najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2016-7-1-99-103najo-806Research ArticlePAPERS, PRESENTED AT THE CONFERENCEPAPERS, PRESENTED AT THE CONFERENCEInvestigation and modeling of evolution of C60/NMP solution UV-Vis spectraInvestigation and modeling of evolution of C60/NMP solution UV-Vis spectraJargalanN.JargalanN.

Dubna, Russia; Ulaanbaatar, Mongolia

Dubna, Russia; Ulaanbaatar, Mongolia

narmandah@jinr.ruTropinT. V.TropinT. V.

Dubna

Dubna

ttv@jinr.ruAvdeevM. V.AvdeevM. V.

Dubna

Dubna

AksenovV. L.AksenovV. L.

Dubna; Gatchina

Dubna; Gatchina

Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research; Institute of Physics and Technology, Mongolian Academy of SciencesFrank Laboratory of Neutron Physics, Joint Institute for Nuclear Research; Institute of Physics and Technology, Mongolian Academy of SciencesFrank Laboratory of Neutron Physics, Joint Institute for Nuclear ResearchFrank Laboratory of Neutron Physics, Joint Institute for Nuclear ResearchFrank Laboratory of Neutron Physics, Joint Institute for Nuclear Research; Petersburg Nuclear Physics Institute, National Research Centre ‘Kurchatov Institute’Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research; Petersburg Nuclear Physics Institute, National Research Centre ‘Kurchatov Institute’20161408202571Special Issue: Proceedings of the 12th Biennial International Conference “Advanced Carbon Nanostructures” (ACNS’2015)99103Copyright © Jargalan N., Tropin T.V., Avdeev M.V., Aksenov V.L., 20252025Jargalan N., Tropin T.V., Avdeev M.V., Aksenov V.L.Jargalan N., Tropin T.V., Avdeev M.V., Aksenov V.L.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/806

The kinetics for the dissolution of fullerene C60 in N-methyl-2-pyrrolidone (NMP) solvent are investigated through measurements of the stirring speed and temperature dependence of the UV-Vis absorption spectra. We develop a model for the kinetics of simultaneously occurring processes in the solution, employing a system of simple kinetic equations and obtain the corresponding parameters dependence on preparation conditions. The obtained results will allow one in the future to consider these effects when modeling the slow growth kinetics of large clusters in C60/NMP solutions.

The kinetics for the dissolution of fullerene C60 in N-methyl-2-pyrrolidone (NMP) solvent are investigated through measurements of the stirring speed and temperature dependence of the UV-Vis absorption spectra. We develop a model for the kinetics of simultaneously occurring processes in the solution, employing a system of simple kinetic equations and obtain the corresponding parameters dependence on preparation conditions. The obtained results will allow one in the future to consider these effects when modeling the slow growth kinetics of large clusters in C60/NMP solutions.

kinetics of dissolutionfullereneN-methyl-2-pyrrolidoneUV-Viskinetics of dissolutionfullereneN-methyl-2-pyrrolidoneUV-VisThe work was supported by the Russian Foundation of Basic Research, project No. 14-23-01015. The financial support is gratefully acknowledged.ReferencesBeck M.T., M’andi G. Solubility of C60. Fuller. Sci. Technol., 1997, 5 (2), P. 291–310.Beck M.T., M’andi G. Solubility of C60. Fuller. Sci. Technol., 1997, 5 (2), P. 291–310.Avdeev M.V., Aksenov V.L., Tropin T.V. Models of cluster formation and growth in fullerene solutions. Russ. J. Phys. Chem. A, 2010, 84, P. 1273–1283.Avdeev M.V., Aksenov V.L., Tropin T.V. Models of cluster formation and growth in fullerene solutions. Russ. J. Phys. Chem. A, 2010, 84, P. 1273–1283.Wang C.I., Hua C.C., Chen S.A. Dynamic solvation shell and solubility of C60 in organic solvents. J. Phys. Chem. B, 2014, 118, P. 9964–9973.Wang C.I., Hua C.C., Chen S.A. Dynamic solvation shell and solubility of C60 in organic solvents. J. Phys. Chem. B, 2014, 118, P. 9964–9973.Meng Z., Hashmi S.M., Elimelech M. Aggregation rate and fractal dimension of fullerene nanoparticles via simultaneous multiangle static and dynamic light scattering measurement. J. Colloid Interface Sci., 2013, 392, P. 27–33.Meng Z., Hashmi S.M., Elimelech M. Aggregation rate and fractal dimension of fullerene nanoparticles via simultaneous multiangle static and dynamic light scattering measurement. J. Colloid Interface Sci., 2013, 392, P. 27–33.Aksenov V.L., Avdeev M.V., et al. Formation of fullerene clusters in the system C60/NMP/water by SANS. Phys. B: Condens. Matter, 2006, 385–386, P. 795–797.Aksenov V.L., Avdeev M.V., et al. Formation of fullerene clusters in the system C60/NMP/water by SANS. Phys. B: Condens. Matter, 2006, 385–386, P. 795–797.Kyzyma O.A., Bulavin L.A., et al. Aggregation in C60/NMP, C60/NMP/water and C60/NMP/Toluene mixtures. Fullerenes, Nanotub. Carbon Nanostructures, 2008, 16, P. 610–615.Kyzyma O.A., Bulavin L.A., et al. Aggregation in C60/NMP, C60/NMP/water and C60/NMP/Toluene mixtures. Fullerenes, Nanotub. Carbon Nanostructures, 2008, 16, P. 610–615.Yevlampieva N.P., Biryulin Y.F., et al. Aggregation of fullerene C60 in N-methylpyrrolidone. Colloids Surfaces A: Physicochem. Eng. Asp., 2002, 209, P. 167–171.Yevlampieva N.P., Biryulin Y.F., et al. Aggregation of fullerene C60 in N-methylpyrrolidone. Colloids Surfaces A: Physicochem. Eng. Asp., 2002, 209, P. 167–171.Kyzyma O.A., Korobov M.V., et al. Solvatochromism and fullerene cluster formation in C60/N-methyl-2-pyrrolidone. Fullerenes, Nanotub. Carbon Nanostructures, 2010, 18, P. 458–461.Kyzyma O.A., Korobov M.V., et al. Solvatochromism and fullerene cluster formation in C60/N-methyl-2-pyrrolidone. Fullerenes, Nanotub. Carbon Nanostructures, 2010, 18, P. 458–461.Kyzyma O.A., Korobov M.V., et al. Aggregate development in C60/N-metyl-2-pyrrolidone solution and its mixture with water as revealed by extraction and mass spectroscopy. Chem. Phys. Lett., 2010, 493, P. 103–106.Kyzyma O.A., Korobov M.V., et al. Aggregate development in C60/N-metyl-2-pyrrolidone solution and its mixture with water as revealed by extraction and mass spectroscopy. Chem. Phys. Lett., 2010, 493, P. 103–106.Jargalan N., Tropin T.V., Avdeev M.V., Aksenov V.L. Investigation of the dissolution kinetics of fullerene C60 in solvents with different polarities by UV-Vis spectroscopy. J. Surf. Investig. X-Ray, Synchrotron Neutron Tech., 2015, 9, P. 16–20.Jargalan N., Tropin T.V., Avdeev M.V., Aksenov V.L. Investigation of the dissolution kinetics of fullerene C60 in solvents with different polarities by UV-Vis spectroscopy. J. Surf. Investig. X-Ray, Synchrotron Neutron Tech., 2015, 9, P. 16–20.Tropin T.V., Jargalan N., et al. Kinetics of cluster growth in polar solutions of fullerene: Experimental and theoretical study of C60/NMP solution. J. Mol. Liq., 2012, 175, P. 4–11.Tropin T.V., Jargalan N., et al. Kinetics of cluster growth in polar solutions of fullerene: Experimental and theoretical study of C60/NMP solution. J. Mol. Liq., 2012, 175, P. 4–11.

The authors declare that there are no conflicts of interest present.