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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2019-10-6-637-641</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-819</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMISTRY AND MATERIALS SCIENCE</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЯ И НАУКА О МАТЕРИАЛАХ</subject></subj-group></article-categories><title-group><article-title>Pt nanoparticle-functionalized RGO counter electrode for efficient dye-sensitized solar cells</article-title><trans-title-group xml:lang="ru"><trans-title>Pt nanoparticle-functionalized RGO counter electrode for efficient dye-sensitized solar cells</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Alexeeva</surname><given-names>O. V.</given-names></name><name name-style="western" xml:lang="en"><surname>Alexeeva</surname><given-names>O. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><bio xml:lang="en"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Kozlov</surname><given-names>S. S.</given-names></name><name name-style="western" xml:lang="en"><surname>Kozlov</surname><given-names>S. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><bio xml:lang="en"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Larina</surname><given-names>L. L.</given-names></name><name name-style="western" xml:lang="en"><surname>Larina</surname><given-names>L. L.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><bio xml:lang="en"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Shevaleevskiy</surname><given-names>O. I.</given-names></name><name name-style="western" xml:lang="en"><surname>Shevaleevskiy</surname><given-names>O. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><bio xml:lang="en"><p>Department of Solar Photovoltaics</p><p>Kosygin St. 4, Moscow, 119334</p></bio><email xlink:type="simple">shevale2006@yahoo.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Institute of Biochemical Physics RAS</institution></aff><aff xml:lang="en"><institution>Institute of Biochemical Physics RAS</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2019</year></pub-date><pub-date pub-type="epub"><day>13</day><month>08</month><year>2025</year></pub-date><volume>10</volume><issue>6</issue><fpage>637</fpage><lpage>641</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Alexeeva O.V., Kozlov S.S., Larina L.L., Shevaleevskiy O.I., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Alexeeva O.V., Kozlov S.S., Larina L.L., Shevaleevskiy O.I.</copyright-holder><copyright-holder xml:lang="en">Alexeeva O.V., Kozlov S.S., Larina L.L., Shevaleevskiy O.I.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/819">https://nanojournal.ifmo.ru/jour/article/view/819</self-uri><abstract><p>In this paper, we present a facile method for replacing conventional Pt-based counter electrode (CE) in dye-sensitized solar cells (DSCs) for the alternative low-cost nanostructured material containing reduced graphene oxide (RGO). Pt-NPs/RGO-based nanohybrid layers were synthesized at low temperature on a conductive glass substrate using microwave-assisted heating reduction strategy. The obtained material was characterized using XRD, SEM and TEM measurements and used for fabrication layered CEs on glass substrates. Photovoltaic characteristics of the DSCs based on Pt nanoparticle-functionalized RGO CEs were investigated under simulated AM1.5G solar illumination at an intensity of 1000 W/m2. The obtained results have shown that Pt-NPs decorated RGO surfaces can be successfully used as CEs in high-efficiency DSCs and may be promising as low-cost electrodes in energy storage devices.</p></abstract><trans-abstract xml:lang="ru"><p>In this paper, we present a facile method for replacing conventional Pt-based counter electrode (CE) in dye-sensitized solar cells (DSCs) for the alternative low-cost nanostructured material containing reduced graphene oxide (RGO). Pt-NPs/RGO-based nanohybrid layers were synthesized at low temperature on a conductive glass substrate using microwave-assisted heating reduction strategy. The obtained material was characterized using XRD, SEM and TEM measurements and used for fabrication layered CEs on glass substrates. Photovoltaic characteristics of the DSCs based on Pt nanoparticle-functionalized RGO CEs were investigated under simulated AM1.5G solar illumination at an intensity of 1000 W/m2. The obtained results have shown that Pt-NPs decorated RGO surfaces can be successfully used as CEs in high-efficiency DSCs and may be promising as low-cost electrodes in energy storage devices.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>nanostructures</kwd><kwd>reduced graphene oxide</kwd><kwd>thin films</kwd><kwd>semiconductors</kwd><kwd>solar photovoltaics</kwd><kwd>dye-sensitized solar cells</kwd></kwd-group><kwd-group xml:lang="en"><kwd>nanostructures</kwd><kwd>reduced graphene oxide</kwd><kwd>thin films</kwd><kwd>semiconductors</kwd><kwd>solar photovoltaics</kwd><kwd>dye-sensitized solar cells</kwd></kwd-group><funding-group><funding-statement xml:lang="en">This research was supported by RFBR grant 16-29-06416</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">O’Regan B., Gratzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353, P. 737–740.</mixed-citation><mixed-citation xml:lang="en">O’Regan B., Gratzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353, P. 737–740.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Shevaleevskiy O. The future of solar photovoltaics: from physics to chemistry. Pure Appl. Chem., 2008, 80, P. 2079–2089.</mixed-citation><mixed-citation xml:lang="en">Shevaleevskiy O. The future of solar photovoltaics: from physics to chemistry. Pure Appl. Chem., 2008, 80, P. 2079–2089.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Nikolay T., Larina, L., Shevaleevskiy O., Ahn B.T. Electronic structure study of lightly Nb-doped TiO2 electrode for dye-sensitized solar cells. Energ. Environ. Sci., 2011, 4, P.1480–1486.</mixed-citation><mixed-citation xml:lang="en">Nikolay T., Larina, L., Shevaleevskiy O., Ahn B.T. Electronic structure study of lightly Nb-doped TiO2 electrode for dye-sensitized solar cells. Energ. Environ. Sci., 2011, 4, P.1480–1486.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Vildanova M.F., Nikolskaia A.B., Kozlov S.S., Shevaleevskiy O.I., Larina L.L. Novel types of dye-sensitized and perovskite-based tandem solar cells with a common counter electrode. Tech. Phys. Lett., 2018, 44(2), P. 126–129.</mixed-citation><mixed-citation xml:lang="en">Vildanova M.F., Nikolskaia A.B., Kozlov S.S., Shevaleevskiy O.I., Larina L.L. Novel types of dye-sensitized and perovskite-based tandem solar cells with a common counter electrode. Tech. Phys. Lett., 2018, 44(2), P. 126–129.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Yum J., Jung I., Baik. C., Ko J., Nazeeruddin M.K., Gratzel M. High efficient donor–acceptor ruthenium complex for dye-sensitized solar cell application. Energ. Environ. Sci. 2009, 2, P. 100–102.</mixed-citation><mixed-citation xml:lang="en">Yum J., Jung I., Baik. C., Ko J., Nazeeruddin M.K., Gratzel M. High efficient donor–acceptor ruthenium complex for dye-sensitized solar cell application. Energ. Environ. Sci. 2009, 2, P. 100–102.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Dao V.D., Choi Y., Yong K., Larina L.L., Shevaleevskiy O., Choi H.-S. A facile synthesis of bimetallic AuPt nanoparticles as a new transparent counter electrode for quantum-dot-sensitized solar cells. J. Power Sources, 2015, 274, P. 831–838.</mixed-citation><mixed-citation xml:lang="en">Dao V.D., Choi Y., Yong K., Larina L.L., Shevaleevskiy O., Choi H.-S. A facile synthesis of bimetallic AuPt nanoparticles as a new transparent counter electrode for quantum-dot-sensitized solar cells. J. Power Sources, 2015, 274, P. 831–838.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Larina L.L., Alexeeva O.V., Almjasheva O.V., Gusarov V.V., Kozlov S.S., Nikolskaia A.B., Vildanova M.F., Shevaleevskiy O.I. Very widebandgap nanostructured metal oxide materials for perovskite solar cells. Nanosystems: Phys. Chem. Math., 2019, 10(1), P. 70–75.</mixed-citation><mixed-citation xml:lang="en">Larina L.L., Alexeeva O.V., Almjasheva O.V., Gusarov V.V., Kozlov S.S., Nikolskaia A.B., Vildanova M.F., Shevaleevskiy O.I. Very widebandgap nanostructured metal oxide materials for perovskite solar cells. Nanosystems: Phys. Chem. Math., 2019, 10(1), P. 70–75.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Almjasheva O.V., Smirnov A.V., Fedorov B.A., Tomkovich M.V., Gusarov V.V. Structural features of ZrO2–Y2O3 and ZrO2–Gd2O3 nanoparticles formed under hydrothermal conditions. Russ. J. Gen. Chem., 2014, 84(5), P. 804–809.</mixed-citation><mixed-citation xml:lang="en">Almjasheva O.V., Smirnov A.V., Fedorov B.A., Tomkovich M.V., Gusarov V.V. Structural features of ZrO2–Y2O3 and ZrO2–Gd2O3 nanoparticles formed under hydrothermal conditions. Russ. J. Gen. Chem., 2014, 84(5), P. 804–809.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Bugrov A.N., Almjasheva O.V. Effect of hydrothermal synthesis conditions on the morphology of ZrO2 nanoparticles. Nanosystems: Phys. Chem. Math., 2013, 4, P. 810–815.</mixed-citation><mixed-citation xml:lang="en">Bugrov A.N., Almjasheva O.V. Effect of hydrothermal synthesis conditions on the morphology of ZrO2 nanoparticles. Nanosystems: Phys. Chem. Math., 2013, 4, P. 810–815.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Kannan A.G., Zhao J., Jo S.G., Kang Y.S., Kim D.-W. Nitrogen and sulfur co-doped graphene counter electrodes with synergistically enhanced performance for dye-sensitized solar cells. J. Mater. Chem. A, 2014, 2, P. 12232–12239.</mixed-citation><mixed-citation xml:lang="en">Kannan A.G., Zhao J., Jo S.G., Kang Y.S., Kim D.-W. Nitrogen and sulfur co-doped graphene counter electrodes with synergistically enhanced performance for dye-sensitized solar cells. J. Mater. Chem. A, 2014, 2, P. 12232–12239.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Somik M., Balavinayagam R., Griggs L., Hamm S., Baker G.A., Fraundorf P., Sengupta S., Gangopadhyay S. Ultrafine sputter-deposited Pt nanoparticles for triiodide reduction in dye-sensitized solar cells: impact of nanoparticle size, crystallinity and surface coverage on catalytic activity. Nanotechnology, 2012, 23, P. 485405.</mixed-citation><mixed-citation xml:lang="en">Somik M., Balavinayagam R., Griggs L., Hamm S., Baker G.A., Fraundorf P., Sengupta S., Gangopadhyay S. Ultrafine sputter-deposited Pt nanoparticles for triiodide reduction in dye-sensitized solar cells: impact of nanoparticle size, crystallinity and surface coverage on catalytic activity. Nanotechnology, 2012, 23, P. 485405.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Dao V.-D., Hoa N.T.Q., Larina L.L., Lee J.-K., Choi H.-S. Graphene-platinum nanohybrid as a robust and low-cost counter electrode for dye-sensitized solar cells. Nanoscale, 2013, 5, P. 12237–12244.</mixed-citation><mixed-citation xml:lang="en">Dao V.-D., Hoa N.T.Q., Larina L.L., Lee J.-K., Choi H.-S. Graphene-platinum nanohybrid as a robust and low-cost counter electrode for dye-sensitized solar cells. Nanoscale, 2013, 5, P. 12237–12244.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Chen J., Yao B., Li C., Shi G. An improved Hummers method for eco-friendly synthesis of graphene oxide. Carbon, 2013, 64, P. 225–229.</mixed-citation><mixed-citation xml:lang="en">Chen J., Yao B., Li C., Shi G. An improved Hummers method for eco-friendly synthesis of graphene oxide. Carbon, 2013, 64, P. 225–229.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Gong F., Wang H., Wang Z.-S., Self-assembled monolayer of graphene/Pt as counter electrode for efficient dye-sensitized solar cell. Phys. Chem. Chem. Phys., 2011, 13, P. 17676–17682.</mixed-citation><mixed-citation xml:lang="en">Gong F., Wang H., Wang Z.-S., Self-assembled monolayer of graphene/Pt as counter electrode for efficient dye-sensitized solar cell. Phys. Chem. Chem. Phys., 2011, 13, P. 17676–17682.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Qui L., Zhang H., Wang W., Chen Y., Wang. R. Effects of Pt/RGO as counter electrode in dye-sensitized solar cells. Appl. Surf. Sci., 2014, 319, P. 339–343.</mixed-citation><mixed-citation xml:lang="en">Qui L., Zhang H., Wang W., Chen Y., Wang. R. Effects of Pt/RGO as counter electrode in dye-sensitized solar cells. Appl. Surf. Sci., 2014, 319, P. 339–343.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang D.W., Li X.D., Li H.B., Chen S., Sun Z., Yin X.J., Huang S.M. Graphene-based counter electrode for dye-sensitized solar cells. Carbon, 2011, 49(15), P. 5382–5388.</mixed-citation><mixed-citation xml:lang="en">Zhang D.W., Li X.D., Li H.B., Chen S., Sun Z., Yin X.J., Huang S.M. Graphene-based counter electrode for dye-sensitized solar cells. Carbon, 2011, 49(15), P. 5382–5388.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Ahn H.-J., Lee J.-S., Kim H.-S., Hwang I.-T., Hong J.-H., Shin J., Jung C.-H. Fabrication of large Pt nanoparticles-decorated rGO counter electrode for highly efficient DSSCs. J. Ind, Eng. Chem., 2018, 65, P. 318–324.</mixed-citation><mixed-citation xml:lang="en">Ahn H.-J., Lee J.-S., Kim H.-S., Hwang I.-T., Hong J.-H., Shin J., Jung C.-H. Fabrication of large Pt nanoparticles-decorated rGO counter electrode for highly efficient DSSCs. J. Ind, Eng. Chem., 2018, 65, P. 318–324.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Yoon S.-W., Dao V.-D., Larina L.L., Lee J.-K., Choi H.-S. Optimum strategy for designing PtCo alloy/reduced graphene oxide nanohybrid counter electrode for dye-sensitized solar cells. Carbon, 2016, 96, P. 229–336.</mixed-citation><mixed-citation xml:lang="en">Yoon S.-W., Dao V.-D., Larina L.L., Lee J.-K., Choi H.-S. Optimum strategy for designing PtCo alloy/reduced graphene oxide nanohybrid counter electrode for dye-sensitized solar cells. Carbon, 2016, 96, P. 229–336.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Dao V.-D., Ko S.H., Choi H.-S., Lee J.-K. Pt-NP–MWNT nanohybrid as a robust and low-cost counter electrode material for dye-sensitized solar cells. J. Mater. Chem., 2012, 22, P. 14023–14029.</mixed-citation><mixed-citation xml:lang="en">Dao V.-D., Ko S.H., Choi H.-S., Lee J.-K. Pt-NP–MWNT nanohybrid as a robust and low-cost counter electrode material for dye-sensitized solar cells. J. Mater. Chem., 2012, 22, P. 14023–14029.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Dao V.-D., Tran C.Q., Ko S.-H., Choi H.-S. Dry plasma reduction to synthesize supported platinum nanoparticles for flexible dye-sensitized solar cells. J. Mater. Chem. A, 2013, 1, P. 4436–4443.</mixed-citation><mixed-citation xml:lang="en">Dao V.-D., Tran C.Q., Ko S.-H., Choi H.-S. Dry plasma reduction to synthesize supported platinum nanoparticles for flexible dye-sensitized solar cells. J. Mater. Chem. A, 2013, 1, P. 4436–4443.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
