najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМО10.17586/2220-8054-2018-9-6-763-769najo-857Research ArticleCHEMISTRY AND MATERIALS SCIENCEХИМИЯ И НАУКА О МАТЕРИАЛАХSolid-phase interaction in ZrO2–Fe2O3 nanocrystalline systemKirillovaS. A.

ul. Professora Popova, 5, St. Petersburg, 197376

refractory-sveta@mail.ruAlmjashevaO. V.

ul. Professora Popova, 5, St. Petersburg, 197376

almjasheva@mail.ruPanchukV. V.

Universitetskaya nab., 7–9, St. Petersburg, 199034

vitpan@mail.ruSemenovV. G.

Universitetskaya nab., 7–9, St. Petersburg, 199034

val_sem@mail.ruSt. Petersburg State Electrotechnical University “LETI”Russian FederationSt. Petersburg State UniversityRussian Federation20181408202596763–769Copyright © Kirillova S.A., Almjasheva O.V., Panchuk V.V., Semenov V.G., 20252025Kirillova S.A., Almjasheva O.V., Panchuk V.V., Semenov V.G.Kirillova S.A., Almjasheva O.V., Panchuk V.V., Semenov V.G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/857

Based on the results of X-ray phase analysis and Mossbauer spectroscopy, it was demonstrated that in the ZrO¨ 2–Fe2O3 system, represented by the mechanical mixture of m–ZrO2 (14±2 nm) and α-Fe2O3 (43±2 nm) nanoparticles, being heated above the temperature corresponding to the melting temperature of the two-dimensional nonautonomous phase, transformation of α-Fe2O3 occurs resulting in appearing of the X-ray amorphous magnetically disordered state localized on the surface of ZrO2 nanoparticles in the form of a thin layer. Transformation pattern in ZrO2–Fe2O3 nanocrystalline system has been introduced.

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The authors declare that there are no conflicts of interest present.