<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">najo</journal-id><journal-title-group><journal-title xml:lang="en">Nanosystems: Physics, Chemistry, Mathematics</journal-title><trans-title-group xml:lang="ru"><trans-title>Наносистемы: физика, химия, математика</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2220-8054</issn><issn pub-type="epub">2305-7971</issn><publisher><publisher-name>Университет ИТМО</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17586/2220-8054-2016-7-1-146-152</article-id><article-id custom-type="elpub" pub-id-type="custom">najo-826</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PAPERS, PRESENTED AT THE CONFERENCE</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>PAPERS, PRESENTED AT THE CONFERENCE</subject></subj-group></article-categories><title-group><article-title>Fullerenes and fullerenols survival under irradiation</article-title><trans-title-group xml:lang="ru"><trans-title>Fullerenes and fullerenols survival under irradiation</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Shilin</surname><given-names>V. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Shilin</surname><given-names>V. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><bio xml:lang="en"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><email xlink:type="simple">shilin@pnpi.spb.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Szhogina</surname><given-names>A. A.</given-names></name><name name-style="western" xml:lang="en"><surname>Szhogina</surname><given-names>A. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><bio xml:lang="en"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Suyasova</surname><given-names>M. V.</given-names></name><name name-style="western" xml:lang="en"><surname>Suyasova</surname><given-names>M. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><bio xml:lang="en"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Sedov</surname><given-names>V. P.</given-names></name><name name-style="western" xml:lang="en"><surname>Sedov</surname><given-names>V. P.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><bio xml:lang="en"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Lebedev</surname><given-names>V. T.</given-names></name><name name-style="western" xml:lang="en"><surname>Lebedev</surname><given-names>V. T.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><bio xml:lang="en"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Kozlov</surname><given-names>V. S.</given-names></name><name name-style="western" xml:lang="en"><surname>Kozlov</surname><given-names>V. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><bio xml:lang="en"><p>188300, Leningrad district, Gatchina, Orlova Roscha</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">National Research Centre “Kurchatov Institute” B.P. Konstantinov, Petersburg Nuclear Physics Institute<country>Россия</country></aff><aff xml:lang="en">National Research Centre “Kurchatov Institute” B.P. Konstantinov, Petersburg Nuclear Physics Institute<country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2016</year></pub-date><pub-date pub-type="epub"><day>14</day><month>08</month><year>2025</year></pub-date><volume>7</volume><issue>1</issue><issue-title>Special Issue: Proceedings of the 12th Biennial International Conference “Advanced Carbon Nanostructures” (ACNS’2015)</issue-title><fpage>146</fpage><lpage>152</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Shilin V.A., Szhogina A.A., Suyasova M.V., Sedov V.P., Lebedev V.T., Kozlov V.S., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Shilin V.A., Szhogina A.A., Suyasova M.V., Sedov V.P., Lebedev V.T., Kozlov V.S.</copyright-holder><copyright-holder xml:lang="en">Shilin V.A., Szhogina A.A., Suyasova M.V., Sedov V.P., Lebedev V.T., Kozlov V.S.</copyright-holder><license license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://nanojournal.ifmo.ru/jour/article/view/826">https://nanojournal.ifmo.ru/jour/article/view/826</self-uri><abstract><p>Fullerenes C2n, endometallofullerenes Gd@C2n, Gd@C82 and water-soluble Gd@C2n(OH)38−40 derivatives were synthesized. These substances’ survival dependences on the accumulated flux (1016 – 1019 neutron/cm2) of neutron irradiation over a wide spectrum of energies (from thermal to fast) in the WWR-M reactor zone (Petersburg Nuclear Physics Institute) have been examined.</p></abstract><trans-abstract xml:lang="ru"><p>Fullerenes C2n, endometallofullerenes Gd@C2n, Gd@C82 and water-soluble Gd@C2n(OH)38−40 derivatives were synthesized. These substances’ survival dependences on the accumulated flux (1016 – 1019 neutron/cm2) of neutron irradiation over a wide spectrum of energies (from thermal to fast) in the WWR-M reactor zone (Petersburg Nuclear Physics Institute) have been examined.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>fullerenes</kwd><kwd>endometallofullerenes</kwd><kwd>fullerenols</kwd><kwd>irradiation</kwd><kwd>survival</kwd></kwd-group><kwd-group xml:lang="en"><kwd>fullerenes</kwd><kwd>endometallofullerenes</kwd><kwd>fullerenols</kwd><kwd>irradiation</kwd><kwd>survival</kwd></kwd-group><funding-group xml:lang="en"><funding-statement>The work was supported by Russian Foundation for Basic Research (grant 14-23-01015 ofi_m).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Popov A.A., Yang S., Dunsch L. Endohedral Fullerenes. Chem. Rev., 2013, 113(8), P. 5989–6113.</mixed-citation><mixed-citation xml:lang="en">Popov A.A., Yang S., Dunsch L. Endohedral Fullerenes. Chem. Rev., 2013, 113(8), P. 5989–6113.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Gan L., Yang D., Zhang Q., Huang H. Preparation of open-cage fullerenes and incorporation of small molecules through their orifices. Adv. Mater., 2010, 22, P. 1498–1507.</mixed-citation><mixed-citation xml:lang="en">Gan L., Yang D., Zhang Q., Huang H. Preparation of open-cage fullerenes and incorporation of small molecules through their orifices. Adv. Mater., 2010, 22, P. 1498–1507.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Gan T., Hu C., Hu S. Preparation of graphene oxide-fullerene/phosphotungstic acid films and their application as sensor for the determination of cis-jasmone. Anal. Methods, 2014, 6, P. 9220–9227.</mixed-citation><mixed-citation xml:lang="en">Gan T., Hu C., Hu S. Preparation of graphene oxide-fullerene/phosphotungstic acid films and their application as sensor for the determination of cis-jasmone. Anal. Methods, 2014, 6, P. 9220–9227.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Grushko Yu.S., Khodorkovski M.A., Kozlov V.S., Kolesnik S.G., Shilin V.A., Grachev S.A., Artamonova T.O. Radioactive Metallofullerenes: Hot Atom Chemistry Aspects. Fuller., Nanotub. Carbon Nanostr., 2006, 14, P. 249–259.</mixed-citation><mixed-citation xml:lang="en">Grushko Yu.S., Khodorkovski M.A., Kozlov V.S., Kolesnik S.G., Shilin V.A., Grachev S.A., Artamonova T.O. Radioactive Metallofullerenes: Hot Atom Chemistry Aspects. Fuller., Nanotub. Carbon Nanostr., 2006, 14, P. 249–259.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Averbukh V., Cederbaum L.S. Interatomic electronic decay in endohedral fullerenes. Phys. Rev. Lett., 2006, 96, P. 401–405.</mixed-citation><mixed-citation xml:lang="en">Averbukh V., Cederbaum L.S. Interatomic electronic decay in endohedral fullerenes. Phys. Rev. Lett., 2006, 96, P. 401–405.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Sueki K., Akiyama K., Zhao Y. L., Ito I., Ohkubo Y., Kikuchi K., Katada M., Nakahara H. Systematic study of lanthanoid endohedral metallofullerenes: Production yields, HPLC retention time and reactor irradiation effects. J. Radioanalytical Nuclear Chem., 2003, 255(1), P. 159–164.</mixed-citation><mixed-citation xml:lang="en">Sueki K., Akiyama K., Zhao Y. L., Ito I., Ohkubo Y., Kikuchi K., Katada M., Nakahara H. Systematic study of lanthanoid endohedral metallofullerenes: Production yields, HPLC retention time and reactor irradiation effects. J. Radioanalytical Nuclear Chem., 2003, 255(1), P. 159–164.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Sueki K., Kikuchi K., Tomura K., Nakahara H. Stability of metallofullerenes following neutron capture reaction on the metal ion. J. Radioanal. Nucl. Chem., 1998, 234, P. 95–100.</mixed-citation><mixed-citation xml:lang="en">Sueki K., Kikuchi K., Tomura K., Nakahara H. Stability of metallofullerenes following neutron capture reaction on the metal ion. J. Radioanal. Nucl. Chem., 1998, 234, P. 95–100.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Sueki K., Akiyama K., Kikuchi K., Nakahara H., Tomura K. Stability of Radio-Metallo-Fullerene against Beta-Decay. J. Radioanal. Nucl. Chem., 1999, 239(1), P. 179–185.</mixed-citation><mixed-citation xml:lang="en">Sueki K., Akiyama K., Kikuchi K., Nakahara H., Tomura K. Stability of Radio-Metallo-Fullerene against Beta-Decay. J. Radioanal. Nucl. Chem., 1999, 239(1), P. 179–185.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Nakahara H., Sueki K., Sato W., Akiyama K. Nuclear reactions and radionuclides in study of fullerenes. J. Radioanal. Nucl. Chem., 2000, 243(1), P. 169–179.</mixed-citation><mixed-citation xml:lang="en">Nakahara H., Sueki K., Sato W., Akiyama K. Nuclear reactions and radionuclides in study of fullerenes. J. Radioanal. Nucl. Chem., 2000, 243(1), P. 169–179.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Kozlov V.S., Suyasova M.V., Lebedev V.T. Synthesis, Extraction, and Chromatographic Purification of Higher Empty Fullerenes and Endoghedral Gadolinium Metallofullerenes. Russian J. Appl. Chem., 2014, 87(2), P. 121–127.</mixed-citation><mixed-citation xml:lang="en">Kozlov V.S., Suyasova M.V., Lebedev V.T. Synthesis, Extraction, and Chromatographic Purification of Higher Empty Fullerenes and Endoghedral Gadolinium Metallofullerenes. Russian J. Appl. Chem., 2014, 87(2), P. 121–127.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Suyasova M.V., Kozlov V.S. Synthesis and Chromatographic Study of Higher Empty Fullerenes and Endometallofullerenes in solutions. Communication of PNPI 2941. Gatchina, 2014. 20 p. (Rus.).</mixed-citation><mixed-citation xml:lang="en">Suyasova M.V., Kozlov V.S. Synthesis and Chromatographic Study of Higher Empty Fullerenes and Endometallofullerenes in solutions. Communication of PNPI 2941. Gatchina, 2014. 20 p. (Rus.).</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Goswami T.H., Singh R., Alam S., Mathur G.N. Thermal analysis: a unique method to estimate the number of substituents in fullerene derivatives. Thermochimica Acta, 2004, 419, P. 97–104.</mixed-citation><mixed-citation xml:lang="en">Goswami T.H., Singh R., Alam S., Mathur G.N. Thermal analysis: a unique method to estimate the number of substituents in fullerene derivatives. Thermochimica Acta, 2004, 419, P. 97–104.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Grushko Yu.S., Alekseev E.G., V.V. Voronin et. al. Tracer Study of Smx@C2n. Mol. Mat., 2006, 7, P. 115–118.</mixed-citation><mixed-citation xml:lang="en">Grushko Yu.S., Alekseev E.G., V.V. Voronin et. al. Tracer Study of Smx@C2n. Mol. Mat., 2006, 7, P. 115–118.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Shilin V.A., Lebedev V.T., Sedov V.P., Szhogina A.A. Fullerenes and their derivatives synthesis and radiation resistance. Crystallography (in press, Rus.).</mixed-citation><mixed-citation xml:lang="en">Shilin V.A., Lebedev V.T., Sedov V.P., Szhogina A.A. Fullerenes and their derivatives synthesis and radiation resistance. Crystallography (in press, Rus.).</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Suenaga K., Iijima S., Kato H., Shinohara H. Fine-structure analysis of Gd M45 near-edge EELS on the valence state of Gd@C82 microcrystals. Phys. Rev. B, 2000, 62(3), P. 1627–1630.</mixed-citation><mixed-citation xml:lang="en">Suenaga K., Iijima S., Kato H., Shinohara H. Fine-structure analysis of Gd M45 near-edge EELS on the valence state of Gd@C82 microcrystals. Phys. Rev. B, 2000, 62(3), P. 1627–1630.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Nishibori E., Takata M., Sakata M., Tanaka H., Hasegawa M., Shinohara H. Giant motion of La atom inside C82 cage. Chem. Phys. Lett., 2000, 330, P. 497–502.</mixed-citation><mixed-citation xml:lang="en">Nishibori E., Takata M., Sakata M., Tanaka H., Hasegawa M., Shinohara H. Giant motion of La atom inside C82 cage. Chem. Phys. Lett., 2000, 330, P. 497–502.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Nishibori E., Takata M., Sakata M., Inakuma M., Shinohara H. Determination of the cage structure of Sc@C82 by synchrotron powder diffraction. Chem. Phys. Lett., 1998, 298, P. 79–84.</mixed-citation><mixed-citation xml:lang="en">Nishibori E., Takata M., Sakata M., Inakuma M., Shinohara H. Determination of the cage structure of Sc@C82 by synchrotron powder diffraction. Chem. Phys. Lett., 1998, 298, P. 79–84.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Takata M., Imeda B., Nishibori E., Sakata M., Saito Y., Ohno M., Shinohara H. Confirmation by X-ray-diffraction of the Endohedral Nature of the Metallofullerene Y@C82. Nature, 1995, 377, P. 46–49.</mixed-citation><mixed-citation xml:lang="en">Takata M., Imeda B., Nishibori E., Sakata M., Saito Y., Ohno M., Shinohara H. Confirmation by X-ray-diffraction of the Endohedral Nature of the Metallofullerene Y@C82. Nature, 1995, 377, P. 46–49.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Nishibori E., Iwata K., Sakata M., Takata M., Tanaka H., Kato H., Shinohara H. Anomalous endohedral structure of Gd@C82 metallofullerenes. Phys. Rev. B, 2004, 69, P. 113412(1-4).</mixed-citation><mixed-citation xml:lang="en">Nishibori E., Iwata K., Sakata M., Takata M., Tanaka H., Kato H., Shinohara H. Anomalous endohedral structure of Gd@C82 metallofullerenes. Phys. Rev. B, 2004, 69, P. 113412(1-4).</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Tang J.X., Yuan G.M., Cao H., et. al. Tuning electronic properties of metallic atom in bondage to a nanospace. J. Phys. Chem., 2005, 109, P. 8779–8785.</mixed-citation><mixed-citation xml:lang="en">Tang J.X., Yuan G.M., Cao H., et. al. Tuning electronic properties of metallic atom in bondage to a nanospace. J. Phys. Chem., 2005, 109, P. 8779–8785.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Starke K., Navas E., Arenholz E., Hu Z., Baumgarten L., van der Laan G., Chen C. T., Kaindl G. Magnetic circular dichroism in 4d→4f resonant photoemission and photoabsorption of Gd metal. Phys. Rev. B, 1997, 55, P. 2672–2675.</mixed-citation><mixed-citation xml:lang="en">Starke K., Navas E., Arenholz E., Hu Z., Baumgarten L., van der Laan G., Chen C. T., Kaindl G. Magnetic circular dichroism in 4d→4f resonant photoemission and photoabsorption of Gd metal. Phys. Rev. B, 1997, 55, P. 2672–2675.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Tobin J.G., Chung B.W., Schulze R.K., Terry J., Farr J. D., Shuh D. K., Heinzelman K., Rotenberg E., Waddill G.D., Van der Laan G. Resonant photoemission in f-electron systems: Pu and Gd. Phys. Rev. B, 2003, 68, P. 115109(1-11).</mixed-citation><mixed-citation xml:lang="en">Tobin J.G., Chung B.W., Schulze R.K., Terry J., Farr J. D., Shuh D. K., Heinzelman K., Rotenberg E., Waddill G.D., Van der Laan G. Resonant photoemission in f-electron systems: Pu and Gd. Phys. Rev. B, 2003, 68, P. 115109(1-11).</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Szhogina A.A., Shilin V.A., Sedov V.P., Lebedev V.T. Endohedral metallofulerenols survival under neutron irradiation. Crystallography (in press, Rus.).</mixed-citation><mixed-citation xml:lang="en">Szhogina A.A., Shilin V.A., Sedov V.P., Lebedev V.T. Endohedral metallofulerenols survival under neutron irradiation. Crystallography (in press, Rus.).</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Shilin V.A., Lebedev V.T., Kolesnik S.G., Kozlov V.SGrushko., Yu.S., Sedov V.P., Kukorenko V.V. Investigation of the Neutron Activation of Endohedral Rare Earth Metallofullerenes. Crystallography Reports, 2011, 56(7), P. 1192–1196.</mixed-citation><mixed-citation xml:lang="en">Shilin V.A., Lebedev V.T., Kolesnik S.G., Kozlov V.SGrushko., Yu.S., Sedov V.P., Kukorenko V.V. Investigation of the Neutron Activation of Endohedral Rare Earth Metallofullerenes. Crystallography Reports, 2011, 56(7), P. 1192–1196.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Okazaki T., Lian Y., Gu Z., Suenaga K., Shinohara H. Isolation and spectroscopic characterization of Sm-containing metallofullerenes. Chem. Phys. Lett., 2000, 320, P. 435–440.</mixed-citation><mixed-citation xml:lang="en">Okazaki T., Lian Y., Gu Z., Suenaga K., Shinohara H. Isolation and spectroscopic characterization of Sm-containing metallofullerenes. Chem. Phys. Lett., 2000, 320, P. 435–440.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
