najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2018-9-3-401-409najo-815Research ArticleCHEMISTRY AND MATERIAL SCIENCEХИМИЯ И МАТЕРИАЛОВЕДЕНИЕOptical properties and photocatalytic activity of nanocrystalline TiO2 doped by 3d-metal ionsKolesnikI. V.

Leninskie Hills, 1, Moscow, 119992

Leninsky avenue, 31, Moscow, 119991

kolesnik.iv@gmail.comLebedevV. A.

Leninskie Hills, 1, Moscow, 119992

vasya_lebedev@mail.ruGarshevA. V.

Leninskie Hills, 1, Moscow, 119992

Leninsky avenue, 49, Moscow, 119334

garshev@inorg.chem.msu.ruLomonosov Moscow State University; Institute of General and Inorganic ChemistryRussian FederationLomonosov Moscow State UniversityRussian FederationLomonosov Moscow State University; Institute of MetallurgyRussian Federation20181408202593401409Copyright © Kolesnik I.V., Lebedev V.A., Garshev A.V., 20252025Kolesnik I.V., Lebedev V.A., Garshev A.V.Kolesnik I.V., Lebedev V.A., Garshev A.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/815

The influence of impurities on optical and photocatalytic properties was studied in a series of nanocrystalline TiO2 with similar coherent scattering region sizes, phase compositions, surface areas and lattice parameters doped by Fe, Cr, Mn and V ions. Doping leads to an increase of absorption in the visible part of the spectrum due to the formation of additional levels in the band gap. In the case of Fe and Cr ions, d-d transitions are observed, whereas in the case of Mn and V ions, an additional band is associated with the transition from impurity level to Ec. The presence of impurities effectively suppresses photocatalytic activity in the methyl orange decoloration reaction.

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The authors declare that there are no conflicts of interest present.