed-citation><mixed-citation xml:lang="en">Alimov O.K., Basiev T.T., et al. Investigation of Nd3+ ions spectroscopic and laser properties in SrF2 fluoride single crystal. Optical Materials, 2012, 34 (5), P. 799–802.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Doroshenko M.E., Demidenko A.A., et al. Progress in fluoride laser ceramics. Phys. Stat. Solidi C, 2013, 10 (6), P. 952–957.</mixed-citation><mixed-citation xml:lang="en">Doroshenko M.E., Demidenko A.A., et al. Progress in fluoride laser ceramics. Phys. Stat. Solidi C, 2013, 10 (6), P. 952–957.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Rozhnova Yu.A., Luginina A.A., et al. White light luminophores based on Yb3+/Er3+/Tm3+ – coactivated strontium fluoride powders. Mat. Chem. Phys., 2014, 148, P. 201–207.</mixed-citation><mixed-citation xml:lang="en">Rozhnova Yu.A., Luginina A.A., et al. White light luminophores based on Yb3+/Er3+/Tm3+ – coactivated strontium fluoride powders. Mat. Chem. Phys., 2014, 148, P. 201–207.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov .P., Luginina A.A., Kuznetsov S.V., Osiko V.V. Nanofluorides. J. Fluorine Chem., 2011, 132 (12), P. 1012–1039.</mixed-citation><mixed-citation xml:lang="en">Fedorov .P., Luginina A.A., Kuznetsov S.V., Osiko V.V. Nanofluorides. J. Fluorine Chem., 2011, 132 (12), P. 1012–1039.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Luginina A.A., Fedorov P.P., et al. Synthesis of ultrafine fluorite Sr1−xNdxF2+x powders. Inorg. Mater., 2012, 48 (5), P. 531–538.</mixed-citation><mixed-citation xml:lang="en">Luginina A.A., Fedorov P.P., et al. Synthesis of ultrafine fluorite Sr1−xNdxF2+x powders. Inorg. Mater., 2012, 48 (5), P. 531–538.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Mayakova M.N., Luginina A.A., et al. Synthesis of SrF2–YF3 nanopowders by co-precipitation from aqueos solutions. Mendeleev Communications, 2014, 24 (6), P. 360–362.</mixed-citation><mixed-citation xml:lang="en">Mayakova M.N., Luginina A.A., et al. Synthesis of SrF2–YF3 nanopowders by co-precipitation from aqueos solutions. Mendeleev Communications, 2014, 24 (6), P. 360–362.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Rozhnova Yu.A., Kuznetsov S.V., et al. New Sr1−x−yRx(NH4)yF2+x−y (R = Yb, Er) solid solution as precursor for high efficiency up-conversion luminophor and optical ceramics on the base of strontium fluoride. Math. Chem. Phys., 2016, 172, P. 150–157.</mixed-citation><mixed-citation xml:lang="en">Rozhnova Yu.A., Kuznetsov S.V., et al. New Sr1−x−yRx(NH4)yF2+x−y (R = Yb, Er) solid solution as precursor for high efficiency up-conversion luminophor and optical ceramics on the base of strontium fluoride. Math. Chem. Phys., 2016, 172, P. 150–157.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Yagoub M.Y.A., Swart H.C., et al. Surface characterization and photoluminescence properties of Ce3+, Eu Co-doped SrF2 nanophosphor. Materials, 2015, 8, P. 2361–2375.</mixed-citation><mixed-citation xml:lang="en">Yagoub M.Y.A., Swart H.C., et al. Surface characterization and photoluminescence properties of Ce3+, Eu Co-doped SrF2 nanophosphor. Materials, 2015, 8, P. 2361–2375.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Sun J., Xian J., Zhang X., Du H. Hydrothermal synthesis of SrF2:Yb3+/Er3+ micro-/nanocrystals with multiform morphologies and upconversion properties. J. Rare Earth, 2011, 29, P. 32–38.</mixed-citation><mixed-citation xml:lang="en">Sun J., Xian J., Zhang X., Du H. Hydrothermal synthesis of SrF2:Yb3+/Er3+ micro-/nanocrystals with multiform morphologies and upconversion properties. J. Rare Earth, 2011, 29, P. 32–38.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Sun J., Xian J., Du H. Facile synthesis of well-dispersed SrF2:Yb3+/Er3+ upconversion nanocrystals in oleate complex systems. Appl. Surf. Sci., 2011, 257, P. 3592–3595.</mixed-citation><mixed-citation xml:lang="en">Sun J., Xian J., Du H. Facile synthesis of well-dispersed SrF2:Yb3+/Er3+ upconversion nanocrystals in oleate complex systems. Appl. Surf. Sci., 2011, 257, P. 3592–3595.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Ritter B., Krahl T., Scholz G., Kemnitz E. Local structures of solid solutions Sr1xYxF2+x (x = 0 0.5) with fluorite structure prepared by SolGel and mechanochemical syntheses. J. Phys. Chem. C, 2016, 120, P. 8992–8999.</mixed-citation><mixed-citation xml:lang="en">Ritter B., Krahl T., Scholz G., Kemnitz E. Local structures of solid solutions Sr1xYxF2+x (x = 0 0.5) with fluorite structure prepared by SolGel and mechanochemical syntheses. J. Phys. Chem. C, 2016, 120, P. 8992–8999.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P., Luginina A.A., Popov A.I. Transparent oxyfluoride glass ceramics. J. Fluorine Chem., 2015, 172, P. 22–50.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P., Luginina A.A., Popov A.I. Transparent oxyfluoride glass ceramics. J. Fluorine Chem., 2015, 172, P. 22–50.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Renaud E., Robelin Ch., Gheribi A.E., Chartrand P. Thermodynamic evaluation and optimization of the (LiF + NaF + KF + MgF2 + CaF2 + SrF2) system. J. Chem. Thermodynamics, 2011, 43, P. 1286–1298.</mixed-citation><mixed-citation xml:lang="en">Renaud E., Robelin Ch., Gheribi A.E., Chartrand P. Thermodynamic evaluation and optimization of the (LiF + NaF + KF + MgF2 + CaF2 + SrF2) system. J. Chem. Thermodynamics, 2011, 43, P. 1286–1298.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Bukhalova G.A. The system Na, Sr, F, Cl. Izv. AN SSSR, Sektor fiz.-khim. analiza, 1955, 26, P. 138–146 (in Russian).</mixed-citation><mixed-citation xml:lang="en">Bukhalova G.A. The system Na, Sr, F, Cl. Izv. AN SSSR, Sektor fiz.-khim. analiza, 1955, 26, P. 138–146 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Berezhnaya V.T., Bukhalova G.A. Ternary systems of strontium fluoride with fluorides of alkaline metals. Zh. Neorg. Khimii, 1960, 5 (4), P. 925–929 (in Russian).</mixed-citation><mixed-citation xml:lang="en">Berezhnaya V.T., Bukhalova G.A. Ternary systems of strontium fluoride with fluorides of alkaline metals. Zh. Neorg. Khimii, 1960, 5 (4), P. 925–929 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Cantor S. Freezing point depressions in sodium fluoride. Effect of alkaline earth fluorides. J. Phys. Chem., 1961, 65, P. 2208–2210.</mixed-citation><mixed-citation xml:lang="en">Cantor S. Freezing point depressions in sodium fluoride. Effect of alkaline earth fluorides. J. Phys. Chem., 1961, 65, P. 2208–2210.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Delbove F. Application de la method cryometrique a haute temperature a letude de la formation de solutions solides dans les fluorures alcalino-terreux, a la limite de dilution infinite. Silicates Industriels, 1967, 32, P. 2659–2667.</mixed-citation><mixed-citation xml:lang="en">Delbove F. Application de la method cryometrique a haute temperature a letude de la formation de solutions solides dans les fluorures alcalino-terreux, a la limite de dilution infinite. Silicates Industriels, 1967, 32, P. 2659–2667.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Bollmann W., Go¨rlich P., Hauk W., Mothes H. Ionic conduction of pure and doped CaF2 and SrF2 crystals. Phys. stat. sol. (a), 1970, 2, P. 157–170.</mixed-citation><mixed-citation xml:lang="en">Bollmann W., Go¨rlich P., Hauk W., Mothes H. Ionic conduction of pure and doped CaF2 and SrF2 crystals. Phys. stat. sol. (a), 1970, 2, P. 157–170.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P., Kuznetsov S.V., et al. Coprecipitation from aqueous solutions to prepare binary fluorides. Russian J. Inorg. Chem., 2011, 56 (10), P. 1525–1531.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P., Kuznetsov S.V., et al. Coprecipitation from aqueous solutions to prepare binary fluorides. Russian J. Inorg. Chem., 2011, 56 (10), P. 1525–1531.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov. P., Mayakova M.N., et al. Co-precipitation of yttrium and barium fluorides from aqueous solutions. Mater. Res. Bull., 2012, 47, P. 1794–1799.</mixed-citation><mixed-citation xml:lang="en">Fedorov. P., Mayakova M.N., et al. Co-precipitation of yttrium and barium fluorides from aqueous solutions. Mater. Res. Bull., 2012, 47, P. 1794–1799.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P., Mayakova M.N., et al. Synthesis of CaF2–YF3 nanopowders by co-precipitation from aqueos solutions. Nanosystems: Physics, Chemistry, Mathematics, 2017, 8 (4), P. 462–470.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P., Mayakova M.N., et al. Synthesis of CaF2–YF3 nanopowders by co-precipitation from aqueos solutions. Nanosystems: Physics, Chemistry, Mathematics, 2017, 8 (4), P. 462–470.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Ivanov V.K., Fedorov P.P., Baranchikov A.Y., Osiko V.V. Oriented aggregation of particles: 100 years of investigations of non-classical crystal growth. Russ. Chem. Rev., 2014, 83 (12), P. 1204–1222.</mixed-citation><mixed-citation xml:lang="en">Ivanov V.K., Fedorov P.P., Baranchikov A.Y., Osiko V.V. Oriented aggregation of particles: 100 years of investigations of non-classical crystal growth. Russ. Chem. Rev., 2014, 83 (12), P. 1204–1222.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P. Third law of thermodynamics as applied to phase diagrams. Russ. J. Inorg. Chem., 2010, 55 (11), P. 1722–1739.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P. Third law of thermodynamics as applied to phase diagrams. Russ. J. Inorg. Chem., 2010, 55 (11), P. 1722–1739.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P. Heterovalent isomorphism and solid solutions with a variable number of ions in the unit cell. Russ. J. Inorg. Chem., 2000, 45 (3), P. 268–291.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P. Heterovalent isomorphism and solid solutions with a variable number of ions in the unit cell. Russ. J. Inorg. Chem., 2000, 45 (3), P. 268–291.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Fedorov P.P., Kuznetsov S.V., Osiko V.V. Elaboration of nanofluorides and ceramics for optical and laser applications. In Photonic &amp; Electronic Properties of Fluoride Materials, Elsevier, 2016, P. 7–31.</mixed-citation><mixed-citation xml:lang="en">Fedorov P.P., Kuznetsov S.V., Osiko V.V. Elaboration of nanofluorides and ceramics for optical and laser applications. In Photonic &amp; Electronic Properties of Fluoride Materials, Elsevier, 2016, P. 7–31.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
