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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2016-7-1-22-29</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-751</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PAPERS, PRESENTED AT THE CONFERENCE</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>PAPERS, PRESENTED AT THE CONFERENCE</subject></subj-group></article-categories><title-group><article-title>Biocompatible water-soluble endometallofullerenes: peculiarities of self-assembly in aqueous solutions and ordering under an applied magnetic field</article-title><trans-title-group xml:lang="ru"><trans-title>Biocompatible water-soluble endometallofullerenes: peculiarities of self-assembly in aqueous solutions and ordering under an applied magnetic field</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Lebedev</surname><given-names>V. T.</given-names></name><name name-style="western" xml:lang="en"><surname>Lebedev</surname><given-names>V. T.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300 Gatchina, Leningrad distr.</p></bio><bio xml:lang="en"><p>188300 Gatchina, Leningrad distr.</p></bio><email xlink:type="simple">vlebedev@pnpi.spb.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Kulvelis</surname><given-names>Yu. V.</given-names></name><name name-style="western" xml:lang="en"><surname>Kulvelis</surname><given-names>Yu. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300 Gatchina, Leningrad distr.</p></bio><bio xml:lang="en"><p>188300 Gatchina, Leningrad distr.</p></bio><email xlink:type="simple">kulvelis@pnpi.spb.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Runov</surname><given-names>V. V.</given-names></name><name name-style="western" xml:lang="en"><surname>Runov</surname><given-names>V. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300 Gatchina, Leningrad distr.</p></bio><bio xml:lang="en"><p>188300 Gatchina, Leningrad distr.</p></bio><email xlink:type="simple">runov@pnpi.spb.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Szhogina</surname><given-names>A. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Szhogina</surname><given-names>A. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300 Gatchina, Leningrad distr.</p></bio><bio xml:lang="en"><p>188300 Gatchina, Leningrad distr.</p></bio><email xlink:type="simple">allin_ok2@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Suyasova</surname><given-names>M. V.</given-names></name><name name-style="western" xml:lang="en"><surname>Suyasova</surname><given-names>M. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300 Gatchina, Leningrad distr.</p></bio><bio xml:lang="en"><p>188300 Gatchina, Leningrad distr.</p></bio><email xlink:type="simple">marinasuyasova@pnpi.spb.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Petersburg Nuclear Physics Institute, NRC Kurchatov Institute</institution></aff><aff xml:lang="en"><institution>Petersburg Nuclear Physics Institute, NRC Kurchatov Institute</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2016</year></pub-date><pub-date pub-type="epub"><day>14</day><month>08</month><year>2025</year></pub-date><volume>7</volume><issue>1</issue><issue-title>Special Issue: Proceedings of the 12th Biennial International Conference “Advanced Carbon Nanostructures” (ACNS’2015)</issue-title><fpage>22</fpage><lpage>29</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Lebedev V.T., Kulvelis Y.V., Runov V.V., Szhogina A.A., Suyasova M.V., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Lebedev V.T., Kulvelis Y.V., Runov V.V., Szhogina A.A., Suyasova M.V.</copyright-holder><copyright-holder xml:lang="en">Lebedev V.T., Kulvelis Y.V., Runov V.V., Szhogina A.A., Suyasova M.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/751">https://nanojournal.ifmo.ru/jour/article/view/751</self-uri><abstract><p>The self-organization of water-soluble endometallofullerenes (fullerenols) in solutions has been studied by neutron scattering in connection with their applications (Magneto-Resonance Imaging, X-Ray Tomography). Their functional characteristics depend strongly on molecular self-assembly which may be altered by chemical additives, concentration increase or the magnetic field applied. Polarized neutrons have been used to search paramagnetic fullerenols’ organization into supramolecular structures influenced by the fullerenol concentration and their intensified interactions in a magnetic field.</p></abstract><trans-abstract xml:lang="ru"><p>The self-organization of water-soluble endometallofullerenes (fullerenols) in solutions has been studied by neutron scattering in connection with their applications (Magneto-Resonance Imaging, X-Ray Tomography). Their functional characteristics depend strongly on molecular self-assembly which may be altered by chemical additives, concentration increase or the magnetic field applied. Polarized neutrons have been used to search paramagnetic fullerenols’ organization into supramolecular structures influenced by the fullerenol concentration and their intensified interactions in a magnetic field.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>endofullerene</kwd><kwd>structure</kwd><kwd>assembly</kwd><kwd>biomedicine</kwd><kwd>neutron scattering</kwd></kwd-group><kwd-group xml:lang="en"><kwd>endofullerene</kwd><kwd>structure</kwd><kwd>assembly</kwd><kwd>biomedicine</kwd><kwd>neutron scattering</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The work is supported by Russian Found for Basic Research (grant 14-23-01015 ofi m).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Heath J.R., O’Brien S.C., et al. Lanthanum complexes of spheriodal carbon shells. J. Am. Chem. Soc., 1985, 107, P. 7779–7780.</mixed-citation><mixed-citation xml:lang="en">Heath J.R., O’Brien S.C., et al. Lanthanum complexes of spheriodal carbon shells. J. Am. Chem. Soc., 1985, 107, P. 7779–7780.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Piotrovsky L., Eropkin M., et al. Biological Effects in Cell Cultures of Fullerene C60: Dependence on Aggregation State. In: Medicinal Chemistry and Pharmacological Potential of Fullerenes and Carbon Nanotubes. Eds. F. Cataldo, T. Da Ros. Germany: Springer, 2008, P. 139–155.</mixed-citation><mixed-citation xml:lang="en">Piotrovsky L., Eropkin M., et al. Biological Effects in Cell Cultures of Fullerene C60: Dependence on Aggregation State. In: Medicinal Chemistry and Pharmacological Potential of Fullerenes and Carbon Nanotubes. Eds. F. Cataldo, T. Da Ros. Germany: Springer, 2008, P. 139–155.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Kato H., Kanazawa Y., et al. Lanthanoid endohe-dral metallofullerenols for MRI contrast agents. J. Am. Chem. Soc., 2003, 125, P. 4391–4397.</mixed-citation><mixed-citation xml:lang="en">Kato H., Kanazawa Y., et al. Lanthanoid endohe-dral metallofullerenols for MRI contrast agents. J. Am. Chem. Soc., 2003, 125, P. 4391–4397.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Yin J.J., Lao F., et al. The scavenging of reactive oxygen species and the potential for cell protection by functionalized fullerene materials. Biomaterials, 2009, 30 (4), P. 611–621.</mixed-citation><mixed-citation xml:lang="en">Yin J.J., Lao F., et al. The scavenging of reactive oxygen species and the potential for cell protection by functionalized fullerene materials. Biomaterials, 2009, 30 (4), P. 611–621.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Grushko Yu.S., Kozlov V.S., et al. MRI-contrasting system based on water-soluble fullerene / Gd-metallofullerene mixture. Fuller., Nanotub. Carbon Nanostr., 2010, 18 (4), P. 417–421.</mixed-citation><mixed-citation xml:lang="en">Grushko Yu.S., Kozlov V.S., et al. MRI-contrasting system based on water-soluble fullerene / Gd-metallofullerene mixture. Fuller., Nanotub. Carbon Nanostr., 2010, 18 (4), P. 417–421.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Grushko Yu.S., Sedov V.P., Kozlov V.S., Tsirlina E.V. Method of preparation of MRI-contrasting agent. Patent RU 2396207 C2 from 10.08.2010, Bull. No. 22, 2010.</mixed-citation><mixed-citation xml:lang="en">Grushko Yu.S., Sedov V.P., Kozlov V.S., Tsirlina E.V. Method of preparation of MRI-contrasting agent. Patent RU 2396207 C2 from 10.08.2010, Bull. No. 22, 2010.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Toth E., Bolskar R.D., et al. Water-soluble gadofullerenes: toward high-relaxivity, pH-responsive MRI contrast agents. J. Am. Chem. Soc., 2005, 127 (2), P. 799–805.</mixed-citation><mixed-citation xml:lang="en">Toth E., Bolskar R.D., et al. Water-soluble gadofullerenes: toward high-relaxivity, pH-responsive MRI contrast agents. J. Am. Chem. Soc., 2005, 127 (2), P. 799–805.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Runov V.V., Il’in D.S., Runova M.K., Radzhabov A.K. Study of ferromagnetic correlations caused by the impurities in non magnetic materials by the method of small-angle scattering of polarized neutrons. JETP Lett., 2012, 95 (9), P. 467–470.</mixed-citation><mixed-citation xml:lang="en">Runov V.V., Il’in D.S., Runova M.K., Radzhabov A.K. Study of ferromagnetic correlations caused by the impurities in non magnetic materials by the method of small-angle scattering of polarized neutrons. JETP Lett., 2012, 95 (9), P. 467–470.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Lindner P. Water standard calibration at D11 verified with polymer samples. J. Appl. Crystallography, 2000, 33, P. 807–811.</mixed-citation><mixed-citation xml:lang="en">Lindner P. Water standard calibration at D11 verified with polymer samples. J. Appl. Crystallography, 2000, 33, P. 807–811.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Kitazawa H., Hashi K., et al. Molecular dynamics and structural phase transition in C60 nanowhiskers. J. Phys.: Conf. Series, 2009, 159, 012022 (1).</mixed-citation><mixed-citation xml:lang="en">Kitazawa H., Hashi K., et al. Molecular dynamics and structural phase transition in C60 nanowhiskers. J. Phys.: Conf. Series, 2009, 159, 012022 (1).</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
