najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2018-9-1-14-16najo-734Research ArticleСтатьиThermal-lens spectrometer for studying thermophysical properties of fullerenesMikheevI. V.

Moscow 

UsoltsevaL. O.

Moscow 

IvshukovD. A.

Moscow 

VolkovD. S.

Moscow 

KorobovM. V.

Moscow 

ProskurninM. A.

Moscow 

Chemistry Department, Lomonosov Moscow State University; Analytical Centre of Lomonosov Moscow State University / Agilent Technologies Authorized Partner LaboratoryRussian FederationChemistry Department, Lomonosov Moscow State UniversityRussian Federation201824082025911416Copyright © Mikheev I.V., Usoltseva L.O., Ivshukov D.A., Volkov D.S., Korobov M.V., Proskurnin M.A., 20252025Mikheev I.V., Usoltseva L.O., Ivshukov D.A., Volkov D.S., Korobov M.V., Proskurnin M.A.Mikheev I.V., Usoltseva L.O., Ivshukov D.A., Volkov D.S., Korobov M.V., Proskurnin M.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/734

A thermal-lens spectrometer implementing back-synchronized detection technique with a mode-mismatched optical scheme was constructed. Steady-state and transient signals of thermal-lens spectrometry are used to characterize concentration parameters of aqueous fullerene dispersions (AFDs) at the level of 10−7 – 10−5 M and to assess thermophysical properties of AFDs. The detection limits of fullerenes in AFDs are 100 nM for C60, 80 nM for C70 and C78 – C88, and 60 nM for Y@C82, which are 20-fold lower than for spectrophotometry. Suitable precision of measurements of thermal diffusivity and thermal effusivity for AFDs is shown.

thermal-lens spectrometrypristine fullerenesaqueous fullerene dispersionsthermal diffusivity.The work is supported by The Russian Science Foundation, grant no. 14-23-00012-P. We are grateful to Dr. I. E. Kareev (Institute of Problems of Chemical Physics of the Russian Academy of Sciences, Chernogolovka, Russia) for the support of endofullerenes and higher fullerene fractions.ReferencesVargas H., Miranda L. Photothermal techniques applied to thermophysical properties measurements (plenary). Rev. Sci. Instrum., 2003, 74 (1), P. 794–799.Vargas H., Miranda L. Photothermal techniques applied to thermophysical properties measurements (plenary). Rev. Sci. Instrum., 2003, 74 (1), P. 794–799.Mikheev I.V., Usoltseva L.O., et al. Approach to the Assessment of Size-Dependent Thermal Properties of Disperse Solutions: TimeResolved Photothermal Lensing of Aqueous Pristine Fullerenes C60 and C70. J. Phys. Chem. C, 2016, 120 (49), P. 28270–28287.Mikheev I.V., Usoltseva L.O., et al. 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The authors declare that there are no conflicts of interest present.