najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2019-10-6-694-700najo-848Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХFacile combustion synthesis of TbFeO3 nanocrystals with hexagonal and orthorhombic structureFacile combustion synthesis of TbFeO3 nanocrystals with hexagonal and orthorhombic structureMartinsonK. D.MartinsonK. D.

Politeknicheskaya St., 26, St. Petersburg, 194021

Politeknicheskaya St., 26, St. Petersburg, 194021

martinsonkirill@mail.ruIvanovV. А.IvanovV. A.

Moskovsky prospect 26, Saint Petersburg, 190013

Moskovsky prospect 26, Saint Petersburg, 190013

ChebanenkoМ. I.ChebanenkoM. I.

Politeknicheskaya St., 26, St. Petersburg, 194021

Politeknicheskaya St., 26, St. Petersburg, 194021

PanchukV. V.PanchukV. V.

Peterhof, 198504 Saint Petersburg

Peterhof, 198504 Saint Petersburg

SemenovV. G.SemenovV. G.

Peterhof, 198504 Saint Petersburg

Peterhof, 198504 Saint Petersburg

PopkovV. I.PopkovV. I.

Politeknicheskaya St., 26, St. Petersburg, 194021

Politeknicheskaya St., 26, St. Petersburg, 194021

Ioffe InstituteIoffe InstituteSaint Petersburg State Institute of TechnologySaint Petersburg State Institute of TechnologySaint Petersburg State UniversitySaint Petersburg State University201913082025106694700Copyright © Martinson K.D., Ivanov V.A., Chebanenko M.I., Panchuk V.V., Semenov V.G., Popkov V.I., 20252025Martinson K.D., Ivanov V.А., Chebanenko М.I., Panchuk V.V., Semenov V.G., Popkov V.I.Martinson K.D., Ivanov V.A., Chebanenko M.I., Panchuk V.V., Semenov V.G., Popkov V.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/848

In this research, the formation process of nanocrystalline terbium orthoferrite (TbFeO3) obtained via a solution combustion technique was studied using powder X-ray diffractometry, scanning electron microscopy, 57Fe Mo¨ssbauer spectroscopy, N2 adsorption analysis, and FTIR spectroscopy. It was shown that glycine-nitrate combustion method permits one to obtain TbFeO3 of three different modifications: orthorhombic o-TbFeO3 (Pbnm), hexagonal h-TbFeO3 (P63/mmc) and amorphous am-TbFeO3. It was found that the average crystallite sizes of orthorhombic and hexagonal TbFeO3 were 29±3 and 15±2 nm, respectively. The formation mechanism of different structural forms of terbium orthoferrite was investigated on the basis of nanopowders morphology, specific surface areas, average pore sizes, and crystallite sizes.

In this research, the formation process of nanocrystalline terbium orthoferrite (TbFeO3) obtained via a solution combustion technique was studied using powder X-ray diffractometry, scanning electron microscopy, 57Fe Mo¨ssbauer spectroscopy, N2 adsorption analysis, and FTIR spectroscopy. It was shown that glycine-nitrate combustion method permits one to obtain TbFeO3 of three different modifications: orthorhombic o-TbFeO3 (Pbnm), hexagonal h-TbFeO3 (P63/mmc) and amorphous am-TbFeO3. It was found that the average crystallite sizes of orthorhombic and hexagonal TbFeO3 were 29±3 and 15±2 nm, respectively. The formation mechanism of different structural forms of terbium orthoferrite was investigated on the basis of nanopowders morphology, specific surface areas, average pore sizes, and crystallite sizes.

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The authors declare that there are no conflicts of interest present.