najoNanosystems: Physics, Chemistry, MathematicsНаносистемы: физика, химия, математика2220-80542305-7971Университет ИТМОnajo-868Research ArticleFULLERENSFULLERENSSynthesis, isolation, and X-ray structural characterization of trifluoromethylated C90 fullerenes: C90(30)(CF3)18 and C90(35)(CF3)14TammN. B.

Department of Chemistry

Moscow

tamm@thermo.chem.msu.ruTroyanovS. I.

Department of Chemistry

Moscow

stroyano@thermo.chem.msu.ruMoscow State UniversityRussian Federation201415082025513945Copyright © Tamm N.B., Troyanov S.I., 20252025Tamm N.B., Troyanov S.I.Tamm N.B., Troyanov S.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://nanojournal.ifmo.ru/jour/article/view/868

Two CF3 derivatives of C90, C90(30)(CF3)18 and C90(35)(CF3)14, have been isolated via HPLC from the products of a high-temperature trifluoromethylation of a C76–C96 fullerene mixture with CF3I. Their molecular structures were determined by single crystal X-ray crystallography using synchrotron radiation. The addition patterns of the new compounds are discussed in comparison with those of the corresponding chlorinated C90.

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The authors declare that there are no conflicts of interest present.